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1.
Chih Ming M Ya Wen Lee Gui Bing Hong Te Li Su Je Lueng Shie Chang Tang Chang 《环境科学学报(英文版)》2011,23(4):687-692
TiO2 nanoparticles, doped with di erent Pt contents, were prepared by a modified photodeposition method using Degussa P-25 TiO2,
H2PtCl6 6H2O and methanol as the solvents. The physicochemical properties of Pt/TiO2 were investigated by the nitrogen adsorption
and desorption isotherm measurement technique, X-ray di raction analysis and photoluminescence spectra, respectively. Reaction rates
from photocatalytic removal of dichloromethane over Degussa P-25 TiO2 and Pt/TiO2 were evaluated. The average diameter and BET
surface area of the TiO2 catalyst particles were 300 nm and 50 m2/g, respectively. The degradation e ciency was 99.0%, 82.7%, 55.2%,
and 57.9% with TiO2 at inlet concentrations of 50, 100, 200, and 300 ppm, respectively. And the degradation e ciency was 99.3%,
79.7%, 76.5%, and 73.4% with a 0.005 wt.% Pt/TiO2 at inlet concentrations of 50, 100, 200, and 300 ppm, respectively. In addition, we
found that the photoluminescence emission peak intensities decreased with increases in the doping amount of Pt, which indicates that
the irradiative recombination was weakened. Furthermore, the results showed that the UV/0.005 wt.% Pt/TiO2 process was capable of
e ciently decomposing gaseous DCM in air. 相似文献
2.
Radon ((222)Rn) is a carcinogenic gas produced by the radioactive decay of radium ((226)Ra). It has been reported that soil and soil-gas are primary factors that could cause indoor radon problems. Six sites were selected for this study--Sanbook, Gangcheon, Jikyeong, Choojung, Geumsung and Homyoung--each was classified according to bedrock type. In order to investigate soil-gas radon activities and radon emanating power, innovated active and passive detecting methods were developed and applied under both field and laboratory conditions. Statistical analysis of results confirmed that the radon activity values measured using either active or passive methods under field or laboratory conditions could be interchangeable with each other. 相似文献
3.
Alkylphenols (APs) have been known as endocrine disruptors and consequently received much environmental concern. This study focused on seasonal variation and spatial distribution of nonylphenol (NP) in various matrixes including dissolved water, particulates, surface sediment, sediment trap and sediment core taken from Shihwa Lake and its adjacent areas. A total of 11 phenolic compounds including nonylphenol, t-octylphenol (t-OP) and bisphenol A (BPA) were measured in February, June and October 2002. NP is the most abundant chemical among the phenolic compounds and its concentrations in dissolved water, particulates and surface sediments from Shihwa Lake were measured as 17.4-1533.1 ng/l, 4.3-831.2 ng/l and 10.4-5054.1 ng/g dw, respectively. NP concentration in dissolved water varied with seasons and generally showed a decreasing order of June > October > February, while the seasonal trend was hardly found in sediment. High levels of NP were measured in surrounding industrial complexes, the concentrations was decreased gradually with distance from the industrial areas. NP in core samples showed an increasing trend toward the core depth. There exists a reasonable correlation between NP in dissolved water and in particulates, whereas the correlation between NP in dissolved water and in sediments is not significant. APs concentrations in Shihwa Lake were comparable to other highly polluted areas of the world and their possible effects on various organisms in the lake are discussed. 相似文献
4.
Yu IJ Choi JK Kang SK Chang HK Chung YH Han JH Song KS Lee YM Chung HK 《Environment international》2002,28(1-2):35-39
Recently, a worker with lung carcinoma and a metastatic brain tumor was diagnosed as having a work-related disease. He had been employed in a non-asbestos textile company for 25 years. Consequently, to identify and explore possible causative agents for lung cancer in a non-asbestos textile manufacturing company and establish a causal relationship between exposure and lung cancer, an epidemiological investigative study was conducted and the work processes the worker was engaged in were examined. Air samples were taken from the workplace and during the drilling processes, and a suspected causative material was analyzed. The study revealed that the subject had been employed in the non-asbestos textile manufacturing company for 25 years from 1973 and his responsibilities included repairing spinning machines. In particular, the subject was involved in drilling B-bushings that were used to protect against gear abrasion in the spinning machines. An analysis of the B-bushings using a transmission electron microscope equipped with an energy dispersive X-ray analyzer indicated that they contained crocidolite asbestos fibers. Air samples obtained when drilling the B-bushings clearly indicated that the subject had most likely been exposed to crocidolite fibers when installing the B-bushings in the spinning machines. The frequency and duration of the work suggested that there would be a sufficient degree of exposure to crocidolite fibers to cause lung cancer. Except for smoking and asbestos exposure, no other chemical exposure was suspected for developing lung cancer in the workplace. Smoking appeared to be more of a potentiating risk factor in conjunction with the asbestos exposure. Accordingly, this case may provide significant evidence in identifying the cause of the mesothelioma or lung carcinoma found among workers in non-asbestos textile manufacturing companies elsewhere. 相似文献
5.
