Cattle egrets as a biosentinels of persistent organic pollutants exposure

We investigated selected chlorinated pollutants (β-HCH, γ-HCH, DDDs, DDEs, o,p′-DDT, p,p′-DDT, heptachlor, aldrin, dieldrin, and endrin) in the Lahore and the Sialkot districts of Pakistan, using eggs of cattle egret (Bubulcus ibis) collected during May and June 2007. The pollutant with highest level and frequency was ΣDDT, followed by β-HCH, γ-HCH, heptachlor, aldrin, dieldrin, and endrin in descending order. The concentration(s) were significantly higher in Sialkot heronry for all the pollutants (except p,p′-DDT) than in Lahore. The values for DDTs, β-HCH, γ-HCH, and heptachlor were significantly higher (p < 0.05) in the egg(s) than in sediment(s) and in the chicks’ diet, due to biomagnification. Among DDTs analogues, p,p′-DDD was the major contaminant with >60 % of total DDT burden, reflecting the widespread aged as well as recent use of DDT as well as anaerobic degradation (DDD/DDE > 1 in many cases) in the nearby paddy soils. In few samples, p,p′-DDT/(DDD + DDE) > 0.5 suggested the recent emission patterns from surrounding contaminated areas of demolished DDT units and obsolete pesticide stores. The higher levels of HCHs (i.e., β-HCH) in the samples collected from Sialkot indicate exposure from long-term agricultural use. Overall, concentrations of all studied POPs were less than the threshold levels known to affect reproduction. Nevertheless, total DDTs and/or HCHs burdens in some eggs contained concentrations of greater than what would educe adverse effects on birds. This is among few studies on OCPs exposure to avian species, which provide the evidence of Pakistan’s contribution toward the Global POPs emission.     

Biochar from municipal solid waste for resource recovery and pollution remediation

Environmental Chemistry Letters - Open dumping of municipal solid waste is a common method of waste disposal in developing countries, thus leading to pollution by gaseous emissions and landfill...     

Pesticide residues in fruits and vegetables from Pakistan: a review of the occurrence and associated human health risks

The main objective of the review is to document, assess and analyze the results of the previously reported data on levels of different pesticides in selected fruits and vegetables from Pakistan. The findings of the previous studies clearly indicated that more than 50 % of the samples were contaminated with organophosphate, pyrethroids and organochlorine pesticides. Many studies reported that among fresh fruits and vegetables tomato, apple, melon, mango, grapes, and plum crossed the FAO/WHO permissible limits for these contaminants residual levels. The comparison of other regions showed that observed levels were found above maximum residue limits (MRLs) in 50 % of the samples but were in agreement with the studies from neighboring countries like China and Bangladesh. Higher hazard risk index (HRI) values were calculated for dieldrin, methamidophos, o,p′-DDT, diazinon and p,p′-DDT in apple, mango, banana, melon, potato and onion. The review also highlights that data on pesticide residues in foodstuff is scarce which should be overcome by further extending studies from different areas of Pakistan. In order to ascertain the provision of food suitable for human consumption, it is imperative to monitor pesticides in food commodities by the country’s authorities and enforce guidelines based on permissible limits.     

The nexus between eco-friendly technology and environmental degradation in India: Does the N or inverted N-shape load capacity curve(LCC) hypothesis hold?

This study aims to investigate the impact of eco-friendly technology on environmental degradation indicated using the load capacity factor (LCF) with the framework of the Load Capacity Curve (LCC) hypothesis. In this regard, an environmental degradation function is formed and analyzed using the Augmented Autoregressive Distributed Lag (AARDL) approach during the period spanning from 1975 to 2021 for India. The outcome indicates that eco-friendly technology reduces the LCF, thereby fostering environmental degradation in the long run, but the relationship is not significant in the short run. Further, an N-shaped LCC hypothesis has been observed in both long and short runs. Besides, energy consumption exhibits a LCF reducing or environmental degradation boosting role in the short run and long run. These findings are consistent with other models that are used to check the robustness of AARDL-based results. Thus, the study recommends policies for promoting eco-friendly technology, judicious economic growth, and cautious energy consumption to attain sustainable development by increasing the LCF in India.     

