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排序方式: 共有209条查询结果,搜索用时 140 毫秒
1.
Yáñez J Fierro V Mansilla H Figueroa L Cornejo L Barnes RM 《Journal of environmental monitoring : JEM》2005,7(12):1335-1341
The analysis for arsenic in hair is commonly used in epidemiological studies to assess exposure to this toxic element. However, poor correlation between total arsenic concentration in hair and water sources have been found in previous studies. Exclusive determination of endogenous arsenic in the hair, excluding external contamination has become an analytical challenge. Arsenic speciation in hair appears as a new possibility for analytical assessing in As-exposure studies. This study applied a relative simple method for arsenic speciation in human hair based on water extraction and HPLC-HG-ICP-MS. The concentration of arsenic species in human hair was assessed in chronically As(V)-exposed populations from two villages (Esqui?a and Illapata) of the Atacama Desert, Chile. The arsenic concentrations in drinking water are 0.075 and 1.25 mg L(-1), respectively, where As(V) represented between 92 and 99.5% of the total arsenic of the consumed waters. On average, the total arsenic concentrations in hair from individuals of Esqui?a and Illapata were 0.7 and 6.1 microg g(-1), respectively. Four arsenic species, As(III), DMA(V), MMA(V) and As(V), were detected and quantified in the hair extracts. Assuming the found species in extracts represent the species in hair, more than 98% of the total arsenic in hair corresponded to inorganic As. On average, As(III) concentrations in hair were 0.25 and 3.75 microg g(-1) in Esqui?a and Illapata, respectively; while, the As(V) average concentrations were 0.15 and 0.45 microg g(-1) in Esqui?a and Illapata, respectively. Methylated species represent less than 2% of the extracted As (DMA(V)+ MMA(V)) in both populations. As(III) in hair shows the best correlation with chronic exposure to As(V) in comparison to other species and total arsenic. In fact, concentrations of As(total), As(III) and As(V) in hair samples are correlated with the age of the exposed individuals from Illapata (R= 0.65, 0.69, 0.57, respectively) and with the time of residence in this village (R= 0.54, 0.71 and 0.58, respectively). 相似文献
2.
3.
Prenatal diagnosis in a pregnancy at risk for a juvenile B1 variant of GM2-gangliosidosis was carried out. The biochemical study of the cultured amniocytes and the affected fetal brain is reported. The results obtained show that the sulphated artificial substrate can be used in the diagnosis of B1 variant, but not the neutral one. The accumulation of GM2-ganglioside in the fetal brain of the B1 juvenile form and an infantile form of GM2-gangliosidosis (0 variant) was compared. 相似文献
4.
Raiane Costa Souza Roberto Bagattini Portella Paula Valéria Nunes Brito Almeida Caroline Oliveira Pinto Priscila Gubert 《Journal of environmental science and health. Part. B》2020,55(6):530-538
AbstractOrganochlorine pesticides (OCPs) are widely used around the world as insecticides, herbicides, fungicides, nematicides, and rodenticides. Despite banned in Brazil, the usage remains occurring in many countries. The persistence and extreme mobility of OCPs contribute to the contamination of the environment and the human body. The OCPs bioaccumulation in adipose tissue triggers the excretion into human milk during breastfeeding. Hence, the present study determined eighteen OCPs residues in the breast milk of mothers from the Western Region of Bahia State, Brazil. Nine different residue species were found, including beta-Hexachlorocyclohexane (9.24?±?0.00?ng g?1 fat), delta- Hexachlorocyclohexane (22.15?±?10.48?ng g?1 fat), Heptachlor (58.08?±?74.13?ng g?1 fat), Aldrin (142.65?±?50.65?ng g?1 fat), Dieldrin (774.62?±?472.68?ng g?1 fat), Endosulfan I (408.44?±?245.51?ng g?1 fat), Dichloro-diphenyl-dichloro-ethylene (29.17?±?22.42?ng g?1 fat), Dichloro-diphenyl-trichloro-ethane (28.87?±?0.00?ng g?1 fat) and Methoxychlor (1699.67?±?797.43?ng g?1 fat). The Methoxychlor presence in all samples may reveal a recent exposure, while Dieldrin and Endosulfan I analyses can point to distant past exposure. 相似文献
5.
Mendes Rafael Farinassi Narciso Carolina Rezende Pinto Mendes Juliana Farinassi Viana Queilla Santos Eugênio Tony Matheus Carvalho Vilela Alan Pereira 《Environmental science and pollution research international》2021,28(28):37217-37230
Environmental Science and Pollution Research - The development of building materials using new types of raw materials is currently on demand by society and the industry. It is intended to reduce... 相似文献
6.
