Occurrence of currently used pesticides in ambient air of Centre Region (France)

Ambient air samples were collected, from 2006 to 2008 at three rural and two urban sites in Centre Region (France) and analyzed for 56 currently used pesticides (CUPs), of which 41 were detected. The four CUPs most frequently detected were the herbicides trifluralin, acetochlor and pendimethalin and the fungicide chlorothalonil, which were found with frequencies ranging between 52 and 78%, and with average concentrations of 1.93, 1.32, 1.84 and 12.15 ng m^?3, respectively. Among the detected pesticides, concentrations of eight fungicides (spiroxamine, fenpropimorph, cyprodinil, tolyfluanid, epoxiconazole, vinchlozolin, fluazinam, fludioxinil), two insecticides (propargite, ethoprophos), and one herbicide (oxyfluorfen) are, to our knowledge, reported for the first time in the literature.The majority of the CUPs showed a seasonal trend, with most of the detections and the highest concentrations occurring during the spring and early summer. The most important pesticides detected were related to arable crops and fruit orchards, the main cultures in this region, highlighting the fact that the main sources come from local applications. Minor differences were found in the profiles of pesticides within rural areas and between rural and urban areas.     

Mangrove mapping in Ecuador: The impact of shrimp pond construction

A cooperative mangrove mapping project between the Ecuadorian Center for Remote Sensing (CLIRSEN) and the University of Delaware was begun in August 1982. The objectives of the project were to create historical maps of mangrove ecosystem extent and change, while transferring aerial photographic interpretation techniques to Ecuadorian personnel. The result of this cooperation was a series of three 125,000 scale maps of historical mangrove extent and change from 1966 to 1982 in the southern Gulf of Guayaquil. This multitemporal study showed a 16% decrease in mangrove extent and a 27% increase in shrimp pond development. If these rates of change prevail into the future, mangroves in Ecuador will reach parity with shrimp ponds in 1984 and completely disappear by mid-1990. Recognizing the significance of this loss to shellfish and fish production along the coast, Ecuadorian scientists at CLIRSEN have subsequently initiated a nationwide mangrove mapping program to create a historical base for future mangrove management strategies.     

Life cycle assessment of upflow anaerobic sludge blanket sludge management and activated sludge systems aiming energy use in the municipality of Itajubá, Minas Gerais,Brazil

Journal of Material Cycles and Waste Management - This study aimed to carry out the Life Cycle Analysis (LCA) targeting to decide the better management system for sludge from both Activated Sludge...     

Community partnered projects: a case study of a collaborative effort to improve sanitation in a marginalized community in northwest Mexico

There is a growing recognition in developing countries that community participation in water and sanitation projects is a necessary strategy in sustainable development. The main advantage of following such an approach is that, if participation can encourage a sense of ownership of the projects, the benefits of the project are more likely to extend over the long term. The case study at hand focuses on the challenges faced in implementing a wastewater treatment system to solve an environmental and public health problem in a rural community, Rosario de Tesopaco, in northwest Mexico. Until recently, the community has been unable to implement an effective plan to treat the wastewater generated in the community. The problems faced by the community can be attributed to the political arrangement of water and sanitation decentralization in Mexico that occurred in the mid 1980’s, whereby communities were required to meet wastewater treatment standards, but were not given the technical and political guidance needed to achieve this goal. However, in this instance, cooperation between the authorities in Rosario de Tesopaco, the federal agency for social development, and an academic institution has led to the successful design and approval of a wastewater treatment project. This achievement can be attributed to the use of an effective collaborative strategy, tailoring the project to the needs and capacity of the local community, positioning the community as the leaders and owners of the project. A model for following this strategy for developing rural sanitation projects in Mexico is proposed. Readers should send their comments on this paper to BhaskarNath@aol.com within 3 months of publication of this issue.     

Effects of thymol and carvacrol,alone or in combination,on fermentation and microbial diversity during in vitro culture of bovine rumen microbes

Two essential oils (EO), thymol and carvacrol, were used in six ratio (100:00, 80:20, 60:40, 40:60, 20:80 and 00:100) combinations of both EO and in a dose of 0.2?g L^?1 in bovine ruminal culture medium, 24-h cultures, to evaluate effects on total gas production (TGP), methane production, in vitro dry matter digestibility (IVDMD) and in vitro culture population dynamics of methanogenic and total bacteria. Total DNA extracted from ruminal microorganisms was subjected to denaturing gradient gel electrophoresis (DGGE)-polymerase chain reaction (PCR) to examine effects on bacterial populations. The effect of EO on TGP and IVDMD were assessed by comparison to untreated control cultures. In general, methane production by the microbial populations appeared to be higher with treatments containing the highest concentration of thymol than with treatments containing more carvacrol resulting in a tendency for greater methane-inhibiting activity achieved as the thymol concentration in the thymol:carvacrol mixtures decreased linearly. The population of total bacteria with a 74.5% Dice similarity coefficient for comparison of DGGE band patterns indicating shifts in bacterial constituents as EO ratios changed. No effects on TGP, IVDMD while only slight shifts in the methanogenic populations were seen with an overall 91.5% Dice similarity coefficient.     

