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Muthusamy Subbulakshmi Anandharaj Swetha Juliet Kumar Ponnusamy Senthil Meganathan Yogesan Vo Dai-Viet Nguyen Vaidyanathan Vinoth Kumar Muthusamy Shanmugaprakash 《Environmental Chemistry Letters》2022,20(5):3199-3234
Environmental Chemistry Letters - Most fossil fuel-derived polymers used for food packaging are non-biodegradable and induce pollution by microplastic, calling for safer material. Here we review... 相似文献
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Rajendran Devi Sri Chidambaram Ashok Kumar Ponnusamy Senthil Venkataraman Swethaa Muthusamy Shanmugaprakash Vo Dai-Viet Nguyen Rangasamy Gayathri Vaithyanathan Vasanth Kumar Vaidyanathan Vinoth Kumar 《Environmental Chemistry Letters》2023,21(2):911-934
Environmental Chemistry Letters - Modern biomass and organic waste are becoming major, carbon-neutral sources of fine chemicals, biomolecules and fuels to replace fossil fuel products. As a... 相似文献
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Shanmugaprakash Muthusamy Sivakumar Venkatachalam Prasana Manikanda Kartick Jeevamani Nandusha Rajarathinam 《Environmental science and pollution research international》2014,21(1):593-608
In this present study, the biosorption of Cr(VI) and Zn(II) ions from synthetic aqueous solution on defatted J atropha oil cake (DJOC) was investigated. The effect of various process parameters such as the initial pH, adsorbent dosage, initial metal ion concentration and contact time has been studied in batch-stirred experiments. Maximum removal of Cr(VI) and Zn(II) ions in aqueous solution was observed at pH 2.0 and pH. 5.0, respectively. The removal efficiency of Cr(VI) and Zn(II) ions from the aqueous solution was found to be 72.56 and 79.81 %, respectively, for initial metal ion concentration of 500 mg/L at 6 g/L dosage concentration. The biosorbent was characterized by Fourier transform infrared, scanning electron microscopy and zero point charge. Equilibrium data were fitted to the Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherm models and the best fit is found to be with the Freundlich isotherm for both Cr(VI) and Zn(II) metal ions. The kinetic data obtained at different metal ion concentration have been analysed using the pseudo-first-order, pseudo-second-order and intraparticle diffusion models and were found to follow the pseudo-second-order kinetic model. The values of mass transfer diffusion coefficients (D e) were determined by Boyd model and compared with literature values. Various thermodynamic parameters, such as ΔG°, ΔH° and ΔS°, were analysed using the equilibrium constant values (K e) obtained from experimental data at different temperatures. The results showed that biosorption of Cr(VI) and Zn(II) ions onto the DJOC system is more spontaneous and exothermic in nature. The results indicate that DJOC was shown to be a promising adsorbent for the removal of Cr(VI) and Zn(II) ions from aqueous solution. 相似文献
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