Tourism: economic development without increasing CO2 emissions in Pakistan

Environment, Development and Sustainability - Globally, the national and cultural resources of a country are major sources of attraction for tourism. Pakistan is gifted with abundant natural and...     

陆浑水库沉积物重金属空间分布特征及风险评价

为了解洛阳市饮用水水源地陆浑水库沉积物中重金属污染程度,采集32个点位的表层沉积物,分析6种重金属（Cd、Cr、Cu、Ni、Pb和Zn）的空间分布特征,并运用地累积指数法、潜在生态风险指数和聚类分析等方法对研究区重金属污染程度进行评价、生态风险评价及源解析.结果表明：Cd、Cu、Pb和Zn含量超过黄河流域河南段重金属土壤背景值,分别是其8.8、2.0、6.5、2.3倍,重金属存在明显富集,且主要污染集中于坝前区域.地累积指数法评价结果显示,Cd为强污染,Pb为中-强污染.潜在生态风险指数表明,陆浑水库沉积物重金属风险呈自上游至下游逐渐增强的趋势,总体处于高度生态危害,潜在生态风险指数均值达到312.94,其中Cd为主要贡献因子.富集系数法和聚类分析结果显示：Cd、Cu、Pb和Zn主要为人为源,Cr和Pb以自然源为主.总体而言,陆浑水库沉积物中重金属Cd和Pb污染相对较重,可能会对水库水环境构成威胁.     

SI-traceable certification of Cu, Cr, Cd and Pb in sediment and fly ash candidate reference materials

Many fields in environmental analytical chemistry deal with very low limits and thresholds as set by governmental legislations or transnational regulations. The need for the accuracy, comparability and traceability of analytical measurements in environmental analytical chemistry has significantly increased and total uncertainties are even asked for by accreditation bodies of environmental laboratories. This paper addresses achieving these goals to guarantee accuracy, quality control, quality assurance or validation of a method by means of certified reference materials. The assessment of analytical results in certified reference materials must be as accurate as possible and every single step has to be fully evaluated. This paper presents the SI-traceable certification of Cu, Cr, Cd and Pb contents in geological and environmentally relevant matrices (three sediments and one fly ash sample). Certification was achieved using isotope dilution (ID) ICPMS as a primary method of measurement. In order to reduce significantly the number of analytical steps and intermediate samples a multiple spiking approach was developed. The full methodology is documented and total uncertainty budgets are calculated for all certified values. A non-element specific sample digestion process was optimised. All wet chemical digestion methods examined resulted in a more or less pronounced amount of precipitate. It is demonstrated that these precipitates originate mainly from secondary formation of fluorides (essentially CaF2) and that their formation takes place after isotopic equilibration. The contribution to the total uncertainty of the final values resulting from the formation of such precipitates was in general < 0.1% for all investigated elements. Other sources of uncertainty scrutinised included the moisture content determination, procedural blank determination, cross-contamination from the different spike materials, correction for spectral interferences, instrumental background and deadtime effects, as well as the use of either certified values or IUPAC data in the IDMS equation. The average elemental content in the sediment samples was 30-130 micrograms g-1 for Pb, 0.5-3 micrograms g-1 for Cd and 50-70 micrograms g-1 for Cu. Cr was measured in one sample and was about 60 micrograms g-1. The concentrations in the fly ash sample were up to 2 orders of magnitude higher. Expanded uncertainty for the investigated elements was about 3% (coverae factor k = 2) except for Cr, (measured by high resolution ICPMS), for which the expanded uncertainty was about 7% (k = 2).     

环境物质拟除虫菊酯毒理学研究进展

拟除虫菊酯作为一种重要的合成杀虫剂,在人们的生产生活中有着广泛的应用,但同时其毒理学问题也越来越引起人们的注意,许多学者对此进行了深入的研究,在此研究基础上,从对动物的神经毒性、生殖毒性和生理生化毒性三个方面,对拟除虫菊酯的毒理学研究进展作一综述.     

铅对几种农作物的影响及迁移积累规律初探

四种作物的盆栽模拟实验表明:铅对作物的影响,主要表现为植株矮化、生物量下降.作物受铅危害,主要在种子萌发期和苗期.进入植物体的铅,主要沉积于导管壁及木质部细胞壁中.作物各部位吸铅的能力不同;作物吸铅量与土壤含铅量呈正相关;各器官含铅量依水分和养料的运输方向互成正相关性,并依此方向减少;作物吸收的铅不仅可以从下至上转移,也可以从上至下转移,但后者较困难.     

炼油装置运行周期评估技术及应用

炼油装置运行周期评估技术通过统计、分析装置故障数据,计算特定时间段装置的可靠性,进而获得装置可靠性随时间的变化规律和装置可靠性最差设备排序。介绍了该技术在某常减压装置的应用,应用结果表明,该评估技术为科学确定炼油装置运行周期提供了决策依据。     

价格体制改革中的环境政策调控

以价格体制改革为主线，着重分析和评价价格体制改革给环境保护工作带来的积极效应和负面影响。依据经济体制改革的客观要求，提出进一步利用价格杠杆加强环境保护工作的措施与方法。     

亚铵制浆黑液非无菌操作连续发酵生产酵母

从土壤中筛选出能在亚铵黑液中生长的毕赤酵母菌株（Ｐｉｃｈｉａ ｓｐ．Ｎｏ．１）经耐毒驯化后，可接种于酸析脱木素和汽提脱毒后的亚铵黑液中，在非无菌操作条件下连续发酵生产酵母菌体，该菌生产迅速，连续培养衡释率达０．２６ｈ＾－１，总糖的酵母得率为０．４８ｇ／ｇ（ＴＳ），ＣＯＤ去除２３％，菌体易絮凝，可自然沉降分离。     

萃取分光光度法测定工业废气中的游离溴

用萃取分光光度法测定工业废气中的游离溴，并对样品的采集与保存，萃取条件的选择进行了研究。结果表明，当溴的含量在１８．０－４５０．０μｇ／ｍＬ范围同时，吸光度与浓度具有良好的线性关系，方法的采样效率大于９９％，精密度和准确度较好当采集气体为１００Ｌ时，最低检出肖度为０．１４ｍｇ／ｍ＾３。     

论可持续发展与城市发展战略

分析了传统发展观和发展模式存在的局限性和严重缺陷，介绍了可持续发展战略的形成过程，核心思想和基本内涵，以及对未来世界发展的重大影响力。以上海城市发展为对象，提出了建设国际大都市中应当特别重视解决城市规划、产业结构调整、大力发展第三产业、推行工业清洁生产。改善城市能源结构和优先发展城市环境建设等方面重大问题和所应采取的对策措施。