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1.
Sergio Caroli Francesco La Torre Francesco Petrucci Nicola Violante 《Environmental science and pollution research international》1994,1(4):205-208
The separation and determination of sub-μmol/l levels of six environmentally significant As compounds was accomplished by
means of high performance liquid chromatography (HPLC) combined online with inductively coupled plasma mass spectrometry (ICP-MS).
The species of interest (arsenite and arsenate, monomethylarsonic acid, dimethylarsinic acid, arsenobetaine and arsenocholine)
were quantified in fish and mussel extracts after separation on a Dionex AS7 column equipped with an on-guard AG7 column using
a bicarbonate buffer as the mobile phase in a gradient mode. The species thus eluted were directly forwarded to the ICP-MS
detector. The detection power of the overall system allows each As form to be determined at concentrations as low a 0.0013–0.0027
μmol 1−1. 相似文献
2.
Federico Pasquaré Mariotto Corrado Venturini 《Environment, Development and Sustainability》2017,19(4):1367-1380
In 2014, there was virtually no summer in northern and central-southern Italy. Storm after storm battered the peninsula, triggering floods and landslides from Veneto to Puglia. We studied the coverage of “the year without a summer” in Italy by analyzing the content of 171 news articles from two influential online newspapers. Our software-based analysis enabled us to observe that the two newspapers hardly ever mentioned climate change in their coverage of the weather anomaly that affected Italy in the summer of 2014. This type of coverage is in line with climate science, according to which there is no evidence of a climate change-related influence on summer precipitation patterns in Southern Europe—whereas such influence has been documented for northern Europe. We compared our results with a recent paper, which documented that the same online dailies chose to represent the particularly hot summer of 2012 in Italy as a direct consequence of climate change. We corroborated this comparison also on the basis of a preliminary analysis we performed on the media coverage of the exceptionally hot and arid summer of 2015 in Italy. 相似文献
3.
4.
Antonio Bucci Vincenzo Allocca Gino Naclerio Giovanni Capobianco Fabio Divino Francesco Fiorillo Fulvio Celico 《环境科学学报(英文版)》2015,(1):131-138
The aim of the research was to evaluate, at site scale, the influence of freezing and freeze/thaw cycles on the survival of faecal coliforms and faecal enterococci in soil, in a climate change perspective. Before the winter period and during grazing, viable cells of faecal coliforms and faecal enterococci were detected only in the first 10 cm below ground, while,after the winter period and before the new seasonal grazing, a lower number of viable cells of both faecal indicators was detected only in some of the investigated soil profiles, and within the first 5 cm. Taking into consideration the results of specific investigations, we hypothesise that the non-uniform spatial distribution of grass roots within the studied soil can play an important role in influencing this phenomenon, while several abiotic factors do not play any significant role. Taking into account the local trend in the increase of air temperature, a different distribution of microbial pollution over time is expected in spring waters, in future climate scenarios. The progressive increase in air temperature will cause a progressive decrease in freeze/thaw cycles at higher altitudes, minimising cold shocks on microbial cells, and causing spring water pollution also during winter. 相似文献
5.
This paper explores the distributional consequences of alternative emissions trading schemes. It is argued that the distributional
impact stems from the difference between two social welfare functions: the function which is implicitly maximised in a competitive
market equilibrium and the function which is implicitly adopted when a given equity principle is chosen. An integrated assessment
model is used to illustrate these findings, by simulating the introduction of various emissions trading schemes for the Kyoto
protocol on the reduction of greenhouse emissions. It is shown that (1) changes produced on an equity index by the imposition
of emission constraints (by country) may not be significantly higher than those obtained by the subsequent introduction of
a market mechanism, and that (2) the various market regimes which could be adopted have quite different distributional implications.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
6.
Ionela Birloaga Ida De Michelis Francesco Ferella Mihai Buzatu Francesco Vegliò 《Waste management (New York, N.Y.)》2013,33(4):935-941
The present lab-scale experimental study presents the process of leaching waste printed circuit boards (WPCBs) in order to recover gold by thioureation. Preliminary tests have shown that copper adversely affects gold extraction; therefore an oxidative leaching pre-treatment was performed in order to remove base metals. The effects of sulfuric acid concentration, hydrogen peroxide volume and temperature on the metal extraction yield were studied by analysis of variance (ANOVA). The highest copper extraction yields were 76.12% for sample A and 18.29% for sample D, after leaching with 2 M H2SO4, 20 ml of 30% H2O2 at 30 °C for 3 h. In order to improve Cu removal, a second leaching was performed only on sample A, resulting in a Cu extraction yield of 90%. Other experiments have shown the negative effect of the stirring rate on copper dissolution. The conditions used for the process of gold extraction by thiourea were: 20 g/L thiourea, 6 g/L ferric ion, 10 g/L sulfuric acid, 600 rpm stirring rate. To study the influence of temperature and particle size, this process was tested on pins manually removed from computer central processing units (CPUs) and on waste CPU for 3½ h. A gold extraction yield of 69% was obtained after 75% of Cu was removed by a double oxidative leaching treatment of WPCBs with particle sizes smaller than 2 mm. 相似文献
7.
