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1.
2.
Self-diffusion coefficients were studied for the highly polar liquid N-methylformamide at pressures up to 200 MPa between the melting pressure curves and 420 K by the spin-echo method. N-Methylformamide exists as a mixture of two conformers in the neat liquid. These conformers have large differences at lower
temperatures in their dynamic and structural properties. The self-diffusion coefficient of the cis-conformer being 17% lower than that of the trans-conformer at the same T and p. This is the first observation of such an effect. The experimental study is supported by Monte Carlo (MC) calculations which
show that the first neighbors around a cis conformer are arranged differently than in an all trans liquid. The difference leads in the simulations to a much lower dielectric constant for the trans-cis mixture and might also explain the retardation of diffusion for the cis conformer.
Received: 15 November 1999 / Accepted in revised form: 28 February 2000 相似文献
3.
Current status and research on E-waste issues in Asia 总被引:2,自引:1,他引:2
Atsushi Terazono Shinsuke Murakami Naoya Abe Bulent Inanc Yuichi Moriguchi Shin-ichi Sakai Michikazu Kojima Aya Yoshida Jinhui Li Jianxin Yang Ming H. Wong Amit Jain In-Suk Kim Genandrialine L. Peralta Chun-Chao Lin Thumrongrut Mungcharoen Eric Williams 《Journal of Material Cycles and Waste Management》2006,8(1):1-12
Rapid economic growth in Asia and the increasing transboundary movement of secondary resources will increasingly require both
3R endeavors (reduce, reuse, recycle) in each country and appropriate control of international material cycles. Recently,
managing electrical and electronic waste (E-waste) has become an important target for domestic and international material
cycles from the viewpoints of environmental preservation and resource utilization efficiency. To understand the current status
of E-waste issues in the context of international material cycles and to discuss the future tasks related to achieving 3R
in the region, we organized the National Institute for Environmental Studies (NIES) E-waste Workshop in December 2004. This
article reviews past studies on E-waste and briefly describes the topics presented and discussions held at the workshop. The
topics at the workshop included E-waste generation, recycling systems, international trade, and environmental impacts. In
addition, we discussed various issues such as terminology, current environmental concerns, and possible solutions. Transboundary
shipments of E-waste should be conducted taking into consideration the concept of sustainable development. The direction of
future research and possible collaborations are also discussed. 相似文献
4.
An overview of the methods used in the characterisation of natural organic matter (NOM) in relation to drinking water treatment 总被引:9,自引:0,他引:9
Matilainen A Gjessing ET Lahtinen T Hed L Bhatnagar A Sillanpää M 《Chemosphere》2011,83(11):1431-1442
Natural organic matter (NOM) is found in all surface, ground and soil waters. During recent decades, reports worldwide show a continuing increase in the color and NOM of the surface water, which has an adverse affect on drinking water purification. For several practical and hygienic reasons, the presence of NOM is undesirable in drinking water. Various technologies have been proposed for NOM removal with varying degrees of success. The properties and amount of NOM, however, can significantly affect the process efficiency. In order to improve and optimise these processes, the characterisation and quantification of NOM at different purification and treatment processes stages is important. It is also important to be able to understand and predict the reactivity of NOM or its fractions in different steps of the treatment. Methods used in the characterisation of NOM include resin adsorption, size exclusion chromatography (SEC), nuclear magnetic resonance (NMR) spectroscopy, and fluorescence spectroscopy. The amount of NOM in water has been predicted with parameters including UV-Vis, total organic carbon (TOC), and specific UV-absorbance (SUVA). Recently, methods by which NOM structures can be more precisely determined have been developed; pyrolysis gas chromatography-mass spectrometry (Py-GC-MS), multidimensional NMR techniques, and Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS). The present review focuses on the methods used for characterisation and quantification of NOM in relation to drinking water treatment. 相似文献
5.
Chowdhury AG Das C Kole RK Banerjee H Bhattacharyya A 《Environmental monitoring and assessment》2007,131(1-3):467-473
A detailed study has been presented on heavy metal content of the Iture Estuary. Waters of the Sorowie and Kakum rivers that
supply water into the Estuary were investigated to ascertain heavy metal pollution levels due to anthropogenic activities.
Concentration s of Cd, Zn, Se and Pb were measured. The study shows pre-occupying pollution levels that constitute a threat
to both terrestrial and aquatic ecosystems. The abundance of metals in the Estuary is in the order Zn > Pb > Cd > Se. The
level of Cd in the Iture Estuary ranged between 0.011 mg/l and 0.041 mg/l while Se was in the range 0.018 mg/l to 0.029 mg/l,
Pb 0.020 mg/l to 0.075 mg/l and Zn 0.040 to 2.45 mg/l. The impact of contaminated water from the Sorowie River on the Iture
Estuary was outstanding and the study points out the importance of the Sorowie River as a primary pollution source to the
Iture Estuary. The pollution of the Iture Estuary was found to be connected to human activities in its catchments. 相似文献
6.
During the second half of the 20th century, the Ganga River ecosystem has been continuously altered by several ongoing anthropogenic
processes, accommodating multi-dimensional pressure due to increase of nearly four-fold human population. For solution of
any environmental issues of the river, the Earth System Science approach is required to have maximum socio-economic benefits
to millions of people living in Indian and Bangladesh. A bibliography containing more than 250 references on environmental
studies of the Ganga River was prepared to preserve its ecosystem by providing the baseline support in this regard. 相似文献
7.
8.
Patil Sakshi Bafana Amit Naoghare Pravin K. Krishnamurthi Kannan Sivanesan Saravanadevi 《Environmental science and pollution research international》2021,28(5):4951-4974
Environmental Science and Pollution Research - Microplastics are considered to be ubiquitous and widespread emerging contaminants. They are persistent in the nature and pose considerable harm to... 相似文献
9.
Gupta Amit Behl Tapan Aleya Lotfi Rahman Md. Habibur Yadav Harlokesh Narayan Pal Giridhari Kaur Ishnoor Arora Sandeep 《Environmental science and pollution research international》2021,28(16):19601-19614
Environmental Science and Pollution Research - Type 2 diabetes (T2D) is one of the most widely spread metabolic disorder also called as “life style” disease. Due to the alarming number... 相似文献
10.
Kumar V Rani S Malik S Trivedi AK Schwabl I Helm B Gwinner E 《Die Naturwissenschaften》2007,94(8):693-696
Daytime light intensity can affect the photoperiodic regulation of the reproductive cycle in birds. The actual way by which
light intensity information is transduced is, however, unknown. We postulate that transduction of the light intensity information
is mediated by changes in the pattern of melatonin secretion. This study, therefore, investigated the effects of high and
low daytime light intensities on the daily melatonin rhythm of Afro-tropical stonechats (Saxicola torquata axillaris) in which seasonal changes in daytime light intensity act as a zeitgeber of the circannual rhythms controlling annual reproduction
and molt. Stonechats were subjected to light conditions simulated as closely as possible to native conditions near the equator.
Photoperiod was held constant at 12.25 h of light and 11.75 h of darkness per day. At intervals of 2.5 to 3.5 weeks, daytime
light intensity was changed from bright (12,000 lux at one and 2,000 lux at the other perch) to dim (1,600 lux at one and
250 lux at the other perch) and back to the original bright light. Daily plasma melatonin profiles showed that they were linked
with changes in daytime light intensity: Nighttime peak and total nocturnal levels were altered when transitions between light
conditions were made, and these changes were significant when light intensity was changed from dim to bright. We suggest that
daytime light intensity could affect seasonal timing via changes in melatonin profiles.
Professor Dr. E. Gwinner died on 07 September 2004. 相似文献