Dynamic linkage between industrialization,energy consumption,carbon emission,and agricultural products export of Pakistan: an ARDL approach

Environmental Science and Pollution Research - This study aims to contribute to the literature and examine the causal relationship between Pakistan’s agricultural products export,...     

Abundance,spatial distribution,and physical characteristics of microplastics in stormwater detention ponds

Despite extensive research on microplastics (MP) in marine environments, little is known about MP abundance and transport in terrestrial systems. There is, therefore, still little understanding of the main mechanisms driving the substantial transport of MP across different environmental compartments. Storm events can transport MP beyond boundaries, such as from the land to groundwater or the ocean, as has already been discovered for organic carbon transport. Urban stormwater detention ponds are suitable environments to study the impact of stormwater on the environmental fate and transport of MP. Herein, we investigate the longitudinal and vertical distribution of MP within two detention ponds with different physical characteristics. Soil samples were collected at various locations and from multiple depths (surface and subsurface layers) for measuring MP concentrations using fluorescence microscopy. Our findings show that MP are retained more near the inlet of the ponds, and MP of larger sizes were found more abundantly near inlets than outlets. We also found that MP mass and sizes decrease from surface soil to subsurface soil. In the pond, where vegetation (grass root network) was more considerable, MP were found more evenly distributed along the depth. In terms of shape, the fragments were the most abundant MP shape.     

Adaptation to climate change as resilience for urban extreme poor: lessons learned from targeted asset transfers programmes in Dhaka city of Bangladesh

This paper aims to identify how targeted asset transfers help to build adaptive capacity and adaptive actions of the urban extreme poor to climate change phenomena. This paper explores the theoretical debates of community-based adaptation approach and failure of such approach to address urban extreme poor. The empirical evidence of these theoretical debates will be drawn from two informal settlements of Dhaka city, where a targeted asset transfer project has been implementing since 2009. This paper explains that urban extreme poor usually work as unskilled labour and lack different livelihood capitals; and climate change is an increasingly important influence exacerbating an already vulnerable livelihood context. There is growing recognition in the literature that poor urban people and communities are adapting to climate change in physical and behavioural terms. But, in the case of urban extreme poor these adaptation approaches are delivering short-term survival strategies disregarding the notion of wellbeing in the medium to long-term perspectives. It is also evident that community level initiatives structurally reproduce the exclusion of the urban extreme poor. However, poverty literatures acknowledge that poverty-centred approaches could help to reduce vulnerability. As urban extreme poor are significantly more resource constrained, it is reasonable to assert that targeted asset transfers could be a poverty-centred adaptation approach in a changing climate. Targeted asset transfers approaches are the outcomes of recent social protection revolution that especially consider accumulation of physical, financial, human, and social capital in order to build adaptive capacity of the urban extreme poor. This adaptive capacity of the extreme poor may facilitate adjustments in assets, livelihoods, behaviours, and technologies in order to reduce future climate vulnerability. In this context, this paper seeks to answer whether targeted asset transfer approaches can be considered as effective poverty-centred adaptation approaches for the urban extreme poor or not.     

Distribution and risk assessment of organochlorine contaminants in surface water from River Chenab, Pakistan

Concentrations in surface waters (including particulate phase) of the River Chenab ranged from 27-1100 ng L(-1) and 25-1200 ng L(-1) for OCPs and 7.7-110 ng L(-1) and 13-99 ng L(-1) for PCBs during summer and winter, respectively from 2007-2009. DDTs exhibited the highest concentration, followed by HCHs > chlordane > ∑(24)PCBs > ∑other OCPs. Different indicative ratios for organochlorines suggest that current use, long range transport and also past application of these chemicals contribute to the total burden. Statistical analysis highlighted agricultural and industrial activities and municipal waste disposal as main sources of OCPs and PCBs in the riverine ecosystem of the River Chenab. Risk Quotients (RQ(CCCs)) > 10 for DDTs and PCBs levels in collected water samples from the River Chenab suggest that risk from DDTs and PCBs is moderate to severe and fluxes calculated for OCPs and PCBs from the River Chenab to the Indus River were 7.5 tons per year and 1.0 tons per year, respectively.     

