Hexachlorocyclohexane (HCH) as new Stockholm Convention POPs��a global perspective on the management of Lindane and its waste isomers

Purpose

Hexachlorocyclohexane (HCH) isomers (??-, ??- and ??- (Lindane)) were recently included as new persistent organic pollutants (POPs) in the Stockholm Convention, and therefore, the legacy of HCH and Lindane production became a contemporary topic of global relevance. This article wants to briefly summarise the outcomes of the Stockholm Convention process and make an estimation of the amount of HCH waste generated and dumped in the former Lindane/HCH-producing countries.

Results

In a preliminary assessment, the countries and the respective amount of HCH residues stored and deposited from Lindane production are estimated. Between 4 and 7 million tonnes of wastes of toxic, persistent and bioaccumulative residues (largely consisting of alpha- (approx. 80%) and beta-HCH) are estimated to have been produced and discarded around the globe during 60 years of Lindane production. For approximately 1.9 million tonnes, information is available regarding deposition. Countries are: Austria, Brazil, China, Czech Republic, France, Germany, Hungary, India, Italy, Japan, Macedonia, Nigeria, Poland, Romania, Slovakia, South Africa, Spain, Switzerland, Turkey, The Netherlands, UK, USA, and former USSR. The paper highlights the environmental relevance of deposited HCH wastes and the related POPs?? contaminated sites and provides suggestions for further steps to address the challenge of the legacy of HCH/Lindane production.

Conclusion

It can be expected that most locations where HCH waste was discarded/stockpiled are not secured and that critical environmental impacts are resulting from leaching and volatilisation. As parties to the Stockholm Convention are legally required to take action to stop further POPs pollution, identification and evaluation of such sites are necessary.     

Coagulant recovery from water treatment plant sludge and reuse in post-treatment of UASB reactor effluent treating municipal wastewater

In the present study, feasibility of recovering the coagulant from water treatment plant sludge with sulphuric acid and reusing it in post-treatment of upflow anaerobic sludge blanket (UASB) reactor effluent treating municipal wastewater were studied. The optimum conditions for coagulant recovery from water treatment plant sludge were investigated using response surface methodology (RSM). Sludge obtained from plants that use polyaluminium chloride (PACl) and alum coagulant was utilised for the study. Effect of three variables, pH, solid content and mixing time was studied using a Box–Behnken statistical experimental design. RSM model was developed based on the experimental aluminium recovery, and the response plots were developed. Results of the study showed significant effects of all the three variables and their interactions in the recovery process. The optimum aluminium recovery of 73.26 and 62.73 % from PACl sludge and alum sludge, respectively, was obtained at pH of 2.0, solid content of 0.5 % and mixing time of 30 min. The recovered coagulant solution had elevated concentrations of certain metals and chemical oxygen demand (COD) which raised concern about its reuse potential in water treatment. Hence, the coagulant recovered from PACl sludge was reused as coagulant for post-treatment of UASB reactor effluent treating municipal wastewater. The recovered coagulant gave 71 % COD, 80 % turbidity, 89 % phosphate, 77 % suspended solids and 99.5 % total coliform removal at 25 mg Al/L. Fresh PACl also gave similar performance but at higher dose of 40 mg Al/L. The results suggest that coagulant can be recovered from water treatment plant sludge and can be used to treat UASB reactor effluent treating municipal wastewater which can reduce the consumption of fresh coagulant in wastewater treatment.     

Synergistic effect of Eugenia jambolana Linn. and Solidago canadensis Linn. leaf extracts with deltamethrin against the dengue vector Aedes aegypti Linn. at Mysore

With the goal in mind to minimize the application of environmentally hazardous chemical insecticides, the larvicidal activity of two plant extracts along with deltamethrin was studied at University of Mysore. The extracts of Solidago canadensis and Eugenia jambolana were employed for working out the synergistic efficacy against Aedes aegypti larvae, as the extracts of both the plants exhibited high efficacy when applied individually. The deltamethrin when analyzed separately, LC₅₀ and LC₉₀ values were 0.00045 and 0.00148 ppm, respectively. Synergistic studies with two plant extracts on deltamethrin revealed S. canadensis as more effective with synergistic factor(SF) of 4.090 for LC₅₀ value and 4.781 for LC₉₀ followed by E. jambolana with SF 1.80 for LC₅₀ and 2.467 for LC₉₀ at 1:1 ratio of the phytoextracts and deltamethrin. Thus, S. canadensis was found to be a better larvicidal and synergistic agent. Combination of phytochemical and insecticide were found to be more effective than insecticides or phytochemicals alone which could be a good ecofriendly and cost-effective approach to reduce the dose of chemicals with high residual effect to be applied in vector control programs.     

Seasonal variation of HCH isomers in open soil and plant-rhizospheric soil system of a contaminated environment

Background, aim, and scope  

Lindane, technically 1, 2, 3, 4, 5, 6-hexachlorocyclohexane (γ- HCH), is the most commonly detected organochlorine pesticide from diverse environmental compartments. Currently, India is the largest consumer and producer of lindane in the world. The production of lindane results in the generation of large quantities of waste HCH isomers (mainly α-, β- and δ-). All these isomers are toxic and have a long-range environmental transport potential. The aim of this study was to monitor the seasonal variation of HCH isomers in an open soil–plant–rhizospheric soil system of a contaminated industrial area. For this, selected plant species and their rhizospheric soil (soil samples collected at a depth range of 0–45 cm near to the root system) and open soil samples (soil samples collected (0–30 cm depth) from 1–1.5 m away from the plant root system) were collected for 2 years (two summer seasons and two winter seasons).     

