基于综合水质标识指数法的四川西充河水质评价

四川省西充河为严重污染河流,选取溶解氧(DO)、氨氮(NH+4-N)、五日生化需氧量(BOD5)、总氮(TN)、总磷(TP)5项指标年平均值,采用综合水质标识指数法,研究了西充河近10年水质状况随时间变化趋势及水污染特征。2003年至2010年水质级别为劣V类,2011年和2012年水质级别为Ⅳ类,水质标识指数Iwq从2003年的12.459逐渐降低到2012年的4.431。西充河近10年水质状况整体呈好转趋势,但未达到国家规定的Ⅲ级水质标准,水质标识指数Iwq结果表明该好转的速度较慢,西充河水质状况有较大的上升潜力和空间。总氮(TN)和氨氮(NH+4-N)为河流主要污染物,为了达到国家Ⅲ级水质标准,西充河的治理已刻不容缓。     

环境监测中重金属污染的控制对策分析

在我国社会经济快速发展的过程中,人们对自然资源需求无度,造成生态环境破坏问题非常严重。通过环境监测可以及时分析空气中有毒有害的物质成分,并且对环境污染问题进行及时有效的解决。但是在监测的过程中所采用大量的空气试剂很容易造成环境二次污染等问题,为此必须要积极加强对环境监测中重金属污染的合理控制,对空气试剂产生的大量废弃物进行及时的回收处理,从而有效避免出现二次污染的情况,充分发挥环境监测的作用。     

黄河中游水保措施对入黄干支流泥沙特性的影响:Ⅱ.减沙效益分析

应用文献［１］关于不同地貌类型及不同水保措施条件下黄河干支流中泥沙粒径分布的研究结果,可以对相应条件下的减沙效益进行有效的分析。利用文献［１］模型,本文不仅探讨了在给定地貌类型条件下各类水保措施实施前后流域汇入黄河干支流的泥沙总量的变化,而且还在扣除降雨变化的影响之后,预测了各类组合条件下非均匀泥沙中减沙效果最佳的粒径级和相应粒径级泥沙的减沙量,预测结果得到了黄河干支流各站所有实测资料的验证。文中还简要讨论了人类活动（主要是开矿）对减沙效益的影响。     

Removal of mercury from flue gas using sewage sludge-based adsorbents

Mercury from coal-fired utility boilers, as the largest atmospheric mercury emission source, imposes serious environmental risks and health concerns. In order to explore the possibility of reducing costs of activated carbon injection, we investigated the most promising mercury control technology, Hg⁰ removal using ZnCl₂-impregnated adsorbents derived from sewage sludge. The results demonstrated that sludge-based adsorbents (SBAs) had fairly high mercury adsorption capacity over a wide range of temperatures (80–170 °C). Oxidizing atmosphere could improve the adsorption of Hg⁰ and weaken the inhibition of SO₂ on mercury adsorption to some extent. NO exhibited no obvious impact on mercury removal performance. In addition, to clarify whether oxygen- or chlorine-containing functional groups attributed to good mercury adsorption capacity of SBAs, the oxygen-containing functional groups were removed using Boehm’s method, and a temperature-programmed decomposition desorption experiment was conducted. The results suggest that chlorine-containing functional groups played a significant role in the removal process of mercury from flue gas using SBAs.     

内循环生物流化床反应器流体力学特性的数值模拟

首先采用气、液两相模型对7组结构参数的反应器进行模拟计算,然后根据计算结果选择了一组较优的结构参数进行气、液、固3相的数值模拟计算.结果表明,通过数值模拟方法对内循环生物流化床反应器流体力学特性进行计算可获得优化的反应器结构参数;明确了循环挡板的长度及位置对反应器内液相流场分布的影响较为显著的事实;同时指出固相颗粒的加入对反应器内液相流速的分布几乎没有影响,固相含率较高的区域在反应器升流区.     

