Characterization of titanium oxide optical band gap produced from leachate sludge treatment with titanium tetrachloride

Environmental Science and Pollution Research - This study investigated the coagulation performance of titanium tetrachloride (TiCl4) for leachate treatment and preparation of titanium oxide (TiO2)...     

The trade-off between economic growth and environmental quality: does economic freedom asymmetric matter for Pakistan?

Environmental Science and Pollution Research - This empirical study investigates the dynamic effects of economic freedom on economic growth and air quality for Pakistan over the period...     

Fractionation and Sequential Extraction of Heavy Metals in the Soil of Scrapyard of Discarded Vehicles

Chemical and physical size fractionation of heavy metals were carried out on 20 soil samples from the scrap yard area. Tessier method was used in sequential extraction. Cadmium showed the highest levels among the other elements studied in the exchangeable fraction (about 33%), while other elements showed low levels in this fraction (≥1%). Lead and manganese were mostly found in the Fe–Mn oxide fraction, zinc and iron were mostly in residual fraction, while copper was mostly found in the organic fraction of the soil. Soil samples were size-fractionated into four sizes: 1000–500, 500–125, 125–53, and less than 53 μm. The highest levels of Fe, Cu, Pb, Mn, and Cd were found in the medium fraction (500–125 μm), while zinc showed its highest levels in the fine fraction (125–53 μm). The order of heavy metal load in the size fractions was found to be medium > fine > coarse > silt for Fe, Mn, Cu, Pb, and Cd, where it was found as fine > medium > coarse > silt for zinc.     

Scenario-based urban growth allocation in a rapidly developing area: a modeling approach for sustainability analysis of an urban-coastal coupled system

Being located in an urban-coastal coupled system, the Hashtpar City is one of the most attractive areas for urban construction, tourism, agricultural activities and environmental protection in northern Iran. To resolve the issues between land developers and environmental conservation agencies, we conducted a scenario-based urban growth allocation procedure through the SLEUTH model. The scenarios consisted of ‘business as usual’, ‘managed urban growth’ and ‘environmentally sound growth’ that were introduced by modification of model parameters and exclusion layer. The resultant urban growth arrangements were compared for composition and configuration attributes of landscape patterns. According to the results, the pattern of urbanized lands under managed urban growth option demonstrated better connectivity and compactness of urban patches, while the two other scenarios generated a highly fragmented pattern. The managed urban growth can be considered as a compromised solution between other scenarios since it simultaneously takes into accounts both developers and environment protectors points’ of views. On this basis, a combination of centralized and decentralized urban land use planning is a recommended strategy for our urban-coastal environment to fulfill the purposes of a sustainable development process. The findings of the present article suggest that further expansion of the major urban core in the targeted area should be prohibited since it can lead to an urban patch with considerable physical size and noticeable ecological footprint.     

Effect of Bimetallic Soybean Oil Based Polymer on Growth and Plasma Membrane H+-ATPase Activity Among Fungi

In view of bio-inorganic importance, iron and zinc incorporated soybean oil based polymer was prepared by condensation polymerization of oil based fatty amide polyole, sebacic acid, zinc acetate and ferric chloride in a process initiated by sodium ethoxide. Microwave assisted synthesis was used throughout the reaction as it is ecofriendly and requires minimal usage of solvents. Physical techniques such as FT-IR and ¹HNMR have been used to establish the structure of the polymers. Standard laboratory methods like acid value, saponification value, iodine value, specific gravity and viscosity were used to study the chemical diversity of each product. Thermo gravimetry/differential thermal analyzer was used to analyse the thermal behavior of polymer. The synthesized compounds were subjected to biological study. The observed fungicidal characteristics of synthesized compounds indicate that these compounds might be promising antifungal agents defining a new class of antimycotics. The polymers were used in preparation of films which can be used as protective packaging material of edible items.     

EVALUATION OF CURRENT TECHNIQUES FOR NUTRIENT REMOVAL FROM WASTEWATERS1

ABSTRACT. A comprehensive evaluation of current techniques for nutrients, nitrogen and phosphorus, removal from wastewaters was conducted by the author under a research project supported by the Office of Water Resources Research, Department of the Interior. The object of this study was to compile and evaluate, under one cover, the available information on current techniques for removing nutrients from wastewaters with emphasis on type of treatment (physical, chemical, biological, or any combination); economics (capital and operating costs); efficiencies, and applications. Due to space limitations, only a brief summary of this work is presented in this paper. A copy of the completion report may be obtained from the author.     

