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排序方式: 共有98条查询结果,搜索用时 15 毫秒
1.
Martin A. Cohen P. Barry Ryan Yukio Yanagisawa John D. Spengler Halûk Özkaynak Paul S. Epstein 《Journal of the Air & Waste Management Association (1995)》2013,63(8):1086-1093
The Kanawha Valley region of West Virginia which is comprised of Charleston and surrounding communities Is the center of a heavily industrialized area known for its chemical manufacturing. As part of a larger study designed to investigate the Impact of the chemical industry on human exposures to volatile organic compounds (VOC), a study of the relationship between indoor and outdoor concentrations was conducted. Thirty-five homes were selected for monitoring from among volunteers; approximately ten in each of three distinct population-industry centers and four outside the Valley to act as controls. Monitoring was performed using passive, badge samplers with a three-week monitoring period. Two separate questionnaires were administered: one for characterization of the residence; and one to characterize source use during monitoring. Participants were also asked to keep a record of their activities with respect to in-home, outdoors and other Indoor environments. Analysis of the samplers was performed by solvent extraction followed by gas chromatography using a flame-ionization detector. Results suggest that indoor VOC concentrations are higher than outdoor concentrations. Additionally, certain ventilation-related parameters were identified that afforded some predictive power for indoor concentrations. No statistically significant differences between regions were identified. 相似文献
2.
Kikuo Oikawa Hiroko Saito Ikuei Kifune Tatsuo Ohshina Masami Fujii Yukio Takizawa 《Chemosphere》1982,11(9):943-951
To study atmospheric mercury absorption in human respiratory passage-ways, mercury in expired air was measured in three different states of breathing: steady breathing, deep breathing and breath held after inspiration.In this study, air containing mercury was inhaled through the nose and expired through the mouth. The concentration of mercury in the exhaled air was determined by the technique of gold-amalgam trapping, heat vaporization, and flameless atomic absorption measurement.The subjects were 13 male adults, aged 25–62 years, and 38 cases were observed. Four different concentrations of mercury, 1–3, 4–6, 10–11, and 20–30 μg/m3 were used, and absorption for each was determined. When the concentration was 1–3 μg/m3, the absorption was 74–92%, the average being 82.5%. At concentrations of 4–6, 10–11, and 20–30 μg/m3, the absorption was 76.6–100%, 75.5–99.2%, and 79.9–95.9% respectively, and the average was 88.8%, 85.2%, and 87.7% respectively.A slightly higher rate of mercury absorption was observed in deep breathing than in steady breathing, and when expiration was suppressed for some time after inspiration, the rate increased remarkably to 97.4–99.7%. Prolonged retention of inhaled air containing mercury in the respiratory tract is believed to have caused the increased absorption. 相似文献
3.
Air pollution and young children's inhalation exposure to organophosphorus pesticide in an agricultural community in Japan 总被引:1,自引:0,他引:1
Kawahara J Horikoshi R Yamaguchi T Kumagai K Yanagisawa Y 《Environment international》2005,31(8):1123-1132
Assessment of airborne organophosphorus pesticides in houses of young children (1-6 years old) and childcare facilities was conducted following pesticide applications in an agricultural community in Japan. Trichlorfon and fenitrothion, applied in two separate periods, were frequently detected from outdoor and indoor air. Dichlorvos, the primary degradation product of trichlorfon, was also detected after the application of trichlorfon. Both the outdoors and indoor concentration of applied pesticide were shown to increase with decreasing distance from the pesticide-applied farm. Indoor concentration of these pesticides significantly correlated with outdoor concentration (p=0.001 for trichlorfon and p=0.001 for fenitrothion), indicating infiltration of applied pesticide inside. Ratio of indoor to outdoor concentration (I/O ratio) of fenitrothion was higher for houses with windows open during the application than those with closed windows (median value: 0.74 vs. 0.16, p=0.003). However, a similar trend was not observed for trichlorfon as well as dichlorvos in the first period. Dichlorvos was found to have a higher I/O ratio than trichlorfon during the period, and clear correlation between indoor concentrations of dichlorvos and those of trichlorfon suggested increased decomposition of trichlorfon in the indoor environment. Daily inhalation exposure estimated by using the fixed measurement data and time-activity questionnaire ranged from 0 to 35 ng/kg/day for trichlorfon, from 0 to 26 ng/kg/day for dichlorvos, and from 0 to 44 ng/kg/day for fenitrothion. Median inhalation exposure from indoor air accounted for 74%, 86.3%, and 45% of the daily inhalation exposure, respectively. For kindergarteners or nursery school children, inhalation exposure at childcare facilities was comparable with or more than that at home, indicating that pollution level at childcare facilities had potential of high impact on children's exposure. Estimated daily inhalation exposures were inversely correlated to the proximity of their activity location to the pesticide-applied farm. 相似文献
4.
