Evaluation of antioxidant potentials of Morinda morindoides leaf extract

This study investigated antioxidant status of animals given aqueous extract of Morinda morindoides leaves using the levels of reduced glutathione, total-thiol, vitamin C, and vitamin E as well as malondialdehyde concentrations as indices, and its in vitro antioxidant capacity. Thirty rats divided into five groups were used. Group A served as control and were administered distilled water while groups B, C, D, and E were given 100, 200, 400, and 800 mg per kilogram body weight of water-extracted constituents of M. morindoides for 28 days. Total phenolic compounds amounted to 83.6 ± 5.9 mg g^?1 gallic acid equivalent, while total flavonoid content was 9.5 ± 0.9 mg g^?1 pyrocathecol equivalent. Malondialdehyde in plasma was significantly decreased in a dose-dependent manner, ranging from 21% in groups B and C to 84% in groups D and E. Vitamins C and E were significantly increased, in group E by 91% and 17% compared with control. Total thiols and glutathione in plasma were significantly increased, with group E having 2.5-fold and 4.2-fold higher values than control.     

Effectiveness of dust dispersion in the 20-L Siwek chamber

The Siwek 20-L chamber is widely used throughout the world to evaluate the explosibility of dusts. This research evaluated the quality of dust dispersion in the Siwek 20-L chamber using Pittsburgh coal, Gilsonite, and purple K dusts. A Pittsburgh Research Laboratory (PRL) optical dust probe was used to measure optical transmittance through the dust cloud at various locations within the chamber. A total of 540 tests were performed, with triplicate tests at five nominal dust concentrations and six locations. The two standard dispersion nozzles (rebound and perforated annular nozzle) were compared. The transmissions corresponding to the normal ignition delay period were used to: (a) determine variations in spatial uniformity of dispersion obtained with both nozzles; (b) make comparisons between the experimental transmission data and those calculated from theory for the three dusts; and (c) make comparisons with transmission data measured in the PRL 20-L and Fike 1-m³ dust explosion chambers.The uniformity of dispersion for the three dusts was similar with both nozzles, despite the differences in nozzle geometry and mode of operation. Transmission data of the three dusts were all significantly lower than those calculated from theory. This was discovered to be, in part, due to significant reduction in particle size that occurred during dispersion. By measuring particle sizes before and after dispersion, values of 60%, 50%, and 20% reduction in particle size (based on the surface-weighted mean diameter) were obtained for Pittsburgh coal, Gilsonite, and purple K, respectively. Transmission data from the PRL 20-L, Fike 1-m³ and the Siwek 20-L chambers indicated comparable results in terms of uniformity of dispersion. However, transmission data from the Siwek 20-L chamber were significantly lower than those of the PRL and Fike chambers. Again, this was attributed, in part, to the significant reduction in particle size that occurred during dispersion in the Siwek chamber. The design of the outlet (dispersion) valve of the Siwek 20-L apparatus charge vessel was largely responsible for the particle break-up. The contribution to particle break-up by the dispersion nozzles and the high level of turbulence in the chamber were found to be minimal. This is a significant finding in that the dust particle size tested for explosibility in the Siwek chamber is considerably smaller than the original dust sample.     

The livelihood potential of non-wood forest products: The case of Mbooni Division in Makueni District, Kenya

Forestry is a productive sector with significant effects on meeting national socio-economic and environmental functions as well as the improvement of rural livelihoods. Non-wood forest products (NWFPs) in particular have been widely advocated by conservation and development organisations as potential alternative livelihood strategies, particularly among vulnerable forest dependant households. Like in most tropical countries, NWFPs are relevant in the sustainable development of Kenya that is particularly endowed with important forest resources. Kenya hosts about 17 million ha of forested land (about 3.51% of the total Sub-Saharan Africa forest cover by 2000), of which about 16,865,000 ha is under natural forest (EarthTrends: Forests, grasslands and drylands, 2003). Outside the gazetted forests, there are other large tracks of forests in trust lands, including national parks and reserves, hill forest reserves and privately owned lands covering about 0.5 million ha (Kenya’s forest resource assessment in the EC-FAO Partnership Programme Report, 2000; The Kenya Forests Act, 2005). Woodlands, bushlands and wooded grasslands, mainly found in the arid and semi-arid lands cover 37.6 million ha, while forest plantations (started in 1946) cover about 170,000 ha of land (The Kenya forestry master plan, 1994–2020, 1994). In most NWFPs endowed regions of the country however, this socio-economic and environmental potential is still unrealized. We illustrate the latter by a case study of NWFPs use and management in four villages in Mbooni Division of Makueni District, Kenya. The division was chosen because of its relatively high NWFPs availability, particularly from South Mbooni forest that is located at a distance less than 5 km for an estimated 80% of the interviewed households. Data used for the analysis was collected through a fieldwork survey carried out on women (35+ years) in August, 2005. One hundred and sixty (160) NWFPs are harvested (from plant and animal species) and used mainly for food, income generation (supplemental) and medicinal purposes. A number of challenges limit women’s enjoyment of the full benefits from NWFPs exploitation, the overriding problem being their inadequacy (in quantity and/or quality). In this paper we discuss these commonly utilized and managed NWFPs plant species in Mbooni and their potential contribution to improved livelihoods and sustainable development in Mbooni, Kenya and Sub-Saharan Africa (SSA) in general.     

