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排序方式: 共有73条查询结果,搜索用时 15 毫秒
1.
Kazuo Kamura Yu Hara Bulent Inanc Masato Yamada Yuzo Inoue Yusaku Ono 《Journal of Material Cycles and Waste Management》2005,7(2):66-70
It is always possible for impermeable layers to exist in landfills. When they do, the properties of the solution at the exit of the leachate-collection system might not accurately reflect the overall properties of the landfill. This study examines whether resistivity monitoring is effective for determining the influence of impermeable layers on the leachate. The test cell used in this study was filled with waste made up mainly of incinerator ash and shredded incombustible material. Three lines of resistivity sensors were laid in the uppermost layer of the fill. A resistivity profile was recorded periodically from each of these lines. The water-table level and leachate properties were measured concurrently. Leachate conductivity was mainly controlled by concentrations of the main ions, and it correlated inversely to variations in resistivity. Temporal changes in the resistivity of the fills are an excellent means of assessing the leaching in fills. Monitoring the properties of leachate, combined with resistivity profiling, is extremely useful for interpreting the temporal changes of properties in landfills containing impermeable layers. 相似文献
2.
Osamu Sawai Teppei Nunoura Kazuo Yamamoto 《Journal of Material Cycles and Waste Management》2014,16(1):82-92
Sewage sludge, a byproduct of municipal wastewater treatment, was gasified by supercritical water using a bench-scale batch reactor. Configuration of bench-scale batch reactor and operation procedures are discussed in detail. Experience and challenges that arose during the experiment are also shared. Using the bench-scale reactor under the condition of 600 °C, 23 MPa, and a reaction time of 60 min without catalyst presence, a total gas yield of 9.8 mol/(kg-sewage sludge) was obtained. Furthermore, investigations on operational parameters were conducted. Extension of reaction time up to 60 min increased the gasification, reaching a plateau thereafter. Investigation on pressure indicated the superiority of supercritical pressure. The addition of Ni as a catalyst also promoted gasification, although inorganic salts and char seemed to cover the catalyst surface. With regard to the prospect of future operation at a municipal waste water treatment plant, the effect of operational parameters on heavy metal concentration in the liquid phase is also discussed. 相似文献
3.
Effects of potassium alkalis and sodium alkalis on the dechlorination of o-chlorophenol in supercritical water 总被引:1,自引:0,他引:1
Effects of potassium alkalis and sodium alkalis on the dechlorination of o-chlorophenol (o-CP) in supercritical water (SCW) were studied in this paper under the conditions of 450 degrees C and 25 MPa. Experimental results indicated that the dechlorination of o-CP can be accelerated significantly by all alkalis investigated. The dechlorination of o-CP proceeded mainly via two pathways: hydrodechlorination and hydrolysis. Both of the two pathways can be promoted by alkalis, and the dechlorination of o-CP can be accelerated by both the cations and hydroxide ion dissociated from alkalis. The overall dechlorination of o-CP can be accelerated by cations via promoting the hydrodechlorination pathway, while, hydroxide ion via promoting the hydrolysis pathway. In addition, the hydrodechlorination can be accelerated faster by sodium alkalis than that by potassium ones, while, the hydrolysis can be promoted faster by potassium alkalis. This difference may be caused by the different charge density between potassium ion and sodium ion, and the different solubility and dissociation constant between potassium alkalis and sodium alkalis in SCW. Dechlorination of o-CP with addition of alkalis prior to supercritical water oxidation (SCWO) process not only can avoid the reactor corrosion caused by the generated hydrochloric acid in direct SCWO of o-CP, but also can reduce the formation of toxic chlorinated byproducts compared with direct SCWO process or SCWO of o-CP with addition of alkali. 相似文献
4.
Teru Yamamoto Kazuo Higashino Tamae Abe Takumi Takasuga Hiroaki Takemori Roland Weber Yuko Sasaki 《Environmental science and pollution research international》2018,25(32):31874-31884
Studies on the formation of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) during the electrolysis of sodium chloride solution (brine) using graphite or titanium electrodes were carried out at a laboratory scale. High concentrations of PCDFs but no PCDDs were formed in tests using graphite electrodes. With titanium electrodes, PCDFs were only formed when tar pitch was added and mainly originated from the dibenzofuran present in the tar. For the first time, a detailed assessment of the formation of mono- to octachlorinated PCDD/PCDF from tar pitch was investigated. The assessment included of the chlorination steps proved that PCDFs were formed by successive lateral chlorinated from dibenzofuran to MonoCDFs, DiCDFs, and TriCDFs to form the typical known “chlorine pattern” of TetraCDF to OctaCDF with a dominance of 1,2,7,8- and 2,3,7,8-TetraCDFs, 1,2,3,7,8-PentaCDF, and 1,2,3,4,7,8-HexaCDF as marker congeners. The final homologue distributions depended on reaction time and reaction temperature. In addition, electrolysis with non-chlorinated dibenzo-p-dioxins, dibenzofuran, and biphenyl was carried out. As a result, PCDDs, PCDFs, and PCB were formed at comparable yields. Congener patterns in soil samples from a PCDD/F-contaminated site where chlor-alkali electrolysis had been operated for decades in Japan had identical isomer distribution demonstrating the source and contamination potential and risk of these processes. Therefore, sites where in the past 120 years chlor-alkali electrolysis has been operated or where residues from chlor-alkali production or other chlorine using industries have been disposed should be assessed for their pollution level and exposure relevance. The assessment of total organohalogen content revealed that PCDF is only a small fraction of organohalogens in the contaminated soils. For an appropriate risk assessment, also other chlorinated aromatic compounds such as PCBs or PCNs need to be considered. 相似文献
5.
