Derivation of correlations to evaluate the impact of retrofitted post-combustion CO2 capture processes on steam power plant performance

When integrating a post-combustion CO₂ capture process and CO₂ compression into a steam power plant, the three interface quantities heat, electricity and cooling duty must be satisfied by the power plant, leading to a loss in net efficiency. The heat duty shows to be the largest contributor to the overall net efficiency penalty of the power plant. Additional energy penalty results from the cooling and electric power duty of the capture and compression units.In this work, the dependency of the energy penalty on the quantity and quality of the heat duty is analyzed and quantified for a state-of-the-art hard coal fired power plant. Furthermore, the energy penalty attributed to the additional cooling and power duty is quantified. As a result correlations are provided which enable to predict the impact of the heat, cooling and electricity duty of post-combustion CO₂ capture processes on the net output of a steam power plant in a holistic approach.     

Model-based prediction of long-term leaching of contaminants from secondary materials in road constructions and noise protection dams

In this study, contaminant leaching from three different secondary materials (demolition waste, municipal solid waste incineration ash, and blast furnace slag) to groundwater is assessed by numerical modeling. Reactive transport simulations for a noise protection dam and a road dam (a typical German autobahn), in which secondary materials are reused as base layers, were performed to predict the breakthrough of a conservative tracer (i.e., a salt) and sorbing contaminants (e.g., PAHs like naphthalene and phenanthrene or heavy metals) at the groundwater table. The dam constructions have a composite architecture with soil covers in inclined layers and distinct contrasts in the unsaturated hydraulic properties of the used materials. Capillary barrier effects result in strong spatial variabilities of flow and transport velocities. Contaminant breakthrough curves at the groundwater table show significant tailing due to slow sorption kinetics and a wide distribution of travel times. While conservative tracer breakthrough depends primarily on subsoil hydraulic properties, equilibrium distribution coefficients and sorption kinetics represent additional controlling factors for contaminant spreading. Hence, the three secondary materials show pronounced differences in the temporal development of leached contaminant concentrations with consequences for breakthrough times and peak concentrations at the groundwater table. Significant concentration reductions due to dispersion occur only if the source concentrations decrease significantly prior to the arrival of the contaminant at the groundwater table. Biodegradation causes significant reduction of breakthrough concentrations only if flow velocities are low.     

Assessing the impacts of mountain biking and hiking on subalpine grassland in Australia using an experimental protocol

Mountain biking is an increasingly popular, but sometimes controversial, activity in protected areas. Limited research on its impacts, including studies comparing biking with hiking, contributes to the challenges for mangers in assessing its appropriateness. The impacts of mountain bike riding off trail were compared to those of hiking on subalpine grassland in Australia using a modification of a common trampling experimental methodology. Vegetation and soil parameters were measured immediately and two weeks after different intensities of mountain biking (none, 25, 75, 200 and 500 passes across slope, 200 pass up and down slope) and hiking (200 and 500 passes across slope). There were reductions in vegetation height, cover and species richness, as well as changes in species composition and increases in litter and soil compaction with riding. Riding up and down a moderate slope had a greater impact than riding across the slope. Hiking also affected vegetation height, cover and composition. Mountain biking caused more damage than hiking but only at high use (500 passes). Further research including other ecosystems, topography, styles of riding, and weather conditions are required, but under the conditions tested here, hiking and mountain biking appear to be similar in their environmental impacts.     

Application of lean flammability limit study and large eddy simulation to burner development for an oxy-fuel combustion system

Previously, we developed a model to predict lean flammability limit L and flame propagation velocity Sb for pulverized coal. In the present paper, we have extended the model to apply it in development of oxy-fuel combustion systems. The basic model consists of two particles. One of the two particles burns first, then, the other particle is ignited by the heat of combustion of the one burning particle. We analyzed at what distance the first burning particle could ignite the next particle, and how fast the first burning particle could ignite the next particle. The model was verified both for air and oxy-fuel combustion conditions. Next, a method to support burner development was examined by using the model. Local Sb and L near the ignition points of the burner could be analyzed from the concentration and temperature profiles of CFD results. Flame stability was judged by the calculated Sb and L profiles, and past results of blow-off limits obtained with actual- and pilot-scale experiments. A DS^®T-burner was developed by Hitachi Power Europe, and installed at the Schwarze Pumpe pilot plant. Combination of the technique and large eddy simulation was applied to confirmation of the system.     

How do transformational leaders foster positive employee outcomes? A self‐determination‐based analysis of employees' needs as mediating links

Although followers' needs are a central aspect of transformational leadership theory, little is known about their role as mediating mechanisms for this leadership style. The present research thus seeks to integrate and extend theorizing on transformational leadership and self‐determination. In particular, we propose that the satisfaction of followers' basic needs (autonomy, competence, and relatedness) mediates the relationship between transformational leadership and employee outcomes (job satisfaction, self‐efficacy, and commitment to the leader). We tested this model in two studies involving employees from a broad spectrum of organizations in Germany (N = 410) and in Switzerland (N = 442). Results revealed largely consistent patterns across both studies. The need for competence fulfillment solely mediated the link between transformational leadership and occupational self‐efficacy; the need for relatedness fulfillment solely mediated the link between transformational leadership and commitment to the leader. The mediating pattern for the link between transformational leadership and job satisfaction varied slightly across studies. In Study 1, only the need for autonomy fulfillment was a significant mediator, whereas in Study 2, all three needs mediated this relationship. Taken together, our study integrates theorizing on transformational leadership and self‐determination by corroborating that need fulfillment indeed is a central mechanism behind transformational leadership. Copyright © 2012 John Wiley & Sons, Ltd.     

Obtaining and characterization of catalytic materials from waste tires for the Fischer–Tropsch process

Journal of Material Cycles and Waste Management - In this contribution, the preparation of iron-based catalysts from waste tires is reported. Waste steel from disused tires was used as feedstock to...