Optimization of activated carbon production from empty fruit bunch fibers in one-step steam pyrolysis for cadmium removal from aqueous solution

The fast growth of the palm oil industry in Malaysia is associated with various waste products, namely the empty fruit bunches (EFB), which have a negative impact on the environment. Therefore, these wastes were utilized as a cheap raw material for the production of activated carbon (AC) with less energy consumption. One-step steam pyrolysis was used to produce AC from oil palm empty fruit bunch fibers (EFBF) by varying the operating parameters of temperature, steam flow rate, and activation time using two-level full factorial experimental design (FFD). Ten samples of AC were prepared and the optimized production conditions were chosen based on the ability to adsorb and remove cadmium. Physical activation comprised of carbonization for 30 min using nitrogen gas (N₂), followed by activation with steam at different flow rates (2.0, 3.0, and 4.0 ml/min), temperatures (600, 750, and 900°C) and times (15, 30, and 45 min). The AC sample produced at an activation temperature of 900°C with a steam flow rate of 2.0 ml/min and activation time of 15 min was selected as the best adsorbent with a total yield of 21.7%. It had adsorbed more than 97% of total cadmium from aqueous solution within 2 min of the contact time. Characterization of EFBF-based AC by SEM and BET surface area analysis had shown a good-quality adsorbent with highly active sites and well-developed pores with BET surface area of 635.16 m²/g. Experimental results indicated that the prepared AC from EFBF provide a promising solution in water and wastewater treatment.     

Anatomical changes,osmolytes accumulation and distribution in the native plants growing on Pb-contaminated sites

Environmental Geochemistry and Health - Native plants growing on heavy-metal-contaminated sites are the potential candidates for phytoremediation of contaminated sites due to their tolerance and...     

The evolving sedentary lifestyle among nomadic pastoralists in the humid zone of Nigeria: implications for land-use policy

SUMMARY

The humid zone of Nigeria has traditionally been considered unsuitable for extensive cattle production because of the prevalence of tsetse fly. Over the years, nomadic pastoralists, mainly Fulani, from the northern part of the country paid seasonal visits to this zone in search of pasture and water for their cattle during the dry season when the threat of the tsetse menace is less. The recent increase in the number of settled pastoralists has been associated with changing trends in the ecology and economy of the zone.

Relying on recent survey data, this paper attempts a systematic analysis of the adaptive strategies of the Fulani in pursuit of a sedentary lifestyle in the humid frontier of southwest Nigeria. Some of the adaptive strategies identified include: establishment of grazing orbits within a 20 km radius of their settlements, adjustment of herd size and structure, adoption of a multiple livelihood system, production of arable crops and appropriation of traditional social structures and kinship networks for herd management.

Long-term insecure land-holding arrangements, incessant seasonal bush burning for regeneration of pasture by the Fulani and the gradual destruction of the native forest cover are some of the problems arising from the sedentarisation of livestock production in the area. It was observed that the present land-use arrangement, even though it appears to guarantee the pastoralists security of tenure in the short term, is not sustainable in the long run, given the increasing commercialization of land in the area and rapid population growth. It was, therefore, concluded that government should put in place a land redistribution arrangement that will ensure secure land ownership by the Fulani. Development initiatives in the area should also focus on reinforcing those traditional practices of the Fulani that would guarantee a sustainable land-use system in the area.     

