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2.
Summary. Using Porapak Q traps, we collected the bark volatiles of six angiosperm trees native to British Columbia: black cottonwood,
Populus trichocarpa Torr. & A. Gray (Salicaceae), trembling aspen, P. tremuloides Michx. (Salicaceae), paper birch, Betula papyrifera Marsh. (Betulaceae), bigleaf maple, Acer macrophyllum Pursh (Aceraceae), red alder, Alnus rubra Bong. (Betulaceae), and Sitka alder, A. viridis ssp. sinuata (Regel) á. L?ve & D. L?ve (Betulaceae). Utilising coupled gas chromatographic-electroantennographic detection analysis, the
captured volatiles were assayed for antennal responses in five species of coniferophagous bark beetles (Coleoptera: Scolytidae),
sympatric with most or all of the angiosperm trees: the Douglas-fir beetle, Dendroctonus pseudotsugae Hopkins, the mountain pine beetle, D. ponderosae Hopkins, the spruce beetle, D. rufipennis (Kirby), the western balsam bark beetle, Dryocoetes confusus Swaine, and the pine engraver, Ips pini (Say). The identities of 25 antennally-active compounds were determined by coupled gas chromatographic-mass spectroscopic
analysis, and co-chromatographic comparisons with authentic chemicals. The compounds identified were: hexanal, (E)-2-hexenal, (Z)-3-hexen-1-ol, 1-hexanol, heptanal, α-pinene, frontalin, benzaldehyde, β-pinene, 2-hydroxycyclohexanone, 3-carene, limonene,
β-phellandrene, benzyl alcohol, (E)-ocimene, salicylaldehyde, conophthorin, guaiacol, nonanal, methyl salicylate, 4-allylanisole, decanal, thymol methyl ether,
(E)-nerolidol, and dendrolasin. A number of these compounds are known semiochemicals that are active in the behaviour of other
organisms, including bark beetles, suggesting a high degree of semiochemical parsimony. Antennally-active compounds ranged
from seven in A. viridis to 17 in P. trichocarpa. The fewest number of compounds (9) were detected by I. pini and the largest number (24) were detected by D. pseudotsugae. Six compounds excited the antennae of all five species of bark beetles. The large number of antennally-active compounds
detected in common by numerous bark beetles and present in common in numerous nonhost trees supports the hypothesis of olfaction-based
recognition and avoidance of nonhost angiosperm trees during the process of host selection by coniferophagous bark beetles.
Received 13 December 1999; accepted 14 March 2000 相似文献
3.
Ilona Riipinen Jeffrey R. Pierce Neil M. Donahue Spyros N. Pandis 《Atmospheric environment (Oxford, England : 1994)》2010,44(5):597-607
The interpretation of thermodenuder (TD) data often relies on the assumption that thermodynamic equilibrium is reached inside the instrument. We modeled the evaporation of three organic aerosol types (adipic acid, α-pinene SOA and aged OA) inside a thermodenuder with a mass transfer model, and calculated equilibration time scales for these systems at realistic conditions. The equilibrium times varied from less than a second to several hours, decreasing with increasing aerosol concentrations, decreasing particle sizes, decreasing volatilities and increasing mass accommodation coefficients. The results indicate that generally TDs measure particle evaporation rates rather than equilibria, and time-dependent modeling of the evaporation is usually needed to interpret the data. Measurements at varying residence times and temperatures, on the other hand, are desirable to investigate the equilibration of the studied aerosol and decouple the kinetic effects from the effects caused by the thermodynamic properties of the aerosol. Organic aerosol is likely to be further from equilibrium under typical field conditions compared with laboratory data. When determining the aerosol properties from TD data, assuming incorrectly equilibrium results in under-prediction of the vaporization enthalpy of the evaporating species. Similar under-estimation is predicted if multicomponent aerosols are approximated with single-component properties. 相似文献
4.
