Towards safety,hygiene and environmental (SHE) management in African small and medium companies

Although Safety, Health and Environment (SHE) principles are adhered to in companies of developed countries, the application in developing countries is at its infant stage, as shown by the present article where the authors surveyed SHE Practice in 242 companies of 8 West-African countries.     

Cd and Zn Concentration in Hybrid Poplar Foliage and Leaf Beetles Grown on Polluted Sediment-Derived Soils

Foliar Cd and Zn concentrations of hybrid poplars commonlyplanted on sediment-derived soils were assessed in field circumstances. Selected sites covered a range of soil types andplantation characteristics. Reference data for foliar concentrations were established from samples taken in a tree-nursery. Even in the reference situation a large variationin foliar Cd and Zn concentrations was observed, with relative standard deviations in the order of 15%. Foliar concentrations of Cd and Zn in poplars growing on sediment-derived soils increased during the growing season. The accumulation rate was markedly higher on polluted sediment-derived soils than in thereference situation. Poplars grown on polluted sedimentderived soils showed elevated and deviating foliar Cd and Znconcentrations (>7.5 mg Cd kg^-1 DW and 320 mg Zn kg^-1 DW). A thin unpolluted covering layer did not influence foliarconcentrations. Regardless of site characteristics, poplarage, species or clone, a significant positive relation wasfound between soil and foliar concentration for Zn and to alesser extent for Cd. Bioconcentration factors for Cd and Znwere higher than one in baseline situations, but mostly lowerthan one on polluted sediment-derived soils. Cd:Zn ratio wason the average twice as high as in the soil. Leaf beetlesshowed normal body concentrations for Zn, but higher Cdconcentrations than in reference situations. BCFs were lowerthan one on sediment-derived soils. Foliar results indicateda possible threat in long-term habitat development of poplarplantations. This conclusion was confirmed by the significanthigher Cd concentrations in leaf beetles grown on poplarswith deviant foliar concentrations. However, litterdecomposition rates were generally evaluated as normal.     

Understanding urban vulnerability,adaptation and resilience in the context of climate change

This paper introduces a special issue of Local Environment that has arisen through collaboration between academic researchers and the Urban Planning and Design Branch of UN-Habitat, focused on how we can understand and respond to the challenges of urban vulnerability, adaptation and resilience in the context of climate change. The paper establishes the existing state of the art in the field, and considers critical challenges that are emerging in the research-based literature. In this context, it introduces UN-Habitat's Cities and Climate Change Initiative and reflects on the lessons learnt and challenges ahead, drawing on insights from across the papers in the special issue. In conclusion, it identifies the role of international/transnational co-operation, the relation between adaptation and mitigation, issues of multi-level governance and the ways in which change in urban socio-technical systems might be achieved as critical issues across the science/policy interface where increased dialogue and the co-production of knowledge needs to focus in order to advance this agenda.     

过去10年来世界各地21世纪地方议程中的 住区经验：方法与汲取的教训

本文评述联合国人类住区中心推动21世纪地方议程的经验.它依据促进21世纪地方议程举措的两个最主要的人类住区方案，即可持续城市方案(SCP)和落实21世纪地方议程方案过程中所取得的经验，对构成参与城市规划和管理的一个共同框架的几个不同阶段做了解释.本文还提出了在全世界40个城市所汲取的几点重要教训.     

The design of cyclonic pre-heaters in suspension cement kilns

Cement manufacturing consumes two main types of energy: fuel and electricity. On average, energy costs represent 40% of the total production costs per ton of cement. The challenge is to reduce the consumption of energy to about 3000 MJ/ton clinker without the consumption of massive additional amounts of electricity, which is normally associated with additional fuel-saving measures. This can only be achieved by implementing sound thermal energy optimization measures. Energy-efficient suspension cement kilns are now widely applied and use a cascade of cyclonic pre-heaters of moist particulate feedstock, with heat transfer from hot kiln exhaust gas to particles being a function of heat transfer coefficient, temperature difference and gas–solid contact mode and time. The gas–solid contact mode and time depend on particle movement in cyclones, which has previously been studied by positron emission particle tracking. Heat transfer is governed by Nusselt–Reynolds equations, with gas velocity and properties being a function of the temperature profile along the cascade of cyclones. A stepwise approach of the design thus combines changing hydrodynamics and heat transfer along the successive cyclones, with the overall thermal balance of the cascade as control. This approach leads to major design recommendations, as developed in the present paper.     

Polymeric cracking of waste polyethylene terephthalate to chemicals and energy

Polyethylene terephthalate (PET) is a widely used thermoplastic. PET residues represent on average 7.6 wt% of the different polymer wastes in Europe. Pyrolysis of these wastes is attracting increasing interest, and PET is a potential candidate for this thermal process. The paper measures and discusses the kinetics of the pyrolysis reaction in terms of the reaction rate constants as determined by dynamic thermogravimetric analysis, with special emphasis on the required heating rate to obtain relevant results. The product yields and compositions are also determined. Gaseous products represent 16-18 wt%. The amounts of condensables and carbonaceous residue are a function of the operating mode, with slow pyrolysis producing up to 24 wt% of carbonaceous residue. Major condensable components are benzoic acid, monovinyl terephthalate, divinyl terephthalate, vinyl benzoate, and benzene. The present paper complements previous literature findings by (1) the study of the influence of the heating rate on the reaction kinetics in dynamic pyrolysis tests, (2) the isothermal investigation in a fluidized bed reactor to pyrolyze PET, and (3) the assessment of upgrading and recovery of the products. The paper concludes with a proposed reactor recommendation for PET pyrolysis, in either the bubbling or circulating fluidized bed operating mode.