Investigation of modified horizontal wing cut twisted tapes fitted with rod and spacer at trailing edge on heat transfer properties in Double Glazing V-Trough solar water heaters

An experimental analysis of heat transfer efficiency in double glazing solar water heating system having full-length Horizontal wing cut twisted tapes having twist ratio 3 fitted with rod or spacer of dimensions 125 mm, 250 mm, and 500 mm as length at the trailing edges has been dealt in this work. The experimental results have been compared with a plain tube with similar operating conditions and concluded that variation in the Nusselt number, as well as friction factor, are ±12.56% and ±10.17%, respectively. The result of empirical correlation concludes that Nusselt number is maximal for horizontal wing cut twisted tapes having rod or spacer at its ends while comparing with full-length horizontal wing cut twisted tapes. The friction factor is low for full-length horizontal wing cut twisted tapes than the horizontal wing cut twisted tapes fitted with rod or spacer. The horizontal wing cut twisted tapes fitted with rod has superior performance than twist fitted with spacer.     

Effect of chlorine pollution on three fruit tree species at Ranoli near Baroda, India

This paper describes the effect of chlorine pollution from an alkalies and chemical plant at Ranoli, near Baroda, on three tropical fruit tree species-Mangifera indica L. (mango) Manilkara hexandra Dubard. (rayan) and Syzygium cumini Skeels (Jamun). As compared to controls growing in a less polluted area, trees growing close to the plant showed reduced mean leaf area, a higher percentage of leaf area damaged, a reduction in fruit yield, chlorophyll pigments, protein and carbohydrate content, and higher accumulation of chloride in the foliar tissues. The accumulation of pollutaant, chloride, in the foliar tissues was very high in mango and jamun. Based on the degree of damage to the plants, the species studied were arranged in decreasing order of their sensitivity to chlorine pollution-mango, jamun and rayan.     

Can rare positive interactions become common when large carnivores consume livestock?

Livestock populations in protected areas are viewed negatively because of their interaction with native ungulates through direct competition for food resources. However, livestock and native prey can also interact indirectly through their shared predator. Indirect interactions between two prey species occur when one prey modifies either the functional or numerical responses of a shared predator. This interaction is often manifested as negative effects (apparent competition) on one or both prey species through increased predation risk. But indirect interactions can also yield positive effects on a focal prey if the shared predator modifies its functional response toward increased consumption of an abundant and higher-quality alternative prey. Such a phenomenon between two prey species is underappreciated and overlooked in nature. Positive indirect effects can be expected to occur in livestock-dominated wildlife reserves containing large carnivores. We searched for such positive effects in Acacia-Zizhypus forests of India's Gir sanctuary where livestock (Bubalus bubalis and Bos indicus) and a coexisting native prey (chital deer, Axis axis) are consumed by Asiatic lions (Panthera leo persica). Chital vigilance was higher in areas with low livestock density than in areas with high livestock density. This positive indirect effect occurred because lion predation rates on livestock were twice as great where livestock were abundant than where livestock density was low. Positive indirect interactions mediated by shared predators may be more common than generally thought with rather major consequences for ecological understanding and conservation. We encourage further studies to understand outcomes of indirect interactions on long-term predator-prey dynamics in livestock-dominated protected areas.     

Motorcycle helmet use in Calicut,India: User behaviors,attitudes, and perceptions

Objectives: The objectives of this study include assessing the motorcycle helmet use pattern in Calicut, India, and analyzing the factors influencing helmet use including motorcyclists' perceptions.

Methods: Field observational studies at 15 locations were conducted to determine the helmet use rate among motorcyclists and pillion passengers. A structured questionnaire interview survey was conducted with 709 motorcyclists to evaluate the users' perceptions and opinions regarding the use of motorcycle helmets.

Results: There was a considerable difference in the level of motorcycle helmet use observed between the locations within and outside the city limits, where different levels of helmet law enforcement were exercised. The helmet use was observed at a maximum of 89% within the city and a minimum of 23% in some locations outside the city. The decreasing percentage of helmet use while moving toward the locations outside the city was confirmed statistically through t tests (t = 1.771, df = 13, P < .05). It was found that only 42% of users revealed that helmets are comfortable and 42% expressed that helmets affect hearing ability. It is important to note that 57% of users are of the opinion that there is no need to use a helmet if you drive slowly and carefully. The price of the helmet was not a deterrent for helmet use. In addition, it was observed that only 45% of helmets used by the motorist were standard helmets with an Indian Standards Institute (ISI) mark.

Conclusion: The widely varying helmet use pattern observed in the study area may be attributed due to the users' behaviors; that is, using a helmet only when the helmet law is strictly enforced rather than using a helmet as a protective device. Further, some of the problems and beliefs associated with helmet use prevent motorcyclists from using a helmet. Hence, the road safety of motorcyclists can be improved only through addressing the identified measures comprehensively.