The pollution halo effect of technology spillover and pollution haven effect of economic growth in agricultural foreign trade: two sides of the same coin?

Environmental Science and Pollution Research - The existing literature on the environmental Kuznets curve (EKC) fails to investigate the spatial attribute of the “pollution halo” effect...     

贸易自由化对我国环境的影响——基于ACT模型的实证研究

近年来我国对外贸易发展迅速，但伴随而来的环境污染问题也越来越严重。学术界对我国贸易与环境问题进行了多方面研究，但并未得到一致的结论。文参考ACT模型，试图将贸易自由化对我国环境的影响从经济发展对我国环境的整体效应中分离出来进行研究。本文采用panel数据对我国1992-2004年期间贸易自由化的环境效应进行了实证分析，结果表明：贸易自由化对我国环境消极的规模效应和结构效应远远超过了积极的技术效应，即贸易自由化使我国环境恶化。这主要归因于我国粗放型的经济增长方式以及不完善的环境法规。要改善其不利影响，我国应采用法律和经济措施相结合的办法，从而达到减少贸易的规模效应、改变现有贸易结购以及加强其技术效应的目的。     

北京水灾及其社会影响

北京在历史上曾发生多次重大水灾,给人民生命财产、城市建设及社会安定带来了巨大影响。形成水灾的主要因素是永定河决口泛溢和区域雨涝。现从大量的历史文献中列举几个实例,来看水灾的严重程度及其影响后果。     

基于时序NDVI数据的鄱阳湖流域常绿覆被季节性变化特征

选择位于红壤丘陵区的鄱阳湖流域作为研究对象，利用1 km×1 km分辨率的时序SPOT4 VEGETATION数据，对流域内典型土地覆被--常绿覆被的绿度值、峰值、谷值、年均NDVI(NDVI-I)和NDVI年内极差(NDVI MM)等特征值进行了提取。在此基础上，探讨了不同常绿覆被类型的NDVI指数年内季节变化规律。结果表明：时序NDVI指数基本上能够较好地刻画不同常绿覆被类型之间的差异性，植被指数NDVI特征值随覆被的类型及其生长状态有规律地变化，即NDVI年均值和最小值基本上按“常绿阔叶林＞常绿针阔叶混交林＞常绿针叶林＞常绿针叶-落叶混交林”的顺序变化；典型常绿阔叶林的NDVI指数年内变化曲线基本上没有大的起伏波动；常绿针叶林以及常绿针阔叶混交林占主导地位的常绿混交林NDVI指数年内变化比较和缓，但常在8月和11月有所波动；以常绿针叶林为主、但有较多落〖JP2〗叶林混杂其中的常绿混交林，其NDVI指数年内变化曲线基本上呈和缓的单峰型波动。     

不同来源土样胶体对氯霉素吸附行为的影响

选取不同来源沉积物或土壤样品（沉积物A1和A2,天然土壤B1和B2,市售营养土B3）,采用切向超滤与多种纳米分析技术相结合的方法,分析了不同土样中胶体的理化特征及其对氯霉素（CAP）吸附行为的影响.荧光区域积分法结果显示,土样胶体的荧光组分以色氨酸类蛋白质、类富里酸和类腐殖酸为主,络氨酸类蛋白质和溶解性微生物代谢物质存在较少.吸附实验结果表明,B3胶体对CAP的吸附率最大（36.25%）,在胶体浓缩液和超滤液中的分配比例最高（1.91）,但其有机碳归一化结合系数最低（3.93）.与天然土壤相比,河湖沉积物胶体的吸附率较高,但其与CAP的结合能力却较低.冗余分析结果表明,胶体对CAP的吸附主要与其芳香度、有色溶解性有机质丰度、溶解性有机碳浓度及分子量有关;此外,胶体的腐殖化程度、芳环上羧基、羰基等官能团的比重及荧光物质中溶解性微生物代谢产物和类腐殖酸对CAP的吸附行为也具有较大影响.     