Takeshi Sasaki Atsushi Iizuka Masayuki Watanabe Teruhisa Hongo Akihiro Yamasaki 《Waste management (New York, N.Y.)》2014,34(10):1829-1835
Solid adsorbent materials, prepared from waste cement powder and concrete sludge were assessed for removal of arsenic in the form of arsenic (As(V)) from water. All the materials exhibited arsenic removal capacity when added to distilled water containing 10–700 mg/L arsenic. The arsenic removal isotherms were expressed by the Langmuir type equations, and the highest removal capacity was observed for the adsorbent prepared from concrete sludge with heat treatment at 105 °C, the maximum removal capacity being 175 mg-As(V)/g. Based on changes in arsenic and calcium ion concentrations, and solution pH, the removal mechanism for arsenic was considered to involve the precipitation of calcium arsenate, Ca3(AsO4)2. The enhanced removal of arsenic for the adsorbent prepared from concrete sludge with heat treatment was thought to reflect ion exchange by ettringite. The prepared adsorbents, derived from waste cement and concrete using simple procedures, may offer a cost effective approach for arsenic removal and clean-up of contaminated waters, especially in developing countries. 相似文献
6.
One of the major consequences of global warming is a rise in sea surface temperature which may affect the survival of marine
organisms including phytoplankton. Here, we provide experimental evidence for heat-induced cell death in a symbiotic microalga.
Shifting Symbiodinium microadriaticum from 27 to 32°C resulted in an increase in mortality, an increase in caspase 3-like activity, and an increase in nitric oxide
(NO) production. The caspase-like activity was strongly correlated with the production of NO in thermally challenged microalgae.
For this experiment, the application of Ac-DEVD-CHO, a mammalian caspase 3-specific inhibitor, partly prevented (by 65%) the
increase in caspase-like activity. To verify the relationship between NO and the caspase-like activity, S. microadriaticum were subsequently incubated with 1.0 mM of the following chemical NO donors: sodium nitroprusside (SNP), S-nitrosoglutathione (GSNO), S-nitroso-N-acetylpenicillamine (SNAP) and 3,3bis(Aminoethyl)-1-hydroxy-2-oxo-1-triazene (NOC-18). The supplementation of both SNP and
NOC-18 caused a significant increase in caspase-like activity compared to the control treatment. Pre-treatment of the microalgae
with the inhibitor Ac-DEVD-CHO before the supplementation of the different NO donors completely prevented the increase in
caspase-like activity. These results suggest that NO could play a role in the induction of cell death in heat-stressed S. microadriaticum by mediating an increase in caspase-like activity. 相似文献
7.
Nagasaka K Mizuno K Tanaka E Yamamoto S Iwamoto M Miki K Kajzer J 《Traffic injury prevention》2003,4(4):345-354
In vehicle-pedestrian collisions, lower extremities of pedestrians are frequently injured by vehicle front structures. In this study, a finite element (FE) model of THUMS (total human model for safety) was modified in order to assess injuries to a pedestrian lower extremity. Dynamic impact responses of the knee joint of the FE model were validated on the basis of data from the literature. Since in real-world accidents, the vehicle bumper can impact the lower extremities in various situations, the relations between lower extremity injury risk and impact conditions, such as between impact location, angle, and impactor stiffness, were analyzed. The FE simulation demonstrated that the motion of the lower extremity may be classified into a contact effect of the impactor and an inertia effect from a thigh or leg. In the contact phase, the stress of the bone is high in the area contacted by the impactor, which can cause fracture. Thus, in this phase the impactor stiffness affects the fracture risk of bone. In the inertia phase, the behavior of the lower extremity depends on the impact locations and angles, and the knee ligament forces become high according to the lower extremity behavior. The force of the collateral ligament is high compared with other knee ligaments, due to knee valgus motions in vehicle-pedestrian collisions. 相似文献
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10.
Mamoru Nishioka Nakamichi Yamasaki Hiroshi Amano Masanori Higuchi 《Waste management (New York, N.Y.)》1992,12(4)
Tritium is generally disposed of as an oxide form, and immobilization of tritium oxide with Portland cement is the most popular disposal method. However, the cement solidified body is rather leachable for tritium and is poor in some physical properties. A silicate powder, such as borosilicate glass powder, forms a synthetic rock by the hydrothermal hot-pressing (HHP) technique, making it a technique for immobilization of tritium oxide. Tritium oxide with borosilicate glass powder was solidified by the HHP technique. Leachability of tritium from the produced solidified bodies and the behavior of fixed tritium oxide during the heating were studied and discussed. The amount of tritium oxide fixed by the present procedure was almost the same as that fixed by the ordinary cement solidifying procedure. The diffusivity of tritium from the body by this procedure was much lower than that from the cement body and the compressive strength of the body was higher than that of the cement body. 相似文献