不同深度脱水污泥的热解特性及动力学分析

选用4种利于深度脱水的复合调理剂(FeCl3/CaO、FeCl3/CaO/煤粉、芬顿试剂(Fe2+和H2O2组成体系)/CaO、芬顿试剂CaO/煤粉)来改善污泥的脱水性能,所得泥饼的含水率为43.7%—56.1%,满足深度脱水的要求.CaO和煤粉的添加能改变污泥的灰分和挥发分含量.与传统聚丙烯酰胺(PAM)脱水污泥的热重分析对比结果表明,由于复合调理剂对EPS的破坏溶解作用,因此对污泥热解性质有较大影响,不仅能前移水分失重峰,还使得热重主要反应阶段峰个数变少.热解动力学计算表明,反应级数在1—2范围内.表观活化能差异表明4种复合调理剂处理后脱水污泥更容易发生热解反应.     

四川升钟水库景区消费生态足迹研究

本文基于生态足迹与岛屿理论,对升钟水库国家4A级水利工程类旅游景区的原住居民和外来旅游者的食物消费状况作出评判.2013年升钟景区总的消费生态足迹为97 695 hm2,人均消费生态足迹为0.756 hm2/人.在生态足迹视角下对比景区的生产消费状况,反映出景区产业结构不合理等问题.建议今后要对景区的产业作出一定的调整,即消减盈余的猪肉、粮食、水果、蔬菜、豆类、鱼的生产性土地面积,增加牛羊肉、牛奶、糖类、蛋类的生产性土地面积,适当控制常住居民人口数量,积极发展生态旅游,增加游客人数,提高当地居民的生活水平,走可持续发展道路.     

Urban nonpoint source pollution buildup and washoff models for simulating storm runoff quality in the Los Angeles County

Many urban nonpoint source pollution models utilize pollutant buildup and washoff functions to simulate storm runoff quality of urban catchments. In this paper, two urban pollutant washoff load models are derived using pollutant buildup and washoff functions. The first model assumes that there is no residual pollutant after a storm event while the second one assumes that there is always residual pollutant after each storm event. The developed models are calibrated and verified with observed data from an urban catchment in the Los Angeles County. The application results show that the developed model with consideration of residual pollutant is more capable of simulating nonpoint source pollution from urban storm runoff than that without consideration of residual pollutant. For the study area, residual pollutant should be considered in pollutant buildup and washoff functions for simulating urban nonpoint source pollution when the total runoff volume is less than 30 mm.     

Modelling the effects of water diversion and combined sewer overflow on urban inland river quality

In order to assist and optimize the operation of a clean water diversion project for the medium-sized inland rivers in Chaohu, China, an integrated hydrodynamic and water quality model was used in this study. Sixteen diversion scenarios and five sewage interception scenarios were defined to assess the improvement of water quality parameters including ammonia nitrogen (NH₃-N), total phosphorus (TP) and chemical oxygen demand (COD) under different diverted water flows, diverting times, diverting points, diverting routines and sewage interception proportions. An index of pollutant removal rate per unit diverted water flow (PRUWF) was proposed to evaluate the effect of the clean water diversion. Results show that operating conditions played important roles in water quality improvement of medium-sized inland rivers. The optimal clean water diversion was operated under the conditions of a flow rate of 5 m³/s for 48 h with an additional constructed bridge sluice. A global sensitivity analysis using the Latin Hypercube One-Factor-at-a-Time (LH-OAT) method was conducted to distinguish the contributions of various driving forces to inland river water restoration. Results show that sewage interception was more important than diverted water flow and diverting time with respect to water quality improvement, especially for COD.     

热水沉积作用与成矿效应

热水活动在岩石圈中是一种非常重要的地质和成矿作用，热水作用的动力学类型主要有深部岩浆作用、碰撞挤压作用和沉积物自生高压脱水作用。根据热水成矿的特点，在传统的三种成矿作用分类范围之外列出热水成矿作用，并进行了次级分类。我国南方主要发育有四期热水沉积作用．其特征是：在演化方式上从震旦纪到二叠纪有从沉积作用向交代和充填作用演化的趋势，在元素组成上有从稳定元素向活泼元素演化的趋势。在时空分有模式上，热水沉积矿床主要发育于张性构造背景中裂陷盆地充填层序碳酸盐岩向细碎屑岩的过渡部位．这个过渡时期正是盆地演化到深部与表层物质和能量强烈交换的时期，也是盆地海平面最高、陆源物最少的时期，同时由于盆地沉积基底碳酸盐岩的较早因此共产生裂隙和层间空隙，有利于形成热水集中供给的通道。