Charles W. Lewis Robert K. Stevens Reinhold A. Rasmussen Carlos A. Cardelino Thomas E. Pierce 《Journal of the Air & Waste Management Association (1995)》2013,63(3):299-300
ABSTRACT Previously reported volatile organic compounds (VOC) radiocarbon (14C) measurements for 1992 summertime Atlanta, GA, have been compared with chromatographic data and emissions inventory predictions. The chromatographic approach that was used provided a more comprehensive VOC characterization than typically achieved, and the emissions inventory was research-grade level (date-, site-, and time-specific). The comparisons are in general agreement that biogenic emissions contribute only modestly (<10%) to the VOC content of the particular ambient samples that were collected and measured. The choices of sampling site (near city-center) and times (early morning and late evening) are major influences on the results, which consequently should not be regarded as representing the average VOC biogenic impact for the Atlanta area. 相似文献
5.
Davies TD Pierce CE Robinson HJ Dorling SR 《Environmental pollution (Barking, Essex : 1987)》1992,75(2):111-119
The EMEP precipitation composition network is used to examine relationships between non-marine SO4(2-), NO3-, NH4+, H+ concentrations and precipitation amount and a local zonal pressure index (an index of the atmospheric circulation). The pattern of the relationships changes across Europe with the zonal pressure gradient explaining more of the variance in ion concentrations in the west, and precipitation amount explaining relatively more of the variance in the east. There is some predictive capability for precipitation composition in the zonal pressure gradient for restricted regions in Europe; R2 values are up to 40% on a daily basis but in some seasons/months attain >60%. The zonal pressure gradient is an index which appears to include pertinent information on transport and wet removal. Preliminary analysis indicates that this approach can be useful in assessing the contributions of changing atmospheric circulation to time-trends of wet acidic deposition in an area stretching from the UK over the North Sea to Denmark. The zonal pressure gradient is known to have varied on time-scales of decades, and the simple index may be one appropriate approach to assessing future deposition patterns from future climate projections. 相似文献
6.
A global assessment of chromium pollution using sperm whales (Physeter macrocephalus) as an indicator species 总被引:1,自引:0,他引:1
John Pierce Wise Sr. Roger Payne Sandra S. Wise Carolyne LaCerte James Wise Christy Gianios Jr. W. Douglas Thompson Christopher Perkins Tongzhang Zheng Cairong Zhu Lucille Benedict Iain Kerr 《Chemosphere》2009,75(11):1461-1467
Chromium (Cr) is a well-known human carcinogen and a potential reproductive toxicant, but its contribution to ocean pollution is poorly understood. The aim of this study was to provide a global baseline for Cr as a marine pollutant using the sperm whale (Physeter macrocephalus) as an indicator species. Biopsies were collected from free-ranging whales around the globe during the voyage of the research vessel The Odyssey. Total Cr levels were measured in 361 sperm whales collected from 16 regions around the globe detectable levels ranged from 0.9 to 122.6 μg Cr g tissue−1 with a global mean of 8.8 ± 0.9 μg g−1. Two whales had undetectable levels. The highest levels were found in sperm whales sampled in the waters near the Islands of Kiribati in the Pacific (mean = 44.3 ± 14.4) and the Seychelles in the Indian Ocean (mean = 19.5 ± 5.4 μg g−1). The lowest mean levels were found in whales near the Canary Islands (mean = 3.7 ± 0.8 μg g−1) and off of the coast of Sri Lanka (mean = 3.3 ± 0.4 μg g−1). The global mean Cr level in whale skin was 28-times higher than mean Cr skin levels in humans without occupational exposure. The whale levels were more similar to levels only observed previously in human lung tissue from workers who died of Cr-induced lung cancer. We conclude that Cr pollution in the marine environment is significant and that further study is urgently needed. 相似文献
7.
