Public Perception of Flood Hazard in the Niger Delta,Nigeria

Summary Our study had the aim of understanding how floodplain dwellers regard the risk of flooding. About 500 questionnaires were administered to landowners in the selected settlements in the study area using systematic random sampling. The results of analysis show, among other things, that the population regards most important the causes of floods as heavy, prolonged rainfall and river overflow. Nevertheless, they have little knowledge of the frequency of severe floods, and flood alleviation schemes. Most flood victims do not get compensation or relief during flood disaster, and the reason why they remain in the study area is influenced by their occupations, especially fishing, subsistence agriculture, and the presence of crude oil in the region which has attracted many migrants who cannot afford the high cost of accommodation and are therefore forced to live in vulnerable areas of the floodplain. Finally, the study concludes that flood control in the region needs the cooperation of government, community efforts and an enlightenment programmes through environmental education and mass media.     

Consequences of Pollution and Degradation of Nigerian Aquatic Environment on Fisheries Resources

Throughout the world, human use of water, and bad planning have led to drier and polluted rivers, lakes, and groundwater resources with dramatic effects on the natural ecosystems. Nigeria's vast freshwater resources are among those most affected by environmental stress imposed by human population growth, urbanization, and industrialization. Disposal and management of wastes in Nigeria present serious environmental problems. The usual methods of waste disposal in the country are: land filling, dumpsites, land spreads, water disposal, and incineration. Each of these methods has serious environmental implications because of their potential to pollute and contaminate underground and surface water bodies in the country. Major cities in Nigeria face serious water pollution crises, in which lack of environmental control of water-dependent activities (including domestic, agricultural, and industrial) play an important part. Fish and marine resources in the country face total collapse or extinction, due to over-fishing and destruction of marine life and natural habitats by pollution of water bodies. Unregulated and excessive use of pesticides for fishing and the deliberate disposal and dumping of toxic and hazardous wastes into water bodies are significant causes of massive fish kills and loss of aquatic life and habitats in the country. The protection of water quality and aquatic ecosystem as a vulnerable resource, essential to sustain life, development and environment is of utmost importance to prevent further pollution and degradation of Nigeria's freshwater resources. Integrating operational measures for safeguarding adequate levels of protection of endemic habitats remains a major challenge. There is therefore a need to examine in tandem the entire range of uses to which freshwater is put, and to design services which neither squander precious resources nor fail to respect other, competing and complementary water needs.This paper attempts to provide an overview of the Nigerian freshwater resources, to assess the pollution status of inland waters, identify the sources of pollution, and infer the consequent effect on fisheries resource. Recommendations were proffered on the strategies to employ to ensure that Nigerian fishery resources are adequately managed in order to address the issue of food security.     

Metal organic frameworks as adsorbents for dye adsorption: overview,prospects and future challenges

Considering the amount of colored waste water generated from many industries (textile, leather, paper, printing, dyestuff, and plastic) that are sent to various water bodies and the ecosystem, the search for efficient and better methods of purification still continues. With the recent research into metal organic frameworks (MOFs), there is a steady growing interest worldwide for their various applications. This article presents a review of MOFs, their application in dye adsorption and their various challenges and future prospects. It was concluded that with the current interest, research and development for various applications, there are possibilities which will bring to limelight more laboratory, industrial and environmental usage of MOFs as dye adsorbents.     

Domestic energy usage and its' health implications on residents of the Ese‐Odo and Okitipupa local government areas of Ondo state,Nigeria

This study examined domestic energy usage and its health implication on residents of Ese‐Odo and Okitipupa Local Government Areas (LGA), of Ondo State. Systematic random sampling was used to select 103 and 156 respondents in Ese‐Odo and Okitipupa LGA, respectively. It was established that environmental and socio‐economic related attributes influenced residents' choice of domestic energy type. Similarly, burns, blindness, stroke, cataract and pulmonary diseases were the most prevalent self‐reported ill‐health. A relatively weak correlation between domestic energy usage and ill‐health is experienced by the residents. Therefore, the study concluded that the use of traditional energy types had significant adverse effects on the health of the residents in Okitipupa and Ese‐Odo LGAs of Ondo State.     

Effect of salinity on survival and growth of blue crab, Callinectes amnicola from Lagos Lagoon, Nigeria

The effect of salinity on the survival and growth of Callinectes amnicola (De Rocheburne) from the Lagos Lagoon, Nigeria was monitored in the laboratory for 22 weeks. The crabs were euryhaline and tolerated a salinity range of 5 to 25 per thousand and had 90% survival at 15 and 20 per thousand. The highest gain in weight (173.0%) and carapace width (56.1%) was obtained at salinity of 15 per thousand. The highest specific growth rate (1.98) was obtained at 15 per thousand, while the lowest specific growth rate (-0.28) was recorded at 35 per thousand. The condition factor of the crabs showed a fairly consistent pattern at the different salinity levels with values ranging from 5.7 to 7.3. Complete moulting was obtained at salinity of 15 per thousand in the 12th week of the experiment. The crab with carapace width of 6.8 cm increased to 8.1 cm (19.1%) after moulting.     