Ground cover impacts on sediment and phosphorus export from manured riparian pasture

Maintaining pasture ground cover is important in preventing environmental degradation of grasslands and associated riparian areas. The objective of this work was to determine the effect of ground cover on sediment and P export from pastured riparian areas under simulated rainfall events. Plots were established on two sites in the North Carolina Piedmont: a 10% slope with Appling sandy loam soils (fine, kaolinitic, thermic Typic Kanhapludults) and a 20% slope with Wedowee sandy loam soils (fine, kaolinitic, thermic Typic Kanhapludults), both with mixed tall fescue (Festuca arundinacea Schreb.)-dallisgrass (Paspalum dilatatum Poir.) vegetation. Existing forage stands were modified to represent a range of ground cover levels: 0, 45, 70, and 95% (bare ground, low, medium, and high cover, respectively), and amended with beef steer (Bos taurus) feces and urine (about 10 kg P ha(-1)). Mean runoff volume from bare ground was generally twice that observed from low, medium, and high levels of cover, which were similar. For all rainfall events combined, export of dissolved reactive P was greatest (P < 0.1) at bare ground and was reduced 31% at low cover, which did not differ from medium or high cover. Mean total Kjeldahl P export was greater (P < 0.001) from bare ground than from other cover levels. Results indicate that riparian bare areas can contribute substantial sediment (>215 kg ha(-1)) and P (0.7 kg P ha(-1)) to surface waters during heavy rainfall, whereas export may be reduced equally well by low cover (45%) as by high cover.     

Carboxymethyl cellulose thiol-imprinted polymers:Synthesis,characterization and selective Hg(Ⅱ) adsorption

Sulfur containing ion imprinted polymers(S-IIPs) were applied for the uptake of Hg(Ⅱ) from aqueous solution. Cysteamine which was used as the ligand for Hg(Ⅱ) complexation, was grafted along the epichlorohydrin crosslinked carboxylated carboxymethyl cellulose polymer chain through an amide reaction. The adsorption ability of S-IIPs towards Hg(Ⅱ)was investigated by kinetic and isotherm models, which, corresponding, showed that the adsorption process followed a pseudo-second-order, fitted well with the Langmuir isotherm with a maximum adsorption capacity of 80 mg/g. Moreover, thermodynamic studies indicated an endothermic and spontaneous reaction with the tendency of an enhanced randomness at the surface of the S-IIPs with temperature increases. S-IIPs indicated a high degree of selectivity towards Hg(Ⅱ) in the presence of Cu~(2+), Zn~(2+), Co~(2+), Pb~(2+)and Cd~(2+).Furthermore, the efficiency of S-IIPs was also evaluated against real samples showing86.78%, 91.88%, and 99.10% recovery for Hg(Ⅱ) wastewater, ground water and tap water,respectively. In this study, the adsorbent was successfully regenerated for five cycles, which allows for their reuse without significant loss of initial adsorption capability.     

Spatial Considerations in Wet and Dry Periods for Phosphorus in Streams of the Fort Cobb Watershed,United States

The Fort Cobb Watershed in Oklahoma has diverse biogeophysical settings and provides an opportunity to explore the association of water quality with a diverse set of landscapes during both wet (April 2007‐December 2009) and dry (January 2005‐March 2007) periods. The objective of this work was to identify spatial patterns in phosphorus (P) (soluble reactive P [SRP] and bioavailable P [BAP]) associated with landscape metrics for two distinct streamflow regimes. Spatial autocorrelation of P was evaluated using contiguous (side‐by‐side) and upstream (upstream:downstream) connectivity matrices. Biogeophysical metrics were compiled for each contributing area, and were partitioned based on association to P concentrations. Results for both SRP and BAP indicated that spatial autocorrelation was present (p < 0.05). There was more spatial autocorrelation and stream P concentrations were three to five times higher in the Wet phase than in the Dry phase (p < 0.05). Analysis with recursive partitioning resulted in higher R² with spatial autocorrelation than without spatial autocorrelation and indicated that lateral metrics (topography, soil, geology, management) were better predictors for SRP than instream metrics. During Wet phase, lateral metrics indicative of rapid surface and subsurface water movement were associated with higher P stream concentrations. This research demonstrated that we can detect landscapes more vulnerable to P losses and/or contaminations in either drought or very wet periods.