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Moe MK Huber S Svenson J Hagenaars A Pabon M Trümper M Berger U Knapen D Herzke D 《Chemosphere》2012,89(7):869-875
For several decades, perfluorooctane sulfonate (PFOS) has widely been used as a fluorinated surfactant in aqueous film forming foams used as hydrocarbon fuel fire extinguishers. Due to concerns regarding its environmental persistence and toxicological effects, PFOS has recently been replaced by novel fluorinated surfactants such as Forafac®1157, developed by the DuPont company. The major component of Forafac®1157 is a 6:2 fluorotelomer sulfonamide alkylbetaine (6:2 FTAB), and a link between the trade name and the exact chemical structure is presented here to the scientific community for the first time. In the present work, the structure of the 6:2 FTAB was elucidated by 1H, 13C and 19F nuclear magnetic resonance spectroscopy and high-resolution mass spectrometry. Moreover, its major metabolites from blue mussel (Mytilus edulis) and turbot (Scophthalmus maximus) and its photolytic transformation products were identified. Contrary to what has earlier been observed for PFOS, the 6:2 FTAB was extensively metabolized by blue mussel and turbot exposed to Forafac®1157. The major metabolite was a deacetylated betaine species, from which mono- and di-demethylated metabolites also were formed. Another abundant metabolite was the 6:2 fluorotelomer sulfonamide. In another experiment, Forafac®1157 was subjected to UV-light induced photolysis. The experimental conditions aimed to simulate Arctic conditions and the deacetylated species was again the primary transformation product of 6:2 FTAB. A 6:2 fluorotelomer sulfonamide was also formed along with a non-identified transformation product. The environmental presence of most of the metabolites and transformation products was qualitatively demonstrated by analysis of soil samples taken in close proximity to an airport fire training facility. 相似文献
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在化学安全信息分享问题上,政府和工业界正在付出更多的努力.有许多国家和国际的法律手段,保障公众知情权.在这一点上,OECD已经开发出指导方针并且采用了一批关于化学安全的决定和建议.与公众的沟通,是政府、工业界和社会的共同责任,而公私合作是基础.当化学作业风险信息被广泛了解的时候,社会通常是受益的.然而,有一种忧虑认为,把某些类特定信息公诸于众,会危及安全. 相似文献
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Life history theory predicts a range of directional generic responses in life history traits with increasing organism size. Among these are the relationships between size and longevity, mortality, growth rate, timing of maturity, and lifetime reproductive output. Spanning three orders of magnitude in size, coral reef fishes provide an ecologically diverse and species-rich vertebrate assemblage in which to test these generic responses. Here we examined these relationships by quantifying the life cycles of three miniature species of coral reef fish from the genus Eviota (Gobiidae) and compared their life history characteristics with other reef fish species. We found that all three species of Eviota have life spans of < 100 days, suffer high daily mortality rates of 7-8%, exhibit rapid linear growth, and matured at an earlier than expected size. Although lifetime reproductive output was low, consistent with their small body sizes, short generation times of 47-74 days help overcome low individual fecundity and appear to be a critical feature in maintaining Eviota populations. Comparisons with other coral reef fish species showed that Eviota species live on the evolutionary margins of life history possibilities for vertebrate animals. This addition of demographic information on these smallest size classes of coral reef fishes greatly extends our knowledge to encompass the full size spectrum and highlights the potential for coral reef fishes to contribute to vertebrate life history studies. 相似文献
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Managing Mediterranean soil resources under global change: expected trends and mitigation strategies
Lagacherie Philippe Álvaro-Fuentes Jorge Annabi Mohamed Bernoux Martial Bouarfa Sami Douaoui Abdelkader Grünberger Olivier Hammani Ali Montanarella Luca Mrabet Rachid Sabir Mohammed Raclot Damien 《Regional Environmental Change》2018,18(3):663-675
Regional Environmental Change - The soils of the Mediterranean Basin are the products of soil processes that have been governed by a unique convergence of highly differentiated natural and... 相似文献
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C. Thauvin-Robinet P. Callier N. Laurent T. Rousseau A. Masurel-Paulet N. Marle F. Huet P. Sagot L. Faivre F. Mugneret 《黑龙江环境通报》2007,27(6):555-559
Occipital encephalocele belongs to the family of neural tube defects, which occur in one among 2000 to 5000 live births. Syndromic encephaloceles include Meckel–Gruber syndrome and various chromosomal abnormalities. We report on a fetal case (13 WG) with bilateral cleft lip and palate, choanal atresia, occipital encephalocele, bilateral club feet, bilateral multicystic kidneys, enlarged bladder and urethral atresia. The fetal chromosome analysis showed a maternally inherited unbalanced translocation between the short arm of chromosome 1 and the long arm of chromosome 14, resulting in 1p35-pter deletion and 14q32-qter duplication (46,XY,der(1),t(1;14)(p35;q32)). Since the chromosomal breakpoints have not previously been implicated in syndromic encephalocele, this observation is of interest for the identification of other genes responsible for occipital encephalocele. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
