岩溶石笋的古环境研究进展

全球变化研究的热点问题是获得十年到百年甚至年月分辨的气候变化规律。岩溶石笋因其诸多优点 ,将在古环境研究中发挥越来越重要的作用。本文从当前研究的现状出发 ,在石笋微层年层对比、微层形成机制、稳定同位素记录、灰度、生长率、微量元素以及紫外激光诱发荧光等方面的研究进行了综述 ,并结合自身研究成果 ,提出了自己的看法     

1947年广东大水灾及地方政府应对——以《广东全省水灾紧急救助委员会会刊》为中心的考察

1947年夏,广东省遭遇数十年来罕见特大水灾,给全省人民的生命和财产带来了不可估量的巨大损失,同时也引起了广东省地方政府的密切关注.面对突如其来的灾害,广东省政府在第一时间内成立广东省水灾紧急救助委员会,具体负责灾后救助与重建事宜.此次水灾,广东省地方政府有力作为,发挥了上下联动、内外配合的优势,在勘灾、筹募、赈济等环节形成一套较为完备的应对机制,弥补了中央政府在特殊时期由于兵祸连年,财政匮乏而导致应灾机制的不足,一定程度上收到较好的效果.     

Heterogeneous UV/Fenton degradation of bisphenol A catalyzed by synergistic effects of FeCo2O4/TiO2/GO

A new method for bisphenol A (BPA) degradation in aqueous solution was developed. The characteristics of BPA degradation in a heterogeneous ultraviolet (UV)/Fenton reaction catalyzed by FeCo₂O₄/TiO₂/graphite oxide (GO) were studied. The properties of the synthesized catalysts were characterized using scanning electron microscopy, X-ray diffraction, and vibrating sample magnetometry. FeCo₂O₄ and TiO₂ were grown as spherical shape, rough surface, and relatively uniform on the surface of GO (FeCo₂O₄/TiO₂/GO). Batch tests were conducted to evaluate the effects of the initial pH, FeCo₂O₄/TiO₂/GO dosage, and H₂O₂ concentration on BPA degradation. In a system with 0.5 g L⁻¹ of FeCo₂O₄/TiO₂/GO and 10 mmol L⁻¹ of H₂O₂, approximately 90 % of BPA (20 mg L⁻¹) was degraded within 240 min of UV irradiation at pH 6.0. The reused FeCo₂O₄/TiO₂/GO catalyst retained its activity after three cycles, which indicates that it is stable and reusable. The heterogeneous UV/Fenton reaction catalyzed by FeCo₂O₄/TiO₂/GO is a promising advanced oxidation technology for treating wastewater that contains BPA.

     

Mechanism of the intermittent motion of two-phase debris flows

A typical two-phase debris flow exhibits a high and steep flow head consisting of rolling boulders and cobbles with intermittent or fluctuating velocity. The relative motion between the solid phase and the liquid phase is obvious. The motion of a two-phase debris flow depends not only on the rheological properties of the flow, but also on the energy transmission between the solid and liquid phases. Several models have been developed to study two-phase debris flows. An essential shortcoming of most of these models is the omission of the interaction between the two phases and identification of the different roles of the different materials in two-phase debris flows. The tracer particles were used for the velocity of solid phase and the velocity of liquid phase was calculated by the water velocity on the surface of the debris flow in the experiments. This paper analyzed the intermittent feature of two-phase debris flows based on videos of debris flows in the field and flume experiments. The experiments showed that the height of the head of the two-phase debris flow increased gradually in the initiation stage and reached equilibrium at a certain distance from the start of the debris flow. The height growth and the velocity of the flow head showed fluctuating characteristics. Model equations were established and the analyses proved that the average velocity of the two-phase debris flow head was proportional to the flood discharge and inversely proportional to the volume of the debris flow head.     

UV/Fenton技术处理某工厂高浓度乳化油废水

研究了UV/Fenton技术对高浓度金属清洗乳化油废水的处理效果,考察了亚铁与双氧水浓度、pH、反应时间和搅拌对COD去除效果的影响。实验结果表明,UV/Fenton技术对高浓度乳化油废水(COD平均浓度为35 000 mg/L)具有较高的去除效果,最佳工艺条件为:亚铁与双氧水浓度分别为2 400 mg/L和6 000 mg/L,pH为3,经过2 h反应,COD可降低至1 050 mg/L,去除率为97%。搅拌会降低COD的去除率。研究表明,UV/Fenton技术对高浓度乳化油废水具有很好的降解效果,且药品消耗较低,为目前此类高浓度有机废水的处理提供了技术参考。     