Re-thinking water policy priorities in the Mediterranean region in view of climate change

Water is scarce in Mediterranean countries: cities are crowded with increasing demand; food is produced with large amounts of water; ecosystems demand more water that is often available; drought affects all. As climate change impacts become more noticeable and costlier, some current water management strategies will not be useful. According to the findings of CIRCE, the areas with limited water resources will increase in the coming decades with major consequences for the way we produce food and we protect ecosystems. Based on these projections this paper discusses water policy priorities for climate change adaptation in the Mediterranean. We first summarise the main challenges to water resources in Mediterranean countries and outline the risks and opportunities for water under climate change based on previous studies. Recognising the difficulty to go from precipitation to water policy, we then present a framework to evaluate water availability in response to natural and management conditions, with an example of application in the Ebro basin that exemplifies other Mediterranean areas. Then we evaluate adaptive capacity to understand the ability of Mediterranean countries to face, respond and recover from climate change impacts on water resources. Social and economic factors are key drivers of inequality in the adaptive capacity across the region. Based on the assessment of impacts and adaptive capacity we suggest thresholds for water policy to respond to climate change and link water scarcity indicators to relevant potential adaptation strategies. Our results suggest the need to further prioritise socially and economically sensitive policies.     

Short chain nitrocompounds as a treatment of layer hen manure and litter; effects on in vitro survivability of Salmonella,generic E. coli and nitrogen metabolism

The current study was conducted to assess the bactericidal effectiveness of several nitrocompounds against pathogens in layer hen manure and litter. Evidence from an initial study indicated that treatment of layer hen manure with 12 mM nitroethane decreased populations of generic E. coli and total coliforms by 0.7 and 2.2 log₁₀ colony forming units (CFU) g^?1, respectively, after 24 h aerobic incubation at ambient temperature when compared to untreated populations. Salmonella concentrations were unaffected by nitroethane in this study. In a follow-up experiment, treatment of 6-month-old layer hen litter (mixed with 0.4 mL water g^?1) with 44 mM 2-nitroethanol, 2-nitropropanol or ethyl nitroacetate decreased an inoculated Salmonella typhimurium strain from its initial concentration (3 log₁₀ CFU g^?1) by 0.7 to 1.7 log₁₀ CFU g^?1 after 6 h incubation at 37°C in covered containers. After 24 h incubation, populations of the inoculated S. Typhmiurium in litter treated with 44 mM 2-nitroethanol, 2-nitropropanol, ethyl nitroacetate or nitroethane were decreased more than 3.2 log₁₀ CFU g^?1 compared to populations in untreated control litter. Treatment of litter with 44 mM 2-nitroethanol, 2-nitropropanol, ethyl nitroacetate decreased rates of ammonia accumulation more than 70% compared to untreated controls (0.167 µmol mL^?1 h^?1) and loses of uric acid (< 1 µmol mL^?1) were observed only in litter treated with 44 mM 2-nitropropanol, indicating that some of these nitrocompounds may help prevent loss of nitrogen in treated litter. Results warrant further research to determine if these nitrocompounds can be developed into an environmentally sustainable and safe strategy to eliminate pathogens from poultry litter, while preserving its nitrogen content as a nutritionally valuable crude protein source for ruminants.     

Towards the definition of budget models for the evolution of deltas

Global climatic change is likely to take place and could eventually affect Mediterranean deltas and other lowlying coastal regions. This would have serious implications for the natural resources of these deltaic areas, as well as for human settlements and related economic activities. To achieve sound decision making, to prevent damages and to avoid risky investments, it is necessary to understand the integral functioning of deltaic areas and to determine their vulnerability and response to large-scale change phenomena. Optimal use of the available knowledge will require that existing and new field measurements are combined and that integrated (physical/ecological) conceptual models of deltaic behaviour are developed with socio-economics scenarios as boundary conditions. This paper illustrates the methodological effort towards organizing a modeling framework to conduct budget computations at various scales with reference to the most significant ‘physiogrpahic units’ and to the most significant deltaic processes. The final objective is to handle the problem of evaluating possible changes under different scenarios.     

Numerical simulation of water mixing and renewals in the Barcelona harbour area: the winter season

In the present paper, we use numerical simulation to investigate currents, mixing and water renewal in Barcelona harbour under typical conditions of wind forcing for the winter season. This site is of particular importance due to the interplay between touristic and commercial activities, requiring detailed and high-definition studies of water quality within the harbour. We use Large Eddy Simulation (LES) which directly resolves the anisotropic and energetic large scales of motion and parametrizes the small, dissipative, ones. Small-scale turbulence is modelled by the anisotropic Smagorinsky model (ASM) to be employed in presence of large cell anisotropy. The complexity of the harbour is modelled using a combination of curvilinear, structured, non-staggered grid and the immersed boundary method. Boundary conditions for wind and currents at the inlets of the port are obtained from in-situ measurements. Analysis of the numerical results is carried out based on both instantaneous and time-averaged velocity fields. First- and second-order statistics, such as turbulent kinetic energy and horizontal and vertical eddy viscosities, are calculated and their spatial distribution is discussed. The study shows the presence of intense current in the narrow and elongated part of the harbour together with sub-surface along-shore elongated rolling structures (with a time scale of a few hours), and they contribute to the vertical water mixing. Time-averaged velocity field reveals intense upwelling and downwelling zones along the walls of the harbour. The analysis of second-order statistics shows strong inhomogeneity of turbulent kinetic energy and horizontal and vertical eddy viscosities in the horizontal plane, with larger values in the regions characterized by stronger currents. The water renewal within the port is quantified for particular sub-domain regions, showing that the complexity of the harbour is such that certain in-harbour basins have a water renewal of over five days, including the yacht marina area. The LES solution compares favourably with available current-meter data. The LES solution is also compared with a RANS solution obtained in literature for the same site under the same forcing conditions, the comparison demonstrating a large sensitivity of properties to model resolution and frictional parametrization.