Mara C. Diguez Claudia P. Queimalios Sergio Ribeiro Guevar Mark Marvin-DiPasquale Carolina Soto Crdenas Mara A. Arribre 《环境科学学报(英文版)》2013,25(10):1980-1991
Ligands present in dissolved organic matter (DOM) form complexes with inorganic divalent mercury (Hg^2+) affecting its bioavailability in pelagic food webs. This investigation addresses the influence of a natural gradient of DOM present in Patagonian lakes on the bioaccumulation of Hg^2+ (the prevailing mercury species in the water column of these lakes) by the algae Cryptomonas erosa and the zooplankters Brachionus calyciflorus and Boeckella antiqua. Hg^2+ accumulation was studied through laboratory experiments using natural water of four oligotrophic Patagonian lakes amended with^197Hg^2+. The bioavailability of Hg^2+ was affected by the concentration and character of DOM. The entrance of Hg^2+ into pelagic food webs occurs mostly through passive and active accumulation. The incorporation of Hg^2+ by Cryptomonas, up to 27% of the Hg^2+ amended, was found to be rapid and dominated by passive adsorption, and was greatest when low molecular weight compounds with protein-like or small phenolic signatures prevailed in the DOM. Conversely, high molecular weight compounds with a humic or fulvic signature kept Hg^2+ in the dissolved phase, resulting in the lowest Hg^2+ accumulation in this algae. In Brachionus and Boeckella the direct incorporation of Hg from the aqueous phase was up to 3% of the Hg^2+ amended. The dietary incorporation of Hg^2+ by Boeckella exceeded the direct absorption of this metal in natural water, and was remarkably similar to the Hg^2+ adsorbed in their prey. Overall, DOM concentration and character affected the adsorption of Hg^2+ by algae through competitive binding, while the incorporation of Hg^2+ into the zooplankton was dominated by trophic or dietary transfer. 相似文献
7.
In field arsenic removal from natural water by zero-valent iron assisted by solar radiation 总被引:1,自引:0,他引:1
Cornejo L Lienqueo H Arenas M Acarapi J Contreras D Yáñez J Mansilla HD 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):827-831
An in situ arsenic removal method applicable to highly contaminated water is presented. The method is based in the use of steel wool, lemon juice and solar radiation. The method was evaluated using water from the Camarones River, Atacama Desert in northern Chile, in which the arsenic concentration ranges between 1000 and 1300 μg L−1. Response surface method analysis was used to optimize the amount of zero-valent iron (steel wool) and the citrate concentration (lemon juice) to be used. The optimal conditions when using solar radiation to remove arsenic from natural water from the Camarones river are: 1.3 g L−1 of steel wool and one drop (ca. 0.04 mL) of lemon juice. Under these conditions, removal percentages are higher than 99.5% and the final arsenic concentration is below 10 μg L−1. This highly effective arsenic removal method is easy to use and inexpensive to implement. 相似文献
8.
Branquinho C Serrano HC Pinto MJ Martins-Loução MA 《Environmental pollution (Barking, Essex : 1987)》2007,146(2):437-443
The several established criteria to define a hyperaccumulator plant were applied to a rare and endangered species, Plantago almogravensis, and to the 3rd most abundant element in the earth crust, Al. Using the most common criteria, P. almogravensis undoubtedly is an Al hyperaccumulator plant. If the recent proposed requirements were considered, most of them matching those for a plant to be used in phytoextraction, it can only be considered an unusual accumulator of Al. A discussion is made concerning the several criteria of a hyperaccumulator plant in order to include rare and endemic ones and abundant elements. In ecological terms, the enrichment in Al and Fe observed may account for the differences in the vegetation pattern. Due to the rarity and endangered nature of this plant, the contribution of this work is also relevant for the ecological understanding and the development of conservation options of this endemic species. 相似文献
9.
Current demand analysis methods do not formally cover the case of chronic deficits in quantity or quality of water and sanitation
services. These services include drinking water supply (DWS), wastewater and sewage treatment (WST), and municipal solid waste
management (MSW). Formal analysis of this case would, at minimum, define the deficit state and evaluate appropriate options
for reducing it. This paper proposes for a formal analytical model for municipal sanitation systems (MSS) that operate with
deficits in at least one of the constituent services of DWS, WST, or MSW. The model introduces definitions and notation for
describing the deficit state for conducting demand analysis on municipal sanitation systems. This model of demand analysis
for systems with chronic deficits will hereinafter be referred to as deficit analysis. A case study for Bacoor, Philippines is presented as an example. 相似文献
10.
Maia Lana S. Balieiro Lorena C. S. Teixeira Ericson J. O. Rodrigues Luciano M. Rosa Derval S. Mulinari Daniella R. 《Journal of Material Cycles and Waste Management》2023,25(4):2295-2311
Journal of Material Cycles and Waste Management - The use of lignocellulosic fibers as fillers in polymer matrices has aroused the interest of the scientific community and industrial sectors. In... 相似文献