Construction of vesicle CdSe nano-semiconductors photocatalysts with improved photocatalytic activity: Enhanced photo induced carriers separation efficiency and mechanism insight

Visible-light-driven photocatalysis as a green technology has attracted a lot of attention due to its potential applications in environmental remediation. Vesicle Cd Se nano-semiconductor photocatalyst are successfully prepared by a gas template method and characterized by a variety of methods. The vesicle Cd Se nano-semiconductors display enhanced photocatalytic performance for the degradation of tetracycline hydrochloride, the photodegradation rate of78.824% was achieved by vesicle Cd Se, which exhibited an increase of 31.779% compared to granular Cd Se. Such an exceptional photocatalytic capability can be attributed to the unique structure of the vesicle Cd Se nano-semiconductor with enhanced light absorption ability and excellent carrier transport capability. Meanwhile, the large surface area of the vesicle Cd Se nano-semiconductor can increase the contact probability between catalyst and target and provide more surface-active centers. The photocatalytic mechanisms are analyzed by active species quenching. It indicates that h+and UO_2~-are the main active species which play a major role in catalyzing environmental toxic pollutants. Simultaneously, the vesicle Cd Se nano-semiconductor had high efficiency and stability.     

基于安全价值工程的煤矿安全隐患优先决策方法

在分析安全价值工程基本原理的基础上,以某煤矿企业为例,介绍了基于安全价值工程的煤矿安全隐患优先解决决策的过程、方法,对所需解决各种安全隐患进行了排序.结果表明,与传统经验决策法比,该方法更科学,结果更合理.     

省内公路可移动危险源的模糊综合安全预警

为了对公路可移动危险源进行有效控制,分析了影响公路可移动危险源危险程度的因素,采用模糊综合评判方法,并通过公路可移动危险源模糊预警系统实现了公路可移动危险源的实时综合安全预警.结果表明,此方法考虑危险因素较全面,且可在屏幕实时显示各公路可移动危险源的预警结果,有利于提高安全管理水平.     

Coping with the liquidity crisis: a new dynamic quota readjustment scheme for carbon markets

Environmental Geochemistry and Health - Because of insufficient liquidity, prices in the carbon market are more vulnerable to unexpected events, for which the impact duration lasts longer than that...     

邻水区域化工企业突发性水污染事故致因模式分析

为了减少和杜绝邻水区域化工企业突发性水污染事故的发生,在分析其突发性水污染事故原因基础上,提出并分析了两种及以上危险态物质耦合与协同的化工事故致因模式和邻水区域化工项目突发性水污染事故致因模式,并通过实例进行了阐释。     

异形阻燃木-混凝土组合梁耐火特性实验*

为提高纯木梁的耐火性能,提出异形阻燃木-混凝土组合梁提高耐火性能的方法。通过实验研究对比Π形、T形的异形阻燃木-混凝土组合梁与全混凝土梁受火特性和剩余承载力。研究结果表明:3面受火后,异形阻燃木-混凝土组合梁上部多数区域未达强度降低起始温度,全混凝土梁均超过强度降低起始温度,且受火温度远远高于木-混凝土组合梁;T形阻燃木-混凝土组合梁试件剩余承载力最大,耐火能力最强,Π形阻燃木-混凝土组合梁次之,全混凝土梁最差;异形阻燃木-混凝土组合梁受火后损坏情况轻于全混凝土梁,但产烟量大于全混凝土梁。     

Performance of bimetallic nanoscale zero-valent iron particles for removal of oxytetracycline

In this study, bimetallic nanoscale zero-valent iron particles(nZVI), including copper/nanoscale zero-valent iron particles(Cu/nZVI) and nickel/nanoscale zero-valent iron particles(Ni/nZVI), were synthesized by one-step liquid-phase reduction and applied for oxytetracycline(OTC) removal. The effects of contact time and initial p H on the removal efficiency were studied. The as-prepared nanoscale particles were characterized by scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray diffraction(XRD). Finally, the degradation mechanisms of OTC utilizing the as-prepared nanoparticles were investigated by using X-ray photoelectron spectroscopy(XPS) and mass spectrometry(MS). Cu/n ZVI presented remarkable ability for OTC degradation and removed71.44% of OTC(100 mg/L) in 4 hr, while only 62.34% and 31.05% of OTC was degraded by Ni/nZVI and nZVI respectively. XPS and MS analysis suggested that OTC was broken down to form small molecules by ·OH radicals generated from the corrosion of Fe0. Cu/nZVI and Ni/n ZVI have been proved to have potential as materials for application in OTC removal because of their significant degradation ability toward OTC.     

Have driving restrictions reduced air pollution: evidence from prefecture-level cities of China

Environmental Science and Pollution Research - With rapid economic development, air pollution became a serious problem in China. Vehicle’s exhaust emissions are among the main sources of air...     

高分子复混溶胀胶体材料防治半前进式工作面煤炭自燃技术的研究

高分子复混溶胀胶体材料具有固水性强、脱水缓慢、脱水后遇水可再生、与煤粘附性强、能形成焦化层、流动性和渗透性好及无毒、无味、无腐蚀、高温无烟等特性。长期以来 ,半前进式工作面防治煤炭自燃技术措施中 ,一直未采用高分子复混溶胀胶体材料。徐州矿务集团公司张集矿在自燃煤层的 74 2 3工作面半前进式开采中 ,采用了高分子复混溶胀胶体材料封堵沿空留巷漏风、喷洒覆盖采空区遗煤、封闭联络巷道等为主的综合防灭火技术与措施 ,取得了良好的效果 ,采空区漏风率降到 4 .35 % ,工作面开采期间杜绝了煤炭自燃隐患的出现 ,因此 ,高分子复混溶胀胶体材料防治半前进式工作面煤炭自燃技术是成功的     

基于 Fl ue nt 的压气水自吸风喷雾与常规喷雾比较分析

利用Fluent软件分别对压气水自吸风喷雾与常规喷雾进行了数值模拟,并对二者的内部流场进行了比较分析,另外,还比较了相同截面距离下二者的雾滴粒径大小,实验结果表明,相对于常规喷雾降尘,采用压气水自吸风喷雾降尘的效果要更好。