Exergetic Sustainability Indicators as a Tool in Commercial Aircraft: A Case Study for a Turbofan Engine

This paper focuses on the exergetic sustainability indicators of a medium-range commercial aircraft engine for constant reference environment and ground running conditions. First, a detailed exergy analysis of turbofan engine have been performed based on engine test cell parameters. Starting from the sustainability considerations and the second law of the thermodynamics, the paper presents six exergy-based sustainability indicators. The indicators of the turbofan engine developed here in conjunction with exergetic analysis and sustainable development are exergy efficiency, waste exergy ratio, exergy destruction factor, recoverable exergy rate, environmental effect factor, and exergetic sustainability index. The investigated sustainable indicators have been calculated by using exergy analysis outputs for aircraft ground running condition. Results from this study show that values of exergy efficiency, waste exergy ratio, exergy destruction factor, recoverable exergy rate, environmental effect factor, and exergetic sustainability index of investigated turbofan engine are found to be 0.315, 0.685, 0.408, 0, 2.174, and 0.460, respectively. These parameters are expected to quantify how the turbofan engine and aircraft become more environmentally benign and sustainable.     

THE MEANDERING OF NATURAL STREAMS IN ALLUVIAL MATERIALS1

Although there have been numerous publications which might be classified under the general subject of meanders, they have, for the most part, been preoccupied with the origin of meanders, helicoidal flow or the search for a characteristic or standard meander. There seems to be little published information on the analysis of actual velocity patterns, the nature and role of bank caving or anomalies and differences in the geometry of bends. The purpose of this paper is to present a qualitative summary of current knowledge on the meandering of streams in alluvial materials, based upon a review of pertinent literature, data supplied by the Vicksburg and Little Rock Districts, Corps of Engineers, U.S. Army, and the observation of small-scale meanders on a tilting sand table. It is intended that this paper provide some coverage of the aspects of meandering that have hitherto been neglected.     

Copper modulates non-enzymatic antioxidants in the freshwater fish Channa punctata (Bloch) exposed to deltamethrin

The assessment of the ecotoxicological risks caused by pesticides to ecosystems are based on data on the toxicity and effects of pesticide preparations to non-target organisms like fish. Deltamethrin is a widely used pesticide based on pyrethroids, which is reported to be extremely toxic to fish species. Modulatory effect of copper pre-exposure (10 ppb) on deltamethrin (0.75 microg l-1)-induced oxidative stress was investigated in freshwater fish Channa punctata (Bloch). Non-enzymatic antioxidants were studied as biomarkers of exposure to deltamethrin and possible protection afforded by copper pre-exposure. Glutathione levels were reduced significantly (P<0.05) in liver of copper-acclimatized deltamethrin-exposed group when compared with deltamethrin-exposed groups. The total thiol levels of copper-acclimatized deltamethrin-exposed group was significantly lowered (P<0.01) in liver when compared with deltamethrin-exposed group, while non-protein thiol levels recorded a significant (P<0.01) increase in liver of copper-acclimatized deltamethrin-exposed group when compared with deltamethrin-exposed group. The lipid peroxidation levels of copper-acclimatized deltamethrin-exposed groups were significantly lowered (P<0.01) in liver when compared with deltamethrin-exposed group. Deltamethrin is known to induce toxic responses by generating reactive oxygen species and to neutralize its toxic effect various non-enzymatic antioxidants were found to be modulated thus implicating their role as biomarkers in pollution control programmes.     

Mode choice model for vulnerable motorcyclists in Malaysia

OBJECTIVE: In developing countries, motorcycle use has grown in popularity in the past decades. Commensurate with this growth is the increase in death and casualties among motorcyclists in these countries. One of the strategic programs to minimize this problem is to reduce motorcyclists exposure by shifting them into safer modes of transport. This study aims to explore the differences in the characteristics of bus and motorcycle users. It identifies the factors contributing to their choice of transport mode and estimates the probability that motorcyclists might change their travel mode to a safer alternative; namely, bus travel. METHODS: In this article, a survey of 535 motorcycle and bus users was conducted in seven districts of Selangor state, Malaysia. A binary logit model was developed for the two alternative modes, bus and motorcycle. RESULTS: It was found that travel time, travel cost, gender, age, and income level are significant in influencing motorcyclists' mode choice behavior. The probability of motorcycle riders shifting to public transport was also examined based on a scenario of a reduction in bus travel time and travel cost. CONCLUSIONS: Reduction of total travel time for the bus mode emerges as the most important element in a program aimed at attracting motorcyclists towards public transport and away from the motorcycle mode.