2,2-二氯乙烯基二甲基磷酸酯在TiO2/H2O界面上光催化降解

实验研究了２,２－二氯乙烯基二甲基磷酸酯在ＴｉＯ２／Ｈ２Ｏ界面上光催化降解的最适空气通入量,初始ＰＨ值, 不同浓度的调变性助催经剂Ｆｅ＾３＋、Ａｇ＾＋在供Ｏ２条件下对ＴｉＯ２光催化降解有机磷速率的影响。     

山东省1960—2011年参考作物蒸散量变化特征研究

为了研究山东省参考作物蒸散量（ET0）的变化特征,选取属于湿润气候的成山头站以及属于半湿润气候的惠民站、济南站、潍坊站、定陶站、兖州站6个气象站,利用国家气象资料中心提供的1960—2011年的逐日气象资料,采用距平分析、回归分析和地理信息系统分析了山东省ET0的年代际、年际和年内的时空变化趋势,并通过偏相关分析及标准化偏回归系数对各站ET0的影响因素进行研究。结果表明：半湿润区ET0年代均值大于湿润区ET0年代均值,其中济南站最大,最大值出现在20世纪70年代,达到1269.2 mm,成山头站最小,最小值也出现在20世纪70年代,为900.8 mm;6个站点中,济南站ET0值年际间的变化最大,极差达到351.9mm,定陶的极差最小,为157.8 mm。潍坊的ET0年际波动最大,标准差达到74.4 mm;定陶的年际ET0标准差达到51.4 mm,波动最小。6个站点的ET0年均值随时间呈现不同程度的降低,其中潍坊和兖州为极显著,济南和定陶为显著降低。ET0年均值在空间上的分布规律为：济南站〉潍坊站〉惠民站〉兖州站〉定陶站〉成山头站;6个站点的ET0都是夏季最高,冬季最低。春季平均ET0值中部地区最大,达到409.0 mm,东北部沿海区最小,只有237.2 mm。夏季平均ET0值的空间分布与全年平均ET0值的空间分布较为一致,只在惠民站为中心的小区域内出现降低,与周围区域有反差。秋、冬季平均ET0值在中部及东北部均较大,东北部最大,西南部及西北部较小,最小值出现在西南地区。半湿润气候的惠民站、济南站、潍坊站、定陶站、兖州站的ET0随时间的年内变化曲线为单峰型,峰值均出现在夏季6月,全年的第162天。湿润气候下成山头站的ET0随时间的年内变化曲线呈双峰型,峰值分别出现在春季5月,全年第150天以及秋季9月,全年第270天;山东省ET0与气象要素间的相关性很好,除成山头站的最低气温外,均达到极显著水平。影响山东省湿润气候和半湿润气候ET0变化的主要气象要素分别为最高气温和平均气温。     

Photocatalysis of aqueous PFOA by common catalysts of In2O3, Ga2O3, TiO2, CeO2 and CdS: influence factors and mechanistic insights

Environmental Geochemistry and Health - Gallium oxide (Ga2O3), titanium dioxide (TiO2), cerium dioxide (CeO2), indium oxide (In2O3) and cadmium sulfide (CdS) were commonly used under UV light as...     

Electrocatalytic biofilm reactor for effective and energy-efficient azo dye degradation: the synergistic effect of MnOx/Ti flow-through anode and biofilm on the cathode

● MnO _x /Ti flow-through anode was coupled with the biofilm-attached cathode in ECBR. ● ECBR was able to enhance the azo dye removal and reduce the energy consumption. ● Mn^IV=O generated on the electrified MnO _x /Ti anode catalyzed the azo dye oxidation. ● Aerobic heterotrophic bacteria on the cathode degraded azo dye intermediate products. ● Biodegradation of intermediate products was stimulated under the electric field. Dyeing wastewater treatment remains a challenge. Although effective, the in-series process using electrochemical oxidation as the pre- or post-treatment of biodegradation is long. This study proposes a compact dual-chamber electrocatalytic biofilm reactor (ECBR) to complete azo dye decolorization and mineralization in a single unit via anodic oxidation on a MnO_x/Ti flow-through anode followed by cathodic biodegradation on carbon felts. Compared with the electrocatalytic reactor with a stainless-steel cathode (ECR-SS) and the biofilm reactor (BR), the ECBR increased the chemical oxygen demand (COD) removal efficiency by 24 % and 31 % (600 mg/L Acid Orange 7 as the feed, current of 6 mA), respectively. The COD removal efficiency of the ECBR was even higher than the sum of those of ECR-SS and BR. The ECBR also reduced the energy consumption (3.07 kWh/kg COD) by approximately half compared with ECR-SS. The advantages of the ECBR in azo dye removal were attributed to the synergistic effect of the MnO_x/Ti flow-through anode and cathodic biofilms. Catalyzed by Mn^IV=O generated on the MnO_x/Ti anode under a low applied current, azo dyes were oxidized and decolored. The intermediate products with improved biodegradability were further mineralized by the cathodic aerobic heterotrophic bacteria (non-electrochemically active) under the stimulation of the applied current. Taking advantage of the mutual interactions among the electricity, anode, and bacteria, this study provides a novel and compact process for the effective and energy-efficient treatment of azo dye wastewater.     

流化床污泥热解实验及产物性质研究

采用流化床反应器对城市污水污泥在400~600 ℃及800~950 ℃温度区间内进行了热解实验.结果表明,污泥受热升温过程经过干燥脱气、分解解聚和裂解缩聚3个阶段,在此过程中发生复杂的化学反应,生成热解气、焦油和半焦.热解温度为550 ℃时液体产率达到最大值,为50.35%,热解气产率在950 ℃时为51.58%,半焦产率随着热解温度升高而逐渐降低,950 ℃时为36.92%.污泥低温热解焦油含有较高百分含量的脂肪族碳氢化合物和类固醇类化合物,经加工可作为液体燃料利用,高温热解焦油可提取多种化工原料.热解气可作为合成气或燃烧利用.