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1.
The analysis of BTEX and other substituted benzenes in water samples using solid phase microextraction (SPME) and quantification by gas chromatography with flame ionization detection (GC-FID) was validated. The best analytical conditions were obtained using PDMS/DVB/CAR fibre using headspace extraction (HS-SPME) at 50 [degree]C for 20 min without stirring. The linear range for each compound by HS-SPME with GC/FID was defined. The detection limits for these compounds obtained with PDMS/DVB/CAR fibre and GC/FID were: benzene (15 ng L(-1)), toluene (160 ng L(-1)), monochlorobenzene (54 ng L(-1)), ethylbenzene (32 ng L(-1)), m-xylene (56 ng L(-1)), p-xylene (69 ng L(-1)), styrene (35 ng L(-1)), o-xylene (42 ng L(-1)), m-dichlorobenzene (180 ng L(-1)), p-dichlorobenzene (230 ng L(-1)), o-dichlorobenzene (250 ng L(-1)) and trichlorobenzene (260 ng L(-1)). This headspace SPME-GC-FID method was compared with a previously validated method of analysis using closed-loop-stripping analysis (CLSA). The headspace SPME-GC-FID method is suitable for monitoring the production and distribution of potable water and was used, in field trials, for the analysis of samples from main intakes of water (surface or underground) and from the water supply system of a large area (Lisbon and neighbouring municipalities). 相似文献
2.
Salomao O. Bandeira Rui Paula e Silva Jose Paula Adriano Macia Lars Hernroth Almeida T. Guissamulo Domingos Z.Bergman 《Ambio-人类环境杂志》2002,31(7):606-609
本文概述了莫桑比克包括渔业在内的海洋生物学研究的发展情况.莫桑比克的海岸线约为3000km,海洋的生物资源在莫桑比克的社会中起着重要的作用,主要是作为人们的蛋白质来源以及收入和出口创汇的来源. 相似文献
3.
Raiane Costa Souza Roberto Bagattini Portella Paula Valéria Nunes Brito Almeida Caroline Oliveira Pinto Priscila Gubert 《Journal of environmental science and health. Part. B》2020,55(6):530-538
AbstractOrganochlorine pesticides (OCPs) are widely used around the world as insecticides, herbicides, fungicides, nematicides, and rodenticides. Despite banned in Brazil, the usage remains occurring in many countries. The persistence and extreme mobility of OCPs contribute to the contamination of the environment and the human body. The OCPs bioaccumulation in adipose tissue triggers the excretion into human milk during breastfeeding. Hence, the present study determined eighteen OCPs residues in the breast milk of mothers from the Western Region of Bahia State, Brazil. Nine different residue species were found, including beta-Hexachlorocyclohexane (9.24?±?0.00?ng g?1 fat), delta- Hexachlorocyclohexane (22.15?±?10.48?ng g?1 fat), Heptachlor (58.08?±?74.13?ng g?1 fat), Aldrin (142.65?±?50.65?ng g?1 fat), Dieldrin (774.62?±?472.68?ng g?1 fat), Endosulfan I (408.44?±?245.51?ng g?1 fat), Dichloro-diphenyl-dichloro-ethylene (29.17?±?22.42?ng g?1 fat), Dichloro-diphenyl-trichloro-ethane (28.87?±?0.00?ng g?1 fat) and Methoxychlor (1699.67?±?797.43?ng g?1 fat). The Methoxychlor presence in all samples may reveal a recent exposure, while Dieldrin and Endosulfan I analyses can point to distant past exposure. 相似文献
4.
Almeida Hanna N. Calixto Guilherme Q. Chagas Bruna M. E. Melo Dulce M. A. Resende Fabio M. Melo Marcus A. F. Braga Renata Martins 《Environmental science and pollution research international》2017,24(16):14142-14150
Environmental Science and Pollution Research - Biofuels have been seen as potential sources to meet future energy demand as a renewable and sustainable energy source. Despite the fact that the... 相似文献
5.
Ilton Curty Leal Junior Márcio de Almeida D'Agosto 《Journal of Cleaner Production》2011,19(2-3):229-240
Performance evaluation is important in managing freight transport. The transport of certain products, especially those that are hazardous, can have significant financial and socio-environmental impacts. This article presents an application of the modal choice method (MCM) to establish an order of priority among the alternatives considered to carry a determined hazardous product. After a research of the literature on the concepts and development of the proposed method, we consulted experts about their experiences and knowledge, to determine a set of relevant attributes for the evaluation process. We then applied this method to the specific case of the Brazilian bio-ethanol industry, to demonstrate the potential of using the MCM as a tool to support make decisions. We can conclude that highway transport, though the most often used, is not the best compared to trains or pipelines (or combinations of any of the three) from a socio-environmental standpoint. Alternatives with longer pipeline segments are the most suitable to replace the current practice in environmental terms. 相似文献
6.