Takashi Yamamoto Yasufumi Kai Hiroaki Nakauchi Toshiaki Abuku Yukio Noma 《Environmental science and pollution research international》2014,21(12):7557-7566
A series of treatment experiments were carried out to evaluate the applicability of a high-temperature melting treatment (GeoMelt process) to the destruction of polychlorinated naphthalene (PCN) formulation. We started with 10-kg-scale experiments in which a small melting furnace was used and then scaled up to a 1-t-scale experiment in which a melting furnace that resembled an actual treatment system was used. These runs were evaluated whether destruction efficiency (DE) of total PCNs was more than 99.999 % and whether concentrations of PCNs and polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/DFs) in vitrified materials, emission gas, and scrubber water were below the target levels. Because DE values and the target levels of PCNs and PCDDs/DFs in these runs were satisfactory, then we carried out a demonstrative experiment using the actual treatment system and confirmed destruction of PCNs. Based on good results of the demonstrative experiment, stock of PCN formulation was successfully treated continuously. 相似文献
5.
Wayfinding with a GPS-based mobile navigation system: A comparison with maps and direct experience 总被引:2,自引:0,他引:2
Toru Ishikawa Hiromichi Fujiwara Osamu Imai Atsuyuki Okabe 《Journal of environmental psychology》2008
This study examined the effectiveness of a Global Positioning System (GPS)-based mobile navigation system in comparison to paper maps and direct experience of routes, by focusing on the user's wayfinding behavior and acquired spatial knowledge. Based on information received from one of these three media, participants walked six routes finding the way to goals. Results showed that GPS users traveled longer distances and made more stops during the walk than map users and direct-experience participants. Also, GPS users traveled more slowly, made larger direction errors, drew sketch maps with poorer topological accuracy, and rated wayfinding tasks as more difficult than direct-experience participants. Characteristics of navigation with these three learning media and possible reasons for the ineffectiveness of the GPS-based navigation system are discussed. 相似文献
6.
When using stable enzyme genes from a thermophile to create a biosensor in Escherichia coli, it is vital that these genes be overexpressed in order to provide a sufficient supply of enzymes. In this study, overexpression of the NADH oxidase (Nox) gene from the thermophile Deinococcus geothermalis was successfully achieved with the aim of creating a stable biosensor active at room temperatures. To do so, modification of 10 nucleotides, GAAATTAACT, upstream of the start codon of the Nox gene was necessary. 相似文献
7.
DNA damage is an important step in carcinogenesis. The Ames assay is a short-term screening of carcinogens that induce DNA damage. Most carcinogens require enzymatic activation through oxidation by cytochrome P450 (CYP450) in the presence of S9 mix. A combination of iron (Fe)(III) porphyrin and an oxidant is also able to oxidize compounds as an alternative metabolic pathway to CYP450. Previously it was reported that a chemical model containing a water-soluble 5,10,15,20-tetrakis(1-methylpyridinium4-yl)porphyrinatoiron(III) chloride (4-MPy) and tert-butyl hydroperoxide (t-BuOOH) activated aromatic amines and amides. In this study, a chemical model composed of an Fe porphyrin, water-insoluble 5,10,15,20-tetrakis(pentafluorophenyl)porphyrinatoiron(III) chloride (F5P) or water-soluble 4-MPy was optimized with an oxidant – t-BuOOH, magnesium monoperoxyphthalate (MPPT), or iodosylbenzene (PhIO). Subsequently the mutagenicity of benzo[a]pyrene (B[a]P) and chrysene in Salmonella typhimurium TA strains was compared. B[a]P was activated by a combination of F5P or 4-MPy plus MPPT or PhIO in S. typhimurium TA1538. The B[a]P-induced mutagenicity with F5P plus oxidant was higher than 4-MPy plus oxidant. Mutagenicity of chrysene, a tetracyclic aromatic hydrocarbon, was not detected in the presence of F5P/PhIO in S. typhimurium TA98, but was activated in the presence of F5P/MPPT. The F5P/MPPT activated other polyaromatic hydrocarbons (PAH) in the S. typhimurium TA98 assay including dibenz[a,c]anthracene, dibenz[a,h]anthracene, 3-methylcholanthrene, and benzo[a]anthracene. The results indicated that the F5P/MPPT was the most efficient model for detecting PAH-induced mutagenicity in the Ames assay. 相似文献
8.