Monitoring results for organochlorine pesticides in soil and water from selected obsolete pesticide stores in Pakistan

Seasonal changes in micromineral and macromineral concentrations in tissues of shrimp (Parapenaus longirostris) from Marmara Sea were measured for a 1-year period by using inductively coupled plasma mass spectrometer. The contents of investigated minerals in shrimp were found to be in the range of 0.374–0.716 mg/kg for Hg, 0.526–1.286 mg/kg for Se, 0.007–0.098 mg/kg for Cd, 0.197–0.230 mg/kg for Pb, 5.194–7.600 mg/kg for Cu, 11.090–17.707 mg/kg for Zn, 22.128–38.850 mg/kg for Al, 61.769–88.437 mg/kg for Fe, 0.262–0.368 mg/kg for As, 0.081–0.249 mg/kg for Co, 0.850–1.459 mg/kg for Mn, 0.316–0.507 mg/kg for Ni, 0.032–0.107 mg/kg for Sn, 1.262–1.502 mg/kg for Cr, 2,813.770–3,317.819 mg/kg for Na, 3,702.230–4,479.648 mg/kg for K, 495.782–650.280 mg/kg for Mg, 790.407–1,016.112 mg/kg for Ca, 2,685.873–3,657.658 mg/kg for P, and 0.454–0.942 mg/kg for I. The levels of Hg found in autumn were higher than maximum levels proposed by the European legislation.     

The level and distribution of selected organochlorine pesticides in sediments from River Chenab,Pakistan

Organochlorine pesticides (OCPs), viz. β-hexachlorocyclohexane (β-HCH), γ-HCH, aldrin, dieldrin, endrin, heptachlor, endosulfan-I, endosulfan-II, heptachlor endoepoxide, heptachlor exoepoxide, mirex, dicofol, o,p′-dichlorodiphenyltrichloroethane (o,p′-DDT), p,p′-dichlorodiphenyltrichloroethane (p,p′-DDT), dichlorodiphenyldichloroethane (DDD), and dichlorodiphenyltrichloroethylene (DDE) and 12 other physicochemical parameters were measured in surface sediments from River Chenab during two sampling seasons (summer and winter, 2007) to evaluate spatial and temporal trends of sediment pollution. Hierarchical agglomerative cluster analysis identified three groups of sites based on spatial similarities in physicochemical parameters and OCP residual concentrations. Spatial discriminant function analysis (DFA) segregated 14 parameters, viz. dicofol, endosulfan-I, heptachlor endoepoxide, dieldrin, DDD, DDE, endosulfan-II, o,p′-DDT, p,p′-DDT, pH, electrical conductivity (EC), Cl⁻¹, total P (%), and silt, which explained 96% of total variance between spatial groups. γ-HCH was the most frequently detected (63%) pesticide, followed by DDD (56%). The ratio of DDTs to their metabolites indicated current input and anaerobic biodegradation. Temporal DFA highlighted aldrin, heptachlor endoepoxide, Cl⁻¹, total P, and EC as important variables which caused variations between summer and winter. DDTs were relatively more prevalent as compared to other OCPs in the sediments samples during both seasons. DDT metabolites were detected at greater frequencies and concentrations in winter, whereas DDT isomers were more prevalent in summer sediment samples. Factor analysis identified agricultural and industrial activities as major sources of sediment OCP contamination. Concentrations of γ-HCH, heptachlor endoepoxide, dieldrin, and DDTs (isomers and metabolites) in all sediment samples were well above interim sediment quality guidelines (ISQGs) and probable effect limits (PEL) given by Canadian Sediment Quality Guidelines (CSQGs).