A minimum data set of water quality parameters to assess and compare treatment efficiency of stormwater facilities

Urban stormwater runoff is often of poor quality, impacting aquatic ecosystems and limiting the use of stormwater runoff for recreational purposes. Several stormwater treatment facilities (STFs) are in operation or at the pilot testing stage, but their efficiencies are neither well documented nor easily compared due to the complex contaminant profile of stormwater and the highly variable runoff hydrograph. On the basis of a review of available data sets on urban stormwater quality and environmental contaminant behavior, we suggest a few carefully selected contaminant parameters (the minimum data set) to be obligatory when assessing and comparing the efficiency of STFs. Consistent use of the minimum data set in all future monitoring schemes for STFs will ensure broad-spectrum testing at low costs and strengthen comparability among facilities. The proposed minimum data set includes: (i) fine fraction of suspended solids (<63 μm), (ii) total concentrations of zinc and copper, (iii) total concentrations of phenanthrene, fluoranthene, and benzo(b,k)fluoranthene, and (iv) total concentrations of phosphorus and nitrogen. Indicator pathogens and other specific contaminants (i.e., chromium, pesticides, phenols) may be added if recreational or certain catchment-scale objectives are to be met. Issues that need further investigation have been identified during the iterative process of developing the minimum data set.     

Application of processed organic municipal solid waste on agricultural land – a scenario analysis

Source separation, composting and anaerobic digestion, with associated land application, are increasingly being considered as alternative waste management strategies to landfilling and incineration of municipal solid waste (MSW). Environmental life cycle assessments are a useful tool in political decision-making about waste management strategies. However, due to the diversity of processed organic MSW and the situations in which it can be applied, the environmental impacts of land application are very hard to determine by experimental means. In the current study, we used the agroecosystem model Daisy to simulate a range of different scenarios representing different geographical areas, farm and soil types under Danish conditions and legislation. Generally, the application of processed organic MSW resulted in increased emissions compared with the corresponding standard scenarios, but with large differences between scenarios. Emission coefficients for nitrogen leaching to the groundwater ranged from 0.03 to 0.87, while those for nitrogen lost to surface waters through tile drains ranged from 0 to 0.30. Emission coefficients for N₂O formation ranged from 0.013 to 0.022 and for ammonia volatilization from 0.016 to 0.11. These estimates are within reasonable range of observed values under similar conditions. Furthermore, a sensitivity analysis showed that the estimates were not very sensitive to the mineralization dynamics of the processed organic MSW. The results show that agroecosystem models can be powerful tools to estimate the environmental impacts of land application of processed MSW under different conditions. Despite this, agroecosystem models have only been used to a very limited degree for this purpose.     

Interactions between soil texture and placement of dairy slurry application: II. Leaching of phosphorus forms

Managing phosphorus (P) losses in soil leachate folllowing land application of manure is key to curbing eutrophication in many regions. We compared P leaching from columns of variably textured, intact soils (20 cm diam., 20 cm high) subjected to surface application or injection of dairy cattle (Bos taurus L.) manure slurry. Surface application of slurry increased P leaching losses relative to baseline losses, but losses declined with increasing active flow volume. After elution of one pore volume, leaching averaged 0.54 kg P ha(-1) from the loam, 0.38 kg P ha(-1) from the sandy loam, and 0.22 kg P ha(-1) from the loamy sand following surface application. Injection decreased leaching of all P forms compared with surface application by an average of 0.26 kg P ha(-1) in loam and 0.23 kg P ha(-1) in sandy loam, but only by 0.03 kg P ha(-1) in loamy sand. Lower leaching losses were attributed to physical retention of particulate P and dissolved organic P, caused by placing slurry away from active flow paths in the fine-textured soil columns, as well as to chemical retention of dissolved inorganic P, caused by better contact between slurry P and soil adsorption sites. Dissolved organic P was less retained in soil after slurry application than other P forms. On these soils with low to intermediate P status, slurry injection lowered P leaching losses from clay-rich soil, but not from the sandy soils, highlighting the importance of soil texture in manageing P losses following slurry application.     

Interactions between soil texture and placement of dairy slurry application: I. Flow characteristics and leaching of nonreactive components

Land application of manure can exacerbate nutrient and contaminant transfers to the aquatic environment. This study examined the effect of injecting a dairy cattle (Bostaurus L.) manure slurry on mobilization and leaching of dissolved, nonreactive slurry components across a range of agricultural soils. We compared leaching of slurry-applied bromide through intact soil columns (20 cm diam., 20 cm high) of differing textures following surface application or injection of slurry. The volumetric fraction of soil pores >30 microm ranged from 43% in a loamy sand to 28% in a sandy loam and 15% in a loam-textured soil. Smaller active flow volumes and higher proportions of preferential flow were observed with increasing soil clay content. Injection of slurry in the loam soil significantly enhanced diffusion of applied bromide into the large fraction of small pores compared with surface application. The resulting physical protection against leaching of bromide was reflected by 60.2% of the bromide tracer was recovered in the effluent after injection, compared with 80.6% recovery after surface application. No effect of slurry injection was observed in the loamy sand and sandy loam soils. Our findings point to soil texture as an important factor influencing leaching of dissolved, nonreactive slurry components in soils amended with manure slurry.     