水泥窑共处置过程中水泥生料对砷的吸附/冷凝特性

针对水泥生料开展了氮吸附与SEM测试分析,研究了水泥生料的比表面积,孔径结构和微观表面积。同时,利用管式回转炉和控温立式炉联用装置研究了砷元素在水泥生料上的吸附冷凝特性。结果表明,水泥生料的比表面积很小,微观表面结构致密无孔,砷元素主要是冷凝在生料表面上。进入吸附冷凝炉的重金属可以分为3部分,第1部分冷凝在管壁上,占80%左右;第2部分吸附/冷凝在生料上,占10%左右;第3部分随烟气释放到空气中,不到10%。水泥生料对砷的吸附冷凝量随时间的增加而增加,随温度的升高而降低。水泥生料对砷的吸附冷凝特性可用双常数速率方程拟合,拟合效果较好,计算得表观活化能在6~7 kJ/mol之间。此外,砷的初始浓度对水泥生料的吸附冷凝特性影响很小。     

Pseudomonas sp.fz胞外分离物降解四溴双酚A

四溴双酚A(TBBPA)是全球消耗量最大的溴系阻燃剂。通过活性物质的定位、分离和TBBPA产物的分析等步骤,对Pseudomonas sp.fz胞外分离物降解TBBPA进行了研究。结果表明,存在于胞外的活性物质通过异丙基断裂和脱溴两条途径降解TBBPA。通过超滤,Sephadex G-10分离纯化得到了具有降解活性的小分子物质,分子量约为376~456 Da,初步鉴定为短肽类物质。这种小分子物质具有很好的热稳定性(30~80℃),在弱酸性条件下(2.0~5.0)活性较高,其活性还受金属离子、氧气和抑制剂(Na N3)的影响。此外,部分纯化的小分子物质在一定条件下能够产生羟基自由基(·OH)。     

Theoretical equation of gas desorption of particle coal under the non-uniform pressure condition and its analytical solution

Based on the second Fick’s law, the theoretical equation of gas desorption of particle coal under the non-uniform pressure condition was developed in this paper. The analytical solution of the theoretical equation and the method of gas desorption quantity of particle coal under non-uniform pressure condition were obtained.     

取芯过程中煤芯温度分布特征模拟研究*

针对取芯过程瓦斯解吸受煤芯的温度影响不明,造成煤层瓦斯含量测不准的问题,开展对取芯过程煤芯温度分布特征研究。采用自主研制的取芯管自动测温装置在赵固二矿原生结构煤层（f=1.71）进行深度20 m的取芯试验,获得取芯管管壁温升变化规律,变化曲线分为4个阶段:缓慢上升、加速上升、减速上升、缓慢下降阶段;应用COMSOL建立含瓦斯煤传热模型,将管壁的温度变化设置为边界条件,模拟取芯过程煤芯与管壁之间的热交换。结果表明:在取芯时间30 min内,煤芯平均温度快速上升,之后上升速度趋于平稳;在煤芯内,相同时刻,等间距的轴向与径向距离,径向较轴向的温度梯度较大,径向传导快于轴向传导;取芯过程煤芯径向温度Ta与径向距离d、时间t满足指数函数关系。研究结果可为测定取芯过程煤芯的瓦斯损失量提供参考依据。     

Screening of indicator pharmaceuticals and personal care products in landfill leachates: a case study in Shanghai,China

● A systematic framework was developed to identify i-PPCPs for landfill leachate. ● The wide-scope target analysis offered a basis for comprehensive i-PPCP screening. ● Source-specificity and representativeness analysis helped to refine i-PPCPs. ● Erythromycin, gemfibrozil and albendazole were identified as i-PPCPs for leachate. Identifying potential sources of pharmaceuticals and personal care products (PPCPs) in the environment is critical for the effective control of PPCP contamination. Landfill leachate is an important source of PPCPs in water; however, it has barely been involved in source apportionment due to the lack of indicator-PPCPs (i-PPCPs) in landfill leachates. This study provides the first systematic framework for identifying i-PPCPs for landfill leachates based on the wide-scope target monitoring of PPCPs. The number of target PPCPs increased from < 20 in previous studies to 68 in the present study. Fifty-nine PPCPs were detected, with median concentrations in leachate samples ranging from below the method quantification limit (MQL) to 41 μg/L, and 19 of them were rarely reported previously. A total of 29 target compounds were determined to be PPCPs of high concern by principal component analysis according to multiple criteria, including occurrence, exposure potential, and ecological effect. Coupled with source-specificity and representativeness analysis, erythromycin, gemfibrozil, and albendazole showed a significant difference in their occurrence in leachate compared to other potential sources (untreated and treated municipal wastewater and livestock wastewater) and correlated with total PPCP concentrations; these were recommended as i-PPCPs for leachates. Indicator screening procedure can be used to develop a sophisticated source apportionment method to identify sources of PPCPs from adjacent landfills.