Capture of carbon dioxide from flue or fuel gas mixtures by clathrate crystallization in a silica gel column

A column of silica gel was employed to contact water with flue gas (CO₂/N₂) mixture to assess if CO₂ can be separated by hydrate crystallization. Three different silica gels were used. One with a pore size of 30 nm (particle size 40–75 μm) and two with a pore size of 100 nm and particle sizes of 40–75 and 75–200 μm respectively. The observed trends indicate that larger pores and particle size increase the gas consumption, CO₂ recovery, separation factor and water conversion to hydrate. Thus, the gel (gel #3) with the larger particle size and larger pore size was chosen to carry out experiments with concentrated CO₂ mixtures and for experiments in the presence of tetrahydrofuran (THF), which itself is a hydrate forming substance. Addition of THF reduces the operating pressure in the crystallizer but it also reduces the gas uptake. Gel #3 was also used in experiments with a fuel gas (CO₂/H₂) mixture in order to recover CO₂ and H₂. It was found that the gel column performs as well as a stirred reactor in separating the gas components from both flue gas and fuel gas mixtures. However, the crystallization rate and hydrate yield are considerably enhanced in the former. Finally the need for stirring is eliminated with the gel column which is enormously beneficial economically.     

Multifunctional metal-organic frameworks in oil spills and associated organic pollutant remediation

The release of toxic organic compounds into the environment in an event of oil spillage is a global menace due to the potential impacts on the ecosystem. Several approaches have been employed for oil spills clean-up, with adsorption technique proven to be more promising for the total reclamation of a polluted site. Of the several adsorbents so far reported, adsorbent-based porous materials have gained attention for the reduction/total removal of different compounds in environmental remediation applications. The superior potential of mesoporous materials based on metal–organic frameworks (MOFs) against conventional adsorbents is due to their intriguing and enhanced properties. Therefore, this review presents recent development in MOF composites; methods of preparation; and their practical applications towards remediating oil spill, organic pollutants, and toxic gases in different environmental media, as well as potential materials in the possible deployment in reclaiming the polluted Niger Delta due to unabated oil spillage and gas flaring.

     

Fractionation and ecotoxicological implication of potentially toxic metals in sediments of three urban rivers and the Lagos Lagoon,Nigeria, West Africa

The potential environmental impact of sediment-bound Cd, Cr, Cu, Pb and Zn in three trans-urban rivers in Lagos state and in the Lagos Lagoon was assessed by use of the modified Community Bureau of Reference (BCR) sequential extraction. The quality of the data was checked using BCR CRM 143R and BCR CRM 701. Good agreement was obtained between found and certified/indicative values. Of the rivers, the Odo-Iyaalaro, was generally the most contaminated and the Ibeshe the least. Higher concentrations of metals were generally found in the dry season compared to the wet season. Cadmium and Zn were released mostly in the acid exchangeable step of the sequential extraction, indicating that they have the greatest potential mobility and bioavailability of the analytes studied. Chromium and Cu were associated mainly with the reducible and oxidisable fractions, and Pb predominantly with the reducible and residual fractions. Sediments with the highest pseudototal analyte concentrations also released higher proportions of analytes earlier in the sequential extraction procedure. The study suggests that, during the dry season, potentially toxic metals (PTM) may accumulate in sediments in relatively labile forms that are released and can potentially be transported or bioaccumulate in the rainy season. Application of risk assessment codes and Hankanson potential risk indices indicated that Cd was the element of greatest concern in the Lagos Lagoon system. The study indicated that there is a need to strengthen environmental management and pollution control measures to reduce risk from PTM, but that even relatively simple strategies, such as seasonal restrictions on dredging and fishing, could be beneficial.     

Comparison of three sequential extraction protocols for the fractionation of potentially toxic metals in coastal sediments

In the determination of the best sequential extraction procedures (SEP) for the speciation of metals in sediment samples from the Lagos lagoon system, three sequential extraction procedures were compared for the fractionation of Cd, Cr, Cu, Pb, and Zn. The SEP compared included a modified Tessier??s procedure carried out in five steps, while the two other procedures were the three-step original Community Bureau of Reference (BCR) and the modified BCR techniques (four steps). Quantification of the metal concentration was achieved with a flame atomic absorption spectrophotometer. The results obtained by the three methods were compared, and the modified BCR and Tessier SEP were found to extract more Cu, Cr, Pb, and Zn in the reducible phase and therefore a decrease in the oxidizable phase than the original BCR SEP. The most mobile elements were found to be Cd, Pb, and Zn. These are of environmental concern, as these potentially toxic metals could be easily released into the aquatic environment with consequent ingestion by aquatic organisms, thereby entering the food chain. The mass balance (percent recovery) was found to be between 85% and 115% in most cases. Prior to the comparison, the analytical performance of the laboratory was tested using a secondary reference material, GLAURM, using the three-step modified BCR procedure. The results showed high reliability of the analytical performance of the laboratory for all the metals considered.