Chemical and microbiological examination of well and Nile water

The chemical composition and microbiological contamination of well water and Nile River water used for drinking were investigated in localities around Khartoum, Sudan, to present baseline data. The chemical analyses results obtained indicated that public health hazards due to pH, Ca⁺⁺, CO₃^??, HCO₃^?, and NO₃^? are unlikely in all the samples studied, while Na⁺ and Cl^? ions concentrations in well water warrant some attention. Contamination from organic matter and suspended material is also negligible. Microbial contamination with coliform and fecal coliform is high in surface wells and in the Nile River, but negligible in deep bores, tap water, and mineral water. The logarithm of the colony count ranges from zero for mineral water to 6.8 for water from the White Nile. In addition to drawing further attention to the well water and Nile water used for drinking by a wide sector of the population, the microbial count data for water from the Nile disagreed with the generally held belief that the Nile, being one of the largest rivers of the world, carries no detectable fecal contamination. Our data also did not support the belief that the White Nile is more contaminated than the Blue Nile.     

Carbon, nitrogen, and phosphorus distribution in particle size-fractionated separated pig and cattle slurry

Solid liquid separation of animal slurry is a method to reduce the excess nutrient loads from intensive livestock production. Five different separation technologies (sedimentation, centrifugation, pressurized filtration, polymer flocculation and drainage, and iron chloride addition + polymer flocculation and drainage) were applied to pig and cattle slurry in a laboratory study. Separation efficiencies of mass, dry matter (DM), N, and P were measured. Particle size fractionation of the solid fractions was performed by subjecting them to wet fractionation and C, organic N (N(org)), and P contents were subsequently measured. Chemical pretreatment with polymer before gravity drainage separated DM, total N, and P from raw pig and cattle slurry with the highest efficiencies. Sedimentation and centrifugation separated P from pig and cattle slurries with higher simple separation efficiencies (0.77 and 0.70, respectively) compared with pressurized filtration (0.15 and 0.37). Pressurized filtration transferred the lowest masses (14 and 18%) to the solid fractions. Solid fractions from pig slurry generally contained higher concentrations of P and C compared with cattle slurry solid fractions. The majority of C in solid fractions was present in particles > 25 microm, whereas N and P were present in larger proportions in particles < 25 microm. Chemical pretreatment increased the capture of smaller N(org)- and P-rich particles into larger particles between 25 and 1000 microm.     

The dilemma of a low rate of chromosomal mosaicism found in fetal blood sampling

We report a case in which mosaicism of trisomy 13 was detected in 4/10 cells (40 per cent) in amniotic fluid cell cultures, followed by a low rate of mosaicism (1/160 cells) detected in a fetal blood sample. This finding presents a dilemma both for the genetic counsellor and for the parents in determining whether or not to terminate the pregnancy.     

Modelling C and N mineralization during decomposition of anaerobically digested and composted municipal solid waste.

Application of municipal solid waste (MSW) to arable land can be used to close the nutrient cycle between urban and rural areas. The aim of the current study was to quantify net N mineralization and respiration from composted MSW (CMSW) and anaerobically digested MSW (ADMSW) applied to soil, and to test whether a simple relationship between net N mineralization and respiration that was developed for plant materials, was applicable for these types of MSW. In a laboratory experiment, CMSW and ADMSW were incorporated into soil and incubated at 15 degrees C. During the 149-day experiment, netN mineralization and respiration were determined. Cumulative respiration derived from both MSW types was very steep during the first 30 days, after which it levelled off. However, calculated on the basis of applied C, the ADMSW was 10 times more degradable than the CMSW. Both MSW types caused initial net N immobilization followed by re-mineralization. A simple model based on the relationship between net N mineralization and respiration was only applicable for the MSW after significant modifications. If farmers are to recognize CMSW and ADMSW as valuable fertilizers, it is important that they can be produced with higher maturity, in order to avoid initial N immobilization.     

pH-dependent release of cadmium,copper, and lead from natural and sludge-amended soils

The pH-dependent release of cadmium, copper, and lead from soil materials was studied by use of a stirred flow cell to quantify their release and release rates, and to evaluate the method as a test for the bonding strength and potential mobility of heavy metals in soils. Soil materials from sludge-amended and nonamended A horizons from a Thai coarse-textured Kandiustult and a Danish loamy Hapludalf were characterized and tested. For each soil sample, release experiments with steady state pH values in the range 2.9 to 7.1 and duration of 7 d were performed. The effluent was continuously collected and analyzed. Release rates and total releases were higher for the Hapludalf than the Kandiustult and higher for the sludge-amended soils than the nonamended soils. With two exceptions the relative release rates (release rate/total content of metal in soil) plotted vs. steady state pH followed the same curves for each metal, indicating similar bonding strengths. These curves could be described by a rate expression of the form: relative release rate = k[H+]a, with specific a (empirical constant) and k (rate constant) parameters for each metal demonstrating that metal release in these systems can be explained by proton-induced desorption and dissolution reactions. With decreasing pH, pronounced increases in release rates were observed in the sequence cadmium > lead > copper, which express the order of metal lability in the soils. The flow cell system is useful for comparison of metal releases as a function of soil properties, and can be used as a test to rank soils with respect to heavy metal leaching.     

A review of the cost and effectiveness of solutions to address plastic pollution

Environmental Science and Pollution Research - Plastic usage increases year by year, and the growing trend is projected to continue. However as of 2017, only 9% of the 9 billion tons of plastic...