Effects of environmental factors on the production and release of matrix-bound phosphine from lake sediments

Effects of pH, temperature, and oxygen on the production and release of phosphine in eutrophic lake sediments were investigated under laboratory tests. Results indicated that the elimination of matrix-bound phosphine was accelerated under initial pH 1 or 12. Phosphine levels could reach maximum under initial pH 10. The contents of phosphine increased with the addition of alkali under pH 4–12. The rates of phosphine production and release from lake sediments varied with temperature. 20°C was the most favorable temperature for the production of matrix-bound phosphine. Oxygen showed little effect on matrix-bound phosphine. Matrix-bound phosphine concentrations in lake sediments were concluded to be dependent on a balance of natural generation and depletion processes. Translated from Acta Scientise Circumstantiae, 2005, 25(5): 681–685 [译自: 环境科学学报]     

长江上游重庆段近20 a降水时空变化特征

全球气候变暖背景下,中国的降水分布日趋复杂,气象灾害造成的损失巨大。为满足防灾减灾与水资源管理的数据支撑需求,基于长江上游重庆段近20 a降水数据,利用线性回归、M-K非参数检验等方法,探究降水的时间变化趋势与空间分异特征。结果表明：近20 a重庆市年降水量在875.6—1348.2 mm。时间上,春、秋两季呈明显增多的趋势,其中3月最显著。降水在14 a时间尺度的周期过程线中波动最强,是第一主周期。空间分布上,呈西低东高的特点,在渝西和长江河谷地区降水相对偏少,主要受重庆地形的影响;渝西和渝东北地区秋季降水显著增多。研究结果可为长江流域旱涝灾害防治、水资源开发利用及经济社会可持续发展提供数据支撑,同时可为植被修复与生态廊道保障提供参考。     

活性碳纤维改性技术研究进展

介绍了活性碳纤维(ACF)的孔结构及表面官能团,综述了国内外ACF改性技术的研究现状.ACF的改性主要包括孔结构调控和表面化学改性,表面化学改性包括氧化还原法、表面负载法、浸渍法、热处理法、远程等离子体处理法、微波辐照法等,也可将多种方法结合来对ACF进行改性,以改善和提高ACF的吸附性能.在总结现有研究的基础上,对ACF改性技术发展趋势进行了展望.     

缅怀中国环境科学研究院环境基准与风险评估国家重点实验室学术委员会副主任傅家谟院士

正2015年6月11日,中国地球化学学科奠基人、中国科学院院士、中国环境科学研究院环境基准与风险评估国家重点实验室学术委员会副主任傅家谟先生因病医治无效在广州逝世。一位中国环境保护的学术泰斗、有机石油地球化学的奠基人与开拓者,温和可亲的谦谦长者离我们而去。听到这个悲痛的消息,不敢也不愿意相信。我与傅先生相识多年,这位亦师亦友的前辈像父亲一样给予我很多指导、关怀和帮助,回想与傅先生相识的点点滴滴,他满头白发、精神矍铄的音容笑貌仿佛又出现在我的眼前,永远无法忘怀。     

灰色系统模型在总悬浮物预测中的应用

以１９８６－１９９４年东北某城市总悬浮物统计资料为依据，应用灰色系统理论ＧＭ（１，１）模型对总量浮物数值进行预测分析。     

Sulfamethoxazole sorption by sediment fractions in comparison to pyrene and bisphenol A

The environmental behavior of antibiotics has attracted great research attention. However, their sorption mechanisms in soils/sediments are still unknown. Comparison of the sorption properties between the widely-studied hydrophobic organic contaminants (HOCs) and antibiotics may provide valuable insight to antibiotic sorption mechanisms. Thus, in this study batch experiments for pyrene (PYR), bisphenol A (BPA), and sulfamethoxazole (SMX) sorption were conducted on a sediment sample and its separated fractions. Our results showed the high sorption of PYR on black carbon and organic matter. Although high sorption of SMX was observed for both separated organic fractions (humic acids) and inorganic mineral particles, the original sediment particles showed relatively low sorption. Competitive sorption between SMX and dissolved humic acid on mineral particles was observed in this study. This competitive interaction is a unique process for antibiotic sorption in soils/sediments compared with apolar HOCs and may be one of the important factors controlling the antibiotic sorption.     