Simulation of resuspended sediments resulting from dredging operations by a numerical flocculent transport model 总被引:4,自引:1,他引:4
Environmental remediations such as dredging operations cause contaminated sediments from the bottom of water bodies to become suspended into the water column. These resuspended particles are significant water quality concerns and cause adverse effects to aquatic organisms. In this paper, we present a vertically integrated two-dimensional flocculent sediment transport model to better model concentration changes of resuspended bottom sediments. The flocculent transport model has been applied to the Savannah River cutterhead dredge field study involving the resuspension of bottom sediments. The results showed that the model predictions correlate reasonably well with field data. These comparisons suggest that the flocculent sediment transport model can be used to predict the concentration profiles of a plume of toxic compounds resulting from cutterhead dredge operation. 相似文献
6.
Jeżak Karolina Kozajda Anna 《Environmental science and pollution research international》2022,29(7):9533-9559
Environmental Science and Pollution Research - Intensive animal farming emits to the environment very high concentrations of bioaerosol, mainly composed of microorganisms, including antibiotics... 相似文献
7.
ZHAO Hongtao YIN Chengqing CHEN Meixue WANG Weidong Je eries Chris SHAN Baoqing 《环境科学学报(英文版)》2009,21(2):162-167
Particles of dust washed o streets by stormwater are an important pathway of polyaromatic hydrocarbons (PAHs) into urban streams.
This article presented a comprehensive assessment of the size distribution of PAHs in street dust particles, the potential risks of the
particles in urban streams, and the sources and sinks of PAHs in the stream network. This assessment was based on measurements of
16 PAHs from the USEPA priority list in street dust particles and river sediments in Xincheng, China. The content of total PAHs ranged
from 1629 to 8986 g/kg in street dust particles, where smaller particles have a higher concentrations. Approximately 55% of the total
PAHs were associated with particles less than 250 m which accounted for 40% of the total mass of street dust. The PAH quantities
increased from 2.41 to 46.86 g/m2 in the sequence of new residential, rising through main roads, old town residential, commercial and
industrial areas. The sediments in stream reaches in town were found to be sinks for street dust particle PAHs. The research findings
suggested that particle size, land use and the hydrological conditions in the stream network were the factors which most influenced the
total loads of PAH in the receiving water bodies. 相似文献
8.
9.
Air quality in underground spaces has seldom been evaluated in Korea. Accordingly, the current study recently evaluated asbestos exposure among Seoul metropolitan subway workers during the renovation of the subway's air-conditioning system. To identify possible routes of asbestos exposure, suspected sources, including gaskets, ceiling boards, ceiling materials, and dust settled inside ducts, were all sampled. Personal air samples were also taken to evaluate any asbestos exposure during the renovation. The asbestos fibers found in the samples were analyzed using a transmission electron microscope (TEM) equipped with an energy dispersive X-ray analyzer (EDX). Twelve out of eighteen bulk samples contained asbestos, the majority of which was chrysotile fibers. Asbestos was detected in 9 out of 72 personal air samples and the level ranged from 0.003 to 0.02 fibers/cm(3). While asbestos levels were below Korean occupational limit of 2 fibers/cm(3), they were still detectable and therefore further monitoring would be appropriate. 相似文献
10.
长江,嘉陵江重庆段水质现状评价与预测 总被引:4,自引:0,他引:4
采用隶属度加权综合平均水质级别法和三参量评价指数法对长江嘉陵江重庆干流段的平均水质进行了现状评价,同时利用一维水质模型和二维水质数学模型对干流平均水质和城区段的岸边水质进行了模拟计算,提出了未来两江可能出现的水质问题以及防治污染需要重点控制的污染物。 相似文献