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Monica Gagliano Mark I. McCormick James A. Moore Martial Depczynski 《Marine Biology》2010,157(8):1849-1856
Ocean acidification is one of the key threats facing coral reef ecosystems, but there are few estimates of spatial and temporal
variability in pH among reef habitats. The present study documents levels of spatial variability in pH among coral reef habitats
(9 to 10), among locations separated by 100’s km of latitude and between east (Great Barrier Reef, GBR) and west (Ningaloo
Reef) coasts of Australia. Differences were found in pH between inshore and offshore waters along Ningaloo Reef (means 8.45,
8.53, respectively). Replicate assessments here ranged from 8.22 to 8.64. On the GBR, the range of values over all habitats
and replicates was 0.39 pH units (7.98 to 8.37). There were minor but significant differences of 0.05 pH units between 5 consecutive
days for habitats on average. Highest pH was recorded in filamentous algal beds maintained by the damselfish Dischistodus perspicillatus. Lowest pH was found in water extracted from sand-dwelling goby holes. While there were marked changes in pH over a 48-h
sampling period among 4 habitats at Lizard Island (GBR), there was little evidence of a diel trend. Understanding how pH varies
at scales that are relevant to organisms that live on shallow coral reefs is crucial for the design and interpretation of
experiments that test the effects on organisms of the changes in water chemistry predicted to affect oceans in the future. 相似文献
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Herpin U Siewers U Markert B Rosolen V Breulmann G Bernoux M 《Environmental science and pollution research international》2004,11(1):57-66
This paper shows the geographic distribution in Germany of iron (Fe), nickel (Ni) and lead (Pb) analyzed in mosses in 1995/96 and compares it with the results of the 1990/91 pilot study within a European moss-monitoring programme. Other elements (As, Cd, Cr, Cu, Ti, V, Zn) are compared on basis of the overall element medians for Germany of the 1990/91 and 1995/96 survey. Samples of Pleurozium schreberi, Scleropodium purum, Hypnum cupressiforme and Hylocomium splendens were taken at a total of 1026 sites. In the 1995/96 monitoring campaign, 95% of the original sites of the 1990/91 study were resampled. The results from 1995/96 display local elevated values and many cases of areas affected by known sources of heavy-metal emissions. The industrialized and urban regions of Germany are shown up clearly by the 1995/96 moss-monitoring results: the Ruhr area, parts of Saarland and Baden-Württemberg, as well as areas in eastern Germany. Relatively low values for many elements were found in large areas of Lower Saxony and Bavaria. A comparison of the results of the 1990/91 and 1995/96 moss-monitoring programmes shows a fall in the concentration of the presented elements (except cadmium, copper and zinc) over the relevant period. Especially in the former GDR, chromium (Cr), iron (Fe), titanium (Ti) and vanadium (V) decreased significantly. This is, firstly, a reflection of the closure of and/or technological improvements to large power plants; secondly it is due to the fact that lignite has given way to other fuels. Vanadium (V) and nickel (Ni), typical constituents of crude oil, also show a decrease in the western part and thus document changes in the type of fuel consumed. The significant fall in lead concentration in 1995/96 as compared to 1990/91 in what used to be East and West Germany probably results from the increasing use of lead-free petrol. A comparison of the median values for 1990/91 and 1995/96 in mosses to the rate of emission of heavy metals in Germany for 1990 and 1995 shows similar trends in the case of elements such as arsenic (As), chromium (Cr), nickel (Ni), and lead (Pb). The comparison of the medians of the elements analyzed for 19 European countries indicates for most of the elements a general tendency to lower values in 1995, except for Lithuania, Netherlands, Portugal, Italy and United Kingdom. 相似文献
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To evaluate the risk of corrosion of cement by geosequestered CO2, samples are being retrieved from wells placed in natural CO2 deposits [e.g., Crow et al., 2009]. If the cement passing through the cap rock is carbonated, it may indicate that annular gaps or cracks have allowed carbonic acid to come into contact with the cement. However, it must be recognized that the pore water in the cap rock has become saturated with CO2 over geological time. After the well is placed, the CO2 will diffuse toward the cement and react with it. A simple analysis of the diffusion kinetics demonstrates that carbonation depths of millimeters to centimeters can be expected from this reaction within the lifetime of a well, in the absence of any cracks or gaps. Therefore, the occurrence of carbonation in cement sealing natural CO2 deposits must be interpreted with caution. 相似文献