Policy evaluation of vehicle exhaust standards in Japan from 1995 to 2005 based on two human health risk indices for air pollution and global warming

Measures for vehicle exhaust emissions aimed at reducing either air pollution or global warming could have counterproductive effects on one another. Increasing diesel passenger vehicles, which generally have lower CO₂ emissions than gasoline counterparts, leads to increasing particulate matter (PM) emissions, while gasoline has lower PM emissions than diesel. It is said that stringent limits on PM emission factors discourages improved CO₂ emission factors. Without including both effects in a risk evaluation, one cannot evaluate whether the total risk is reduced or not. Hence, we evaluated representative exhaust emission measures based on risk evaluation for both air pollution and global warming. Considering consumer choice between diesel and gasoline passenger vehicles and emissions standards adopted in Japan from 1995 to 2005, we built five cases for vehicle policy evaluation. For each case, we estimated disability-adjusted life years (DALY) as an index of human health risk caused by lung cancer linked to inhalation exposure of elemental carbon in PM as well as due to global warming linked to CO₂. The results of our risk evaluation reveal that the case adopting the 2005 new long-term Japanese emission standard reduces the human health risk caused by lung cancer due to air pollution by 0.6 × 10³ DALY, but would increase the risk due to global warming by 31.9 × 10³ DALY compared with the case of adopting EURO 4, for the same conditions of passenger vehicle choice from 1995. These results suggest that the characteristics of Japanese emissions standards are mainly designed to reduce air pollution.     

Quantitative analysis of perfluorinated chemicals in media for in vitro fertilization and related samples

The actual standard in vitro fertilization (IVF) protocol recommends an overnight gamete co-incubation. All of the culture media used for human IVF are supplemented with serum or albumin. In the present study, we determined the concentrations of perfluorinated chemicals (PFCs) in IVF media (IVFM) and related samples by liquid chromatography with tandem mass spectrometry (LC/MS/MS). The results indicated that the concentrations of PFOS and PFOA in the protein source were higher than those in the IVFM samples. Compared with human plasma concentrations of PFCs, PFCs in all of the IVFM samples, such as PFBS, PFHxS and PFOA, were either not detected or present at only trace levels, even when protein source was added. LC/MS/MS could be used to determine PFCs in IVFM samples in future studies of the effects of PFC exposure on intrauterine insemination.     

Effect of density-driven flow on the through-diffusion experiment

Diffusion is one of the main mechanisms of solute transport in pore water of geologic media. The effective diffusion coefficient of a solute in a rock is usually measured by the through-diffusion experiment. However, in this experiment, the effect of advection, induced by density difference between dense aqueous solution and pure water, has not been considered. To evaluate the effect of density-driven flow, a through-diffusion experiment using Fontainebleau sandstone was conducted for KCl and KI aqueous solutions with various densities. The measured effective diffusion coefficients were positively correlated with the density difference; the effective diffusion coefficient of a 1 M KI solution (density difference, 0.119 g/cm³) was one order of magnitude larger than that of a 0.1 M KCl solution (density difference, 0.005 g/cm³). The result is explained by a theoretical model using a diffusion–advection equation including Darcy's law. Based on the theory, a diagram to evaluate the condition at which the measured effective diffusion coefficient does not include the effect of advection is presented.     

Improvement of an efficient separation method for chemicals in diesel exhaust particles: analysis for nitrophenols

GOAL, SCOPE, AND BACKGROUND: Diesel exhaust is believed to consist of thousands of organic constituents and is a major cause of urban pollution. We recently reported that a systematic separation procedure involving successive solvent extractions, followed by repeated column chromatography, resulted in the isolation of vasodilatory active nitrophenols. These findings indicated that the estimation of the amount of nitrophenols in the environment is important to evaluate their effect on human health. The isolation procedure, however, involved successive solvent extractions followed by tedious, repeated chromatography, resulting in poor fractionation and in a significant loss of accuracy and reliability. Therefore, it was crucial to develop an alternative, efficient, and reliable analytical method. Here, we describe a facile and efficient acid-base extraction procedure for the analysis of nitrophenols. MATERIALS AND METHODS: Diesel exhaust particles (DEP) were collected from the exhaust of a 4JB1-type engine (ISUZU Automobile Co., Tokyo, Japan). Gas chromatography-mass spectrometry (GC-MS) analysis was performed with a GCMS-QP2010 instrument (Shimadzu, Kyoto, Japan). RESULTS: A solution of DEP in 1-butanol was extracted with aqueous NaOH to afford a nitrophenol-rich oily extract. The resulting oil was methylated with trimethylsilyldiazomethane and subsequently subjected to GC-MS analysis, revealing that 4-nitrophenol, 3-methyl-4-nitrophenol, 2-methyl-4-nitrophenol, and 4-nitro-3-phenylphenol were present in significantly higher concentrations than those reported previously. DISCUSSION: Simple acid-base extraction followed by the direct analysis of the resulting extract by GC-MS gave only broad peaks of nitrophenols with a poor detection limit, while the GC-MS analysis of the sample pretreated with (trimethylsilyl)diazomethane gave satisfactorily clear chromatograms with sharp peaks and with a significantly lowered detection limit (0.5 ng/ml, approximately 100 times). CONCLUSION: The present method involving an acid-base extraction, in situ derivatization, and GC-MS analysis has shown to be a simple, efficient, and reliable method for the isolation and identification of the chemical substances in DEP.     

Distribution of six anticancer drugs and a variety of other pharmaceuticals,and their sorption onto sediments,in an urban Japanese river

Environmental Science and Pollution Research - The distributions of 31 pharmaceuticals grouped into nine therapeutic classes, including six anticancer drugs, were investigated in the waters and...     

The effects of current water management practices on methane emissions in Japanese rice cultivation

Cultivated wetland rice fields are a source of methane (CH₄) emissions. To estimate CH₄ emissions and develop policies to reduce such emissions, information on water management at the farm level is crucial. It is known that farmers implement midseason drainage (MD) to increase rice yields and save water. However, little is known about whether MD is carried out in soils where CH₄ emissions are high and how part-time status will influence management. The objective of this study is to identify factors that determine MD implementation using a binomial logistic regression model based on a farm-level survey in Japan and to indicate possible changes in estimates of CH₄ emissions, accounting for current water management practices. The implementation rates were significantly higher where the soil types were classified as having the potential for high CH₄ emissions. Under current water management practices, the duration of MD and the percentage of continuous flooding were 5 to 7 days longer and approximately 7 % higher, respectively, than the values used by the Greenhouse Gas Inventory Office of Japan, which in turn are used to report greenhouse gas emissions to the United Nations Framework Convention on Climate Change. By accounting for current water conditions with the Tier 2 method, this study indicates that national estimates of CH₄ emissions from rice straw application areas could be lowered by 12.7 %. These results may contribute to the development of a mitigation policy that will help to further reduce CH₄ emissions.