Recycled blocks with improved sound and fire insulation containing construction and demolition waste
Carlos Leiva Jaime Solís-Guzmán Madelyn Marrero Celia García Arenas 《Waste management (New York, N.Y.)》2013,33(3):663-671
The environmental problem posed by construction and demolition waste (C&D waste) is derived not only from the high volume produced, but also from its treatment and disposal. Treatment plants receive C&D waste which is then transformed into a recycled mixed aggregate. The byproduct is mainly used for low-value-added applications such as land escape restoration, despite the high quality of the aggregate. In the present work, the chemical composition properties and grading curve properties of these aggregates are defined. Furthermore, the resulting recycled concrete with a high proportion of recycled composition, from 20% to 100% replacement of fine and coarse aggregate, is characterized physically and mechanically. An environmental study of the new construction material when all aggregates are substituted by C&D waste shows a low toxicity level, similar to that of other construction materials. The new material also has improved properties with respect to standard concrete such as high fire resistance, good heat insulation, and acoustic insulation. 相似文献
8.
Long-term depletion of calcium and other nutrients in eastern US forests 总被引:10,自引:0,他引:10
C. Anthony Federer James W. Hornbeck Louise M. Tritton C. Wayne Martin Robert S. Pierce C. Tattersall Smith 《Environmental management》1989,13(5):593-601
Both harvest removal and leaching losses can deplete nutrient capital in forests, but their combined long-term effects have not been assessed previously. We estimated changes in total soil and biomass N, Ca, K, Mg, and P over 120 years from published data for a spruce-fir site in Maine, two northern hardwood sites in New Hampshire, central hardwood sites in Connecticut and Tennessee, and a loblolly pine site in Tennessee. For N, atmospheric inputs counterbalance the outputs, and there is little long-term change on most sites. For K, Mg, and P, the total pool may decrease by 2%–10% in 120 years depending on site and harvest intensity. For Ca, net leaching loss is 4–16 kg/ha/yr in mature forests, and whole-tree harvest removes 200–1100 kg/ha. Such leaching loss and harvest removal could reduce total soil and biomass Ca by 20%–60% in only 120 years. We estimated unmeasured Ca inputs from rock breakdown, root-zone deepening, and dry deposition; these should not be expected to make up the Ca deficit. Acid precipitation may be the cause of current high leaching of Ca. Although Ca deficiency does not generally occur now in acid forest soils, it seems likely if anthropogenic leaching and intensive harvest removal continue. 相似文献
9.
Barry A. Pierce 《Environmental management》1983,7(2):151-160
Grass carp (Ctenopharyngodon idella Val.) were introduced into the United States in 1963 as potential biological control agents for nuisance aquatic weeds. Since that time an oftentimes bitter controversy has raged over its effects on sportfishing, and its possible natural reproduction and naturalization in North America. This review considers the history, ecology, and present status of grass carp in the United States in light of the voluminous scientific research conducted since its importation. Particular attention is given to the role of grass carp in the fisheries management plans of Arkansas. Recent development of a sterile, triploid grass carp hybrid may lead to widespread use of grass carp to control nuisance aquatic weeds in culturally eutrophicated waters of the United States. 相似文献
10.
Harvey R. Doerksen John C. Pierce 《Journal of the American Water Resources Association》1975,11(5):953-964
ABSTRACT: The desirable proportion of citizen input into policy making and the proper mechanism for that input engender substantial conflict in the water resources arena. Nevertheless, discussions of citizen participation in water policy formation generally occur within narrow perspectives both with regard to the issues involved and the alternative mechanisms by which that participation can be realized. This paper examines the historical and current contexts of the controversies and presents a discussion of the alternative processes for citizen influence - called linkage. The linkage processes discussed include direct participation, citizen advisory committees, the pressure group model, the electoral model and the bureaucratic model. Each linkage process is discussed in terms of who is considered the public, how the public influence works, the limitations of the process, and what available water policy-related data suggest regarding the adequacy of the process. 相似文献