Francesco Di Maria Alessio Sordi Giuseppe Cirulli Giovanni Gigliotti Luisa Massaccesi Mirko Cucina 《Waste management (New York, N.Y.)》2014,34(9):1603-1608
The co-digestion of a variable amount of fruit and vegetable waste in a waste mixed sludge digester was investigated using a pilot scale apparatus. The organic loading rate (OLR) was increased from 1.46 kg VS/m3 day to 2.8 kg VS/m3 day. The hydraulic retention time was reduced from 14 days to about 10 days. Specific bio-methane production increased from about 90 NL/kg VS to the maximum value of about 430 NL/kg VS when OLR was increased from 1.46 kg VS/m3 day to 2.1 kg VS/m3 day. A higher OLR caused an excessive reduction in the hydraulic retention time, enhancing microorganism wash out. Process stability evaluated by the total volatile fatty acids concentration (mg/l) to the alkalinity buffer capacity (eq. mg/l CaCO3) ratio (i.e. FOS/TAC) criterion was <0.1 indicating high stability for OLR <2.46 kg VS/m3 day. For higher OLR, FOS/TAC increased rapidly. Residual phytotoxicty of the digestate evaluated by the germination index (GI) (%) was quite constant for OLR < 2.46 kg VS/m3 day, which is lower than the 60% limit, indicating an acceptable toxicity level for crops. For OLR > 2.46 kg VS/m3 day, GI decreased rapidly. This corresponding trend between FOS/TAC and GI was further investigated by the definition of the GI ratio (GIR) parameter. Comparison between GIR and FOS/TAC suggests that GI could be a suitable criterion for evaluating process stability. 相似文献
8.
Francesco Massart Flora Micillo Gaetano Rivezzi Laura Perrone Angelo Baggiani Mario Miccoli 《毒物与环境化学》2016,98(1):128-136
The mycotoxin zearalenone exhibits estrogenic and anabolic properties in several animal species, humans included. Food contamination by zearalenone is caused either by direct contamination of grains, fruits, and their based-products or by “carry-over” of mycotoxins in animal tissues, milk, and eggs after intake of contaminated feedstuff. Now, a survey on zearalenone contamination in breast milk of healthy primiparous women living in the Naples countryside was conducted. From 47 healthy primiparous women, breast milk samples were collected within the first six weeks after delivery as well as clinical data of mother–newborn pairs. Breast milk analyses were performed with both competitive indirect enzyme-linked immunosorbent assay and high-performance liquid chromatography with fluorescence detection. At 36.9 ± 2.6 days after vaginal delivery, the mean zearalenone contents of the breast milk samples were 1.13 ± 0.34 µg/L. The zearalenone levels correlated with both mother weights before pregnancy (r = ?0.506; P < 0.001) and at delivery (r = ?0.351; P < 0.05). The present results indicate that breast milk may be contaminated with zearalenone. 相似文献
9.
Fernando Condal Jacopo Aguzzi Francesc Sardà Marc Nogueras Javier Cadena Corrado Costa J. Del Río Antoni Mànuel 《Marine Biology》2012,159(12):2809-2817
To adequately describe seasonal rhythms in habitat utilization by fish communities, observations are needed that occur at a relatively high frequency and over large temporal windows. For the first time, images collected from a cabled video-observatory (the western Mediterranean expandable SEAfloor OBservatory; OBSEA) were utilized to examine habitat utilization by coastal fishes. Over the course of a year, hourly digital images of the water column and an artificial reef were obtained during daylight hours. For each image, the total number of species, an estimate of the abundance of individuals, and the Shannon Diversity Index were quantified. A total of 22 fish species commonly associated with nearshore western Mediterranean habitats were identified, and significant spatial (water column vs. artificial reef), seasonal (spring, summer, autumn, and winter), and daily (morning, midday, and sunset) differences in habitat utilization occurred. Four species (Diplodus vulgaris, Diplodus cervinus, Diplodus sargus, and Scorpaena porcus) were associated with the artificial reef, while one species (Pagrus pagrus) chiefly occurred in the water column. Chromis chromis and Diplodus annularis occurred at the site more frequently in the winter and autumn, respectively, while 14 other species utilized the site more frequently in either the spring (8 spp) or summer (6 spp). In addition, Dentex dentex and Spicara maena occurred more frequently at sunset, while D. cervinus displayed a crepuscular rhythm (occurring more frequently in the morning and at sunset). Species diversity was highest in the summer and lowest in the winter. If not taken into account when planning in situ sampling, such seasonal and/or diel differences may lead to spurious estimates of population sizes and biodiversity. We suggest that cabled video-observatories offer a non-invasive and reliable technology for faunistic sampling and population assessment in coastal water of the Mediterranean and likely elsewhere. 相似文献
10.
Antonella?De?DonnoEmail author Tiziana?Grassi Francesco?Bagordo Adele?Idolo Francesca?Serio Giovanni?Gabutti 《Food and environmental virology》2012,4(2):81-88
The purpose of this study was to demonstrate that shellfish can be used to detect enteric viruses in marine waters where they
are present at very low concentrations. Aqua-cultured mussels were placed in the sea just off the mouth of a drainage channel
affected by human and animal faecal contamination. Samples were taken from the channel, the sea and the mussels at intervals
over two 4-week periods. The samples were tested to verify the presence of both rotaviruses and E. coli. Rotaviruses were detected by Real Time-PCR, typed by multiplex PCR and subsequently sequenced. E. coli was enumerated in water matrices by a filtering method and in mussels by the MPN method. The presence of E. coli in the examined matrices demonstrates contamination of faecal origin throughout the studied environments. Rotaviruses were
recorded in channel waters, but not in sea water. In both experiments, rotaviruses were detected in mussels 21 and 28 days
after being placed in the sea water off the channel mouth. The use of mussels thus enabled the detection of rotaviruses in
waters where the high dilution rendered direct investigation impossible. This study indicates that mussels can be used in
marine virological surveillance programs. 相似文献