Maria J. Ferreira Manuel F. Almeida Sílvia C. Pinho Isabel C. Santos 《Waste management (New York, N.Y.)》2010,30(6):1091-1100
Due to the amounts of chromium in the leachate resulting from leather leaching tests, chromium sulfate tanned leather wastes are very often considered hazardous wastes. To overcome this problem, one option could be recovering the chromium and, consequently, lowering its content in the leather scrap. With this objective, chromium leather scrap was leached with sulfuric acid solutions at low temperature also aiming at maximizing chromium removal with minimum attack of the leather matrix. The effects of leather scrap dimension, sulfuric acid and sodium sulfate concentration in the solutions, as well as extraction time and temperature on chromium recovery were studied, and, additionally, organic matrix degradation was evaluated. The best conditions found for chromium recovery were leather scrap conditioning using 25 mL of concentrated H2SO4/L solution at 293 or 313 K during 3 or 6 days. Under such conditions, 30–60 ± 5% of chromium was recovered and as low as 3–6 ± 1% of the leather total organic carbon (TOC) was dissolved. Using such treatment, the leather scrap area and volume are reduced and the residue is a more brittle material showing enhanced anaerobic biodegradability. Although good recovery results were achieved, due to the fact that the amount of chromium in eluate exceeded the threshold value this waste was still hazardous. Thus, it needs to be methodically washed in order to remove all the chromium de-linked from collagen. 相似文献
7.
Vicente Estela Domingos Alves Célia A. Martins Vânia Almeida Susana Marta Lazaridis Mihalis 《Environmental science and pollution research international》2021,28(46):65385-65398
Environmental Science and Pollution Research - Residential settings are of utmost importance for human exposure, as it is where people spend most of their time. Residential wood combustion is a... 相似文献
8.
Almeida CA Quintar S González P Mallea MA 《Environmental monitoring and assessment》2007,133(1-3):459-465
A study of the water quality of the Potrero de los Funes River (San Luis – Argentina) was carried out in order to evaluate
the possible effect of the anthropogenic activities on the river developed in the homonymous town. Samples were collected
during the period March 2000–November 2005 at three selected sampling sites (RP1, RP2 and RP3). Different physicochemical and bacteriological parameters (turbidity, pH, conductivity, suspended solids, alkalinity, potassium,
sodium, calcium, magnesium, chlorides, nitrates, phosphates, sulphates, chemical oxygen demand (COD), 5-day biological oxygen
demand (BOD5), dissolved oxygen, total coliforms, Escherichia coli and total heterotrophic bacteria) were analysed according to the Standard Method for the Examination of Water and Wastewater.
When comparing the values of total coliforms, E. coli, total heterotrophic bacteria, COD, BOD5 and phosphates from the zone without anthropogenic influence (RP1) and the urban zones (RP2 and RP3) an important variation in the parameters was observed. These results indicate that the urban activity produces a serious
and negative effect on the water quality, thus constituting a sanitary risk and may have a major impact on the trophic status
of the Potrero de los Funes dam. As case study, we report on the use of General Quality Index (GQI) to evaluate spatial and
seasonal changes in the water quality of Potrero de los Funes River. Results revealed a significant degradation of the water
quality at RP2 and RP3. 相似文献
9.
Ferreira Felipe Silva Brito Samuel Vieira de Oliveira Almeida Waltécio Alves Rômulo Romeu Nóbrega 《Regional Environmental Change》2016,16(2):543-551
Regional Environmental Change - The use and trade of animals in traditional medicine involves many different species, some of which are threatened with extinction. Thus, evaluating biological and... 相似文献
10.
Pedro N. Carvalho M. Clara P. Basto C. Marisa R. Almeida Hans Brix 《Environmental science and pollution research international》2014,21(20):11729-11763
Pharmaceuticals are commonly found both in the aquatic and the agricultural environments as a consequence of the human activities and associated discharge of wastewater effluents to the environment. The utilization of treated effluent for crop irrigation, along with land application of manure and biosolids, accelerates the introduction of these compounds into arable lands and crops. Despite the low concentrations of pharmaceuticals usually found, the continuous introduction into the environment from different pathways makes them ‘pseudo-persistent’. Several reviews have been published regarding the potential impact of veterinary and human pharmaceuticals on arable land. However, plant uptake as well as phytotoxicity data are scarcely studied. Simultaneously, phytoremediation as a tool for pharmaceutical removal from soils, sediments and water is starting to be researched, with promising results. This review gives an in-depth overview of the phytotoxicity of pharmaceuticals, their uptake and their removal by plants. The aim of the current work was to map the present knowledge concerning pharmaceutical interactions with plants in terms of uptake and the use of plant-based systems for phytoremediation purposes. 相似文献