铁锰复合氧化物滤料去除地下水中四环素的效能

以化学挂膜成熟运行5a的铁锰复合氧化物滤料为研究对象,利用静态与连续流柱实验相结合的方式,探究了该滤料去除四环素的效果与机理.结果表明,去除过程符合准二级反应动力学模型;且滤料质量越大,初始浓度越高,对四环素去除的效果越好;当水中共存阳离子浓度为0.01mol/L时,Mg²⁺抑制四环素的去除,而Ca²⁺、K⁺对四环素的去除过程无显著影响.连续流柱实验与发光细菌毒性检测分析,表明,铁锰氧化物滤料对四环素去除效果显著高于石英砂,且铁锰复合氧化物滤料去除四环素后急性毒性降低.此外,机理探究实验结果证实了铁锰复合氧化物滤料去除四环素是吸附与氧化的过程.     

Acceleration of floc-water separation and floc reduction with magnetic nanoparticles during demulsification of complex waste cutting emulsions

Waste cutting emulsions are difficult to treat efficiently owing to their complex composition and stable emulsified structure. As an important treatment method for emulsions, chemical demulsification is faced with challenges such as low flocs–water separation rates and high sludge production. Hence, in this study, Fe₃O₄ magnetic nanoparticles (MNPs) were used to enhance chemical demulsification performance for treating waste cutting emulsions under a magnetic field. The addition of MNPs significantly decreased the time required to attain sludge–water separation and sludge compression equilibrium, from 210 to 20 min. In addition, the volume percentage of sludge produced at the equilibrium state was reduced from 45% to 10%. This excellent flocculation–separation performance was stable over a pH range of 3–11. The magnetization of the flocculants and oil droplets to form a flocculant–MNP–oil droplet composite, and the magnetic transfer of the composite were two key processes that enhanced the separation of cutting emulsions. Specifically, the interactions among MNPs, flocculants, and oil droplets were important in the magnetization process, which was controlled by the structures and properties of the three components. Under the magnetic field, the magnetized flocculant–MNP–oil droplet composites were considerably accelerated and separated from water, and the sludge was simultaneously compressed. Thus, this study expands the applicability of magnetic separation techniques in the treatment of complex waste cutting emulsions.     

An investigation of changes in water quality throughout the drinking water production/distribution chain using toxicological and fluorescence analyses

Changes in water quality from source water to finished water and tap water at two conventional drinking water treatment plants(DWTPs) were monitored.Beside the routine water quality testing,Caenorhabditis elegans-based toxicity assays and the fluorescence excitation–emission matrices technique were also applied.Both DWTPs supplied drinking water that met government standards.Under current test conditions,both the investigated finished water and tap water samples exhibited stronger lethal,genotoxic and reprotoxic potential than the relative source water sample,and the tap water sample was more lethal but tended to be less genotoxic than the corresponding finished water sample.Meanwhile,the nearly complete removal of tryptophan-like substances and newly generated tyrosine-like substances were observed after the treatment of drinking water,and humic-like substances were identified in the tap water.Based on these findings,toxic pollutants,including genotoxic/reproductive toxicants,are produced in the drinking water treatment and/or distribution processes.Moreover,further studies are needed to clarify the potentially important roles of tyrosine-like and humic-like substances in mediating drinking water toxicity and to identify the potential sources of these contaminants.Additionally,tryptophan-like fluorescence may be adopted as a useful parameter to monitor the treatment performance of DWTPs.Our observations provided insights into the importance of utilizing biotoxicity assays and fluorescence spectroscopy as tools to complement the routine evaluation of drinking water.     

浙江海宁某典型制革污泥堆场污染分布特征

为研究典型制革污泥堆场区域污染情况,以浙江海宁某制革污泥堆场为研究对象,研究了制革污泥堆场土壤和地下水中有机物和重金属的污染情况。调查结果表明:土壤中无机污染很小,而总铬、六价铬和铅含量较高。污染土壤中铅和总铬含量分别是工业用地规定值的2.82,7.03倍,而六价铬最高含量为管控值的2.8倍。地下水中氨氮含量超标严重,达到1268.0 mg/L,是GB/T 14848—2017《地下水质量标准》中工农业Ⅴ类用水下限值的845.3倍,六价铬的含量<0.004 mg/L。此外,各取样点六价铬和总铬含量的垂直分布显示较大的差异,也与某些制革污泥堆场的重金属垂直分布规律不尽相同。