Environmental assessment of dehydrated alfalfa production in Spain

Alfalfa is the major forage crop produced in temperate regions worlwide. Although this crop is currently used mainly for producing high-value livestock feed, its application for bioenergy production is a recent focus of interest. Even though it is not mandatory, alfalfa is normally dried in order to improve the quality of the final product. In this study, Life Cycle Assessment (LCA) was used to quantify the environmental impacts linked to alfalfa production in the major cultivation zone in Spain (Ebro Valley), including field activities, dehydration and transport to farms for livestock feeding. In addition, the identification of the most relevant processes contributing to the environmental impact and the potential improvements actions were also defined as objectives. Inventory data were obtained mainly from interviews with farmers complemented with published literature and comments from experts.LCA results were obtained for global warming, acidification, eutrophication, photochemical oxidant formation, land use, non-renewable cumulative energy demand and human, terrestrial and aquatic ecotoxicities. Within the life cycle of alfalfa, the dehydration process, production of phosphate fertilizer, application of nitrogen fertilizers and pesticides, water consumption and final transport to the consumer (by road and ship) were identified as hot spots. Based on these, some improvement measures were proposed and evaluated: (i) reduction of the moisture content of alfalfa and the use of a higher percentage of biomass for combustion in the dehydration process, (ii) no application of nitrogen fertilizer in maintenance years and (iii) use of more efficient trucks for transport. Their implementation would produce significant reduction of eutrophication, global warming, acidification, non-renewable cumulative energy demand and, to a lesser extent, photochemical oxidation formation and human toxicity impacts.     

An analytical solution of the advection-diffusion equation considering non-local turbulence closure

Atmospheric air pollution turbulent fluxes can be assumed to be proportional to the mean concentration gradient. This assumption, along with the equation of continuity, leads to the advection-diffusion equation. Moreover, large eddies are able to mix scalar quantities in a manner that is counter to the local gradient. We present a general solution of a two-dimension steady state advection-diffusion equation, considering non-local turbulence closure using the General Integral Laplace Transform Technique. We show some examples of applications of the new solution with different vertical diffusion parameterisations.     

Study of the dynamics of estuarine and coastal waters using remote sensing: the Tinto-Odiel estuary, SW Spain

This paper deals with the application of satellite images to characterize some aspects of the circulation dynamics of the Tinto-Odiel estuary using turbidity patterns as ‘natural tracers’. 15 images (Landsat TM and Spot HRV) were processed to provide synoptic, instantaneous views of the circulation patterns under different environmental conditions. In addition, a comparison was made between results of oceanographic field work, using biplanes and fluorescent tracers, and satellite image turbidity patterns used as ‘ground truth’ data for specific hydroclimatic situations. This approach allowed (1) the identification and mapping of dynamic processes of interest during a theoretical tidal cycle, (2) the elaboration of additional information on the ‘flow schemes’ at the mouth of the estuary with improved spatial and temporal resolution, and (3) the supply of basic data to improve the knowledge of exchange processes between estuarine and coastal waters. The results of this study are considered to be useful for the management of the estuarine system.     

Trace Element Contaminants in Sediments From the Noaa National Status and Trends Programme Compared to Data From Throughout the World

The National Oceanic and Atmospheric Administration's (NOAA) National Status and Trends (NS&T) Programme has analyzed samples of surface sediment collected at almost 300 coastal and estuarine sites throughout the United States since 1984. the overall distributions for concentrations of each element are approximately lognormal allowing a definition of geometric means and of “high” concentrations as those exceeding the mean plus one standard deviation of the lognormal distribution. Those mean and “high” concentrations should be useful for comparing the NS&T data set and with other reports on sediment contamination. A world-wide data set, constructed from data in the literature, was summarized in an identical manner. It was found, after excluding locally extreme values, that the NS&T and world-wide data sets yielded very similar mean and “high” concentrations for Cu, Ni, Pb and Zn. Chromium was the sole element showing higher summary statistics in the NS&T data set, a result attributed to NS&T sampling in areas of naturally (not contaminated) elevated Cr content. It remains undetermined, however, why the world-wide data set, even with exclusion of “hot spots”, yielded higher means and “highs” for Cd, Hg, As, and Ag.     

In Situ flushing of contaminated soils from a refinery: Organic compounds and metal removals

This article demonstrates the applicability of in situ flushing for the remediation of soil contaminated with petroleum hydrocarbons at a Mexican refinery. The initial average total petroleum hydrocarbon (TPH) concentration for the demonstration field test was 55,156 g/kg. After six weeks of in situ flushing with alternate periods of water and water/surfactant, an average concentration of 1,407 mg/kg was reached, achieving a total removal efficiency of 98 percent. At the end of the process, no hydrocarbons such as diesel; gasoline; benzene, toluene, ethyl benzene, and xylene (BTEX); or petroleum aromatic hydrocarbons (PAHs) were found. Iron washing achieved a removal efficiency of 70 percent, and for vanadium, the removal efficiency was 94.4 percent. The volume of soil treated was 41.6 m³ (38 m²), equivalent to 69.5 tons of soil. A rough calculation of the process costs estimated a total cost of $104.20/m³ ($114.00/m²). Our research indicates that there are a few studies demonstrating in situ flushing experiences under field conditions where both organic (TPH, diesel, gasoline, PAHs, BTEX) and metal (iron and vanadium) removals are reported. © 2004 Wiley Periodicals, Inc.