基于N，N─二甲基苯胺与NO_2~－─对氨基苯磺酸重氮盐的偶联反应示波极谱法测定NO_2~－

报道了利用Ｎ，Ｎ─二甲基苯胺为偶联试剂的Ｃｒｉｅｓｓ反应以示波极谱法测定ＮＯ_２~－的测试方法。在拟定的实验条件下，ＮＯ_２~－在４．０×１０~－３～４．８×１０~－１μｇ／ｍｌ范围内与极谱波波高呈良好的线性关系。环境水测定的相对标准偏差小于ｌ％，回收率在９７％～１０１％之间。     

国内外环境监测分析的现状和发展

从实验室分析仪器和技术、与污染物总量控制有关的自动监测系统和技术，与应急事故监测有关的现场简易监测分析仪器和技术等方面概括介绍了环境监测分析仪器和技术的现状与发展，并概要介绍了日美及中国环境监测分析产业的现状与发展。     

高炉瓦斯泥的回收与利用

通过对济钢高炉瓦斯泥进行分离回收与综合利用的系统试验研究,作者推荐采用浮—重联合流程分离回收其中的炭和铁。试验获得如下指标:炭精矿品位80％,回收率50％;铁精矿品位60％,回收率45％;次铁精矿品位45％,回收率11.5％。经济和社会效益明显。     

物化—生化组合工艺在鱼油工业废水处理中的应用

针对鱼油工业废水排放特点及处理技术难点，结合实例，采用混凝、破乳进行物化预处理；采用A／O生化处理技术，提出合适的工艺流程。     

对硝基氯苯废气治理研究

冷却凝固法处理含对硝基氯苯废气 ,用水作冷却剂直接冷却、冷凝、凝固、凝华废气中对硝基氯苯蒸气 ,废气中的升华物、粉尘和水蒸汽同时被分离 ,处理后的废气达到很高的净化程度。在此根据实验结果 ,得到在水蒸汽存在时对硝基氯苯蒸气分压和温度之间的关系     

抚顺市空气可吸入颗粒物特征的研究

于2002年1～7月份在抚顺市区四个点位采集了环境空气中的可吸入颗粒物样品，经分析后获得了可吸入颗粒物组分的时间分布和空间分布特征，即采暖期PM10样品中有机碳（OC）、元素碳（EC）的绝对含量和相对含量均高于非采暖期，工业区PM10样品中的Fe、Zn、Pb的绝对含量和相对含量均明显高于其它点位，反映了其工业区的特点。     

自然灾害变动的集成预测模型及其应用

本文提出了以非线性回归拟合发展趋势、正弦函数逼近周期变动和马尔可夫链刻划随机扰动的集成预测模型，并应用于山东省农业自然灾害成灾面积的变动规律模拟，得到了较好的预测效果。理论和实践表明，集成预测模型优于传统的单模型预测，为预测具有复杂机制的自然灾害演变提供了一种新方法。     

气象卫星遥感在干旱监测中的应用

本文根据ＮＯＡＡ极轨气象卫星ＡＶＨＲＲ资料计算生成植被指数相对距平图用于旱情监测，并在江苏省１９９４年特大干旱中进行了应用服务     

Influence of particle size on the aggregation behavior of nanoparticles: Role of structural hydration layer

More and more attention has been paid to the aggregation behavior of nanoparticles, but little research has been done on the effect of particle size. Therefore, this study systematically evaluated the aggregation behavior of nano-silica particles with diameter 130–480 nm at different initial particle concentration, pH, ionic strength, and ionic valence of electrolytes. The modified Smoluchowski theory failed to describe the aggregation kinetics for nano-silica particles with diameters less than 190 nm. Besides, ionic strength, cation species and pH all affected fast aggregation rate coefficients of 130 nm nanoparticles. Through incorporating structural hydration force into the modified Smoluchowski theory, it is found that the reason for all the anomalous aggregation behavior was the different structural hydration layer thickness of nanoparticles with various sizes. The thickness decreased with increasing of particle size, and remained basically unchanged for particles larger than 190 nm. Only when the distance at primary minimum was twice the thickness of structural hydration layer, the structural hydration force dominated, leading to the higher stability of nanoparticles. This study clearly clarified the unique aggregation mechanism of nanoparticles with smaller size, which provided reference for predicting transport and fate of nanoparticles and could help facilitate the evaluation of their environment risks.     

Photo-degradation organic dyes by Sb-based organic-inorganic hybrid ferroelectrics

The organic-inorganic hybrid halide compounds have emerged as one of the most promising photoelectric material for their superior optoelectronic properties and hold great prospects for renewable energy substitutes and environmental protection as photocatalysis. Here, we report the optical properties of the Sb-based organic-inorganic hybrid ferroelectric materials: pyridine-4-aminium tetrachloroantimonate ((C₅H₇N₂)SbCl₄, sample 1), piperidin-1-aminium tetrachloroantimonate ((C₅H₁₃N₂)SbCl₄, sample 2) and tris(trimethylammonium) nonachlorodiantimonate (((CH₃)₃NH)₃Sb₂Cl₉, sample 3), which are a kind of exploited efficient photocatalysts. Samples 2 and 3 exhibit distinct photoelectric respond, which are mainly ascribed to their minor narrow band-gap compared with sample 1. For the ferroelectrics, the intrinsic of spontaneous polarization of sample 3 at room temperature is favourable for the separation of photogenerated electrons and holes within the photorespond process. Moreover, sample 3 shows the highest efficiency of photo-decomposed Rhodamine B (90.2% within 80 min) and Methyl Orange (MO) (97.4% within 50 min), thanks to the photo-excited electrons and holes promoting the formation of oxidative radical species during the photo-redox progress. These findings prove that the development of a novel Sb-based organic-inorganic hybrid halide compounds with good stability in the degradation of organic dyes paves a way to designing new photocatalyst.