不同活性组分催化剂的氧化活性和热稳定性

采用流动法催化反应装置测定了蜂窝陶瓷负载催化剂同时催化氧化丙烷 ( C₃H₈)、丙烯 ( c₃H₆)和 CO的活性 ,考察活性组分 Pd和非贵金属氧化物、La改性、反应空速对起燃温度、热稳定性和动力学转化特征的影响 .结果显示 ,含 Pd催化剂上 C₃H₆和 CO的起燃温度比 C₃H₈低 ,1150℃高温老化对 C₃H₈氧化性能的影响比对 C₃H₆和 CO的小 .含稀土非贵金属氧化物的活性、热稳定性及动力学转化性能都比单 Pd催化剂低 ,添加 La能提高 2类催化剂的初活性和高温热稳定性 .     

浅海平台油气火灾事故模拟评估应用

全球海洋油气开发重特大火灾事故频发,油气生产安全面临严峻挑战,以我国浅海某中心平台组为研究对象,对可能发生的三相分离器喷射火火灾、管线交叉处喷射火火灾、生产平台池火火灾以及储罐平台池火火灾,采用FDS软件建立该平台组的火灾动力学模型,对油气泄漏后火灾的发展态势、火场温度、热辐射强度、设备温度以及不同火灾工况的对比分析,研究火灾发生后对人员伤害,以及平台上油气管线、分离器、油气储罐、平台栈桥等重要设备安全性的影响,并提出操作人员和重要设备的安全距离。针对火灾事故风险控制提出建议措施,对海上火灾风险分析未来研究方向进行阐述。     

Characteristics of molecular weight distribution of dissolved organic matter in bromide-containing water and disinfection by-product formation properties during treatment processes

The characteristics of dissolved organic matter (DOM) and bromide ion concentration have a significant influence on the formation of disinfection by-products (DBPs). In order to identify the main DBP precursors, DOM was divided into five fractions based on molecular weight (MW), trihalomethane formation potential and haloacetic acid formation potential were determined for fractions, and the change in contents of different fractions and total DBPs during treatment processes (pre-chlorination, coagulation, sand filtration, disinfection) were studied. Moreover, the relationship between bromide concentration and DBP generation characteristics in processes was also analyzed. The results showed that the main DBP precursors were the fraction with MW < 1 kDa and fraction with MW 3−10 kDa, and the DBP''s generation ability of lower molecular weight DOM (< 10 kDa) was higher than that of higher molecular weight DOM. During different processes, pre-chlorination and disinfection had limited effect on removing organics but could alter the MW distribution, and coagulation and filtration could effectively remove organics with higher MW. For DBPs, trihalomethanes (THMs) were mainly generated in pre-chlorination and disinfection, while haloacetic acids (HAAs) were mostly generated during pre-chlorination; coagulation and sand filtration had little effect on THMs but resulted in a slight removal of HAAs. In addition, the results of ANOVA tests suggested that molecular sizes and treatment processes have significant influence on DBP formation. With increasing bromide concentration, the brominated DBPs significantly increased, but the bromine incorporation factor in the processes was basically consistent at each concentration.     

基于环境保护大数据的监测与智能诊断研究

为了提高环境保护的智能监测能力,采用大数据分析方法进行环境监测和诊断分析,提出一种基于环保大数据关联特征挖掘的环境保护智能监测与诊断技术。构建环境监测的约束参量模型,以土壤监测数据、空间污染排放量以及水资源监测数据为原始统计数据,采用关联规则特征提取方法进行环保大数据的有用信息挖掘,结合模糊C均值聚类算法实现对环保大数据的分类处理,根据分类结果进行环保监测和智能诊断分析。仿真结果表明,采用该方法进行环保大数据挖掘的准确性较好,对各种污染信息的分类精度较高,提高了环保监测和诊断的有效性与实时性。