A badge-type personal sampler was developed for measuring personal exposure to nitrogen dioxide (NO2). An absorbent sheet containing triethanolamine (TEA) solution absorbed NO2 which diffused through five layers of hydrophobic fiber filter. Wind effects on absorption rate were suppressed by these filter layers. NO2 was measured by the sampler with a sensitivity of 124.8 μg h/m3 (66 ppb h) and an accuracy of within ± 20%. It could be used for measuring personal exposure to NO2 without interfering with the wearer's daily activities. Nitric oxide (NO) could be measured after a small modification to the sampler provided oxidation ability to the layers of diffusion filter. Three layers of hydrophobic fiber filter were replaced by 12 layers of glass fiber filter containing chromium trioxide solution. NO was oxidized to NO2 in the oxidation layers and absorbed by the absorbent sheet together with the coexisting NO2. Sensitivity and accuracy of the sampler for NO were nearly equal to that for NO2. 相似文献
9.
Takashi Yamamoto Atsushi Ohara Yukio Noma Katsushi Nishizawa Akio Yasuhara Shin-ichi Sakai 《Journal of Material Cycles and Waste Management》2007,9(2):188-193
The photodegradation of tetraphenyltin (TePT) contained in polychlorinated biphenyl (PCB)-based transformer oil simulants
by ultraviolet (UV) irradiation in alkaline 2-propanol solutions was examined. In the absence of PCBs, the TePT level fell
to below 1% of the initial concentration within 30 min. In the absence of both PCBs and an alkali, the concentrations of tri-,
di-, and monophenyltins initially increased to a few milligrams per liter, and then reduced to below the detection limits
within 90 min. The addition of an alkali to the reaction solution slightly accelerated the photodecomposition of TePT. The
decomposition of other phenyltins (PTs) was also accelerated. When PCBs with concentrations of approximately 80 times the
initial TePT concentration were added, only a small fraction of the TePT decomposed within 100 min. Moreover, the levels of
PTs did not change during irradiation. TePT and other PTs did decompose when the level of PCBs was reduced to the same concentration
as that of TePT; however, the decomposition rates were slower than those in the absence of PCBs. In the actual treatment process,
TePT and other PTs in PCB-based transformer oil are decomposed by catalytic reduction, which is used after UV irradiation.
Therefore, in the actual treatment of PCB-based transformer oil wastes, pollution due to PTs can be prevented. 相似文献
10.
To examine whether tree rings can be used to detect or assess local historical 90Sr or 137Cs fallout, such as that resulting from the Hiroshima atomic bomb, radial distribution of 90Sr and 137Cs in trees was examined. We studied a gymnosperm [Japanese cedar, Cryptomeria japonica (L. f.) D. Don] and an angiosperm (Japanese persimmon, Diospyros kaki Thunb.) tree species from the vicinity of the atomic bomb hypocenter, and from other locations in Japan. A significant amount of 137Cs was detected in tree rings formed before 1945, indicating lateral migration of Cs. In contrast, the specific activity of 90Sr in the Hiroshima Japanese cedar showed the highest level in 1945, due to relatively immobile characteristics of Sr compared with Cs. Strontium-90 and Sr analyses in tree rings helped identify and distinguish between residual 90Sr activity from the Hiroshima atomic bomb and the atmospheric nuclear testing. This indicates the possibility of detecting or assessing previous local 90Sr pollution through with treering analysis. 相似文献