Sustainability Assessment for Agriculture Scenarios in Europe’s Mountain Areas: Lessons from Six Study Areas

Sustainability assessment (SA) is a holistic and long-range strategic instrument capable of assisting policy-making in electing, and deciding upon, future development priorities. The outcomes of an SA process become more relevant and strengthened when conducted with multi-stakeholder engagement, which provides for multiple dialogues and perspectives. This was the object of research of the SA team in the context of BioScene (Scenarios for Reconciling Biodiversity Conservation with Declining Agriculture Use in Mountain Areas in Europe), a three-year project (2002–2005) funded by the European Union 5th Framework Program, which aimed to investigate the implications of agricultural restructuring and decline for biodiversity conservation in the mountain areas of Europe, using three distinct methodological streams: the ecological, the socio-economic, and the SA approaches. The SA approach drew on the previous two to assess the importance for biodiversity management of different scenarios of agri-environmental change and rural policy in six countries (France, Greece, Norway, Slovakia, Switzerland, and the United Kingdom), develop causal chains, include stakeholder views, and identify potential contributions for, or conflicts with, sustainability. This article tells how SA was used, what sustainability meant in each study area through different objectives of sustainability considered, discusses the methods used in SA, and the benefits arising. The SA was conducted by a team independent of any study area, who developed and oversaw the application of the SA methodology, assisting national teams, and developing a cross-country understanding of the sustainability of proposed scenarios in the different geographical and social contexts, and their implications for policy-making. Finally, it reflects on the persistent challenges of interdisciplinary research, compounded by multi-cultural teams, and concludes on the BioScene’s lessons for the further development and application of SA.

Decay profile and metabolic pathways of quinalphos in water, soil and plants

The widespread occurrence of pesticide residues in different agricultural and food commodities has raised concern among the environmentalists and food chemists. In order to keep a proper track of these materials, studies on their decay profiles in the various segments of ecosystem under varying environmental conditions are needed. In view of this, the metabolites of quinalphos in water and soil under controlled conditions and in plants, namely tomato and radish in field conditions have been analysed and possible pathways suggested. In order to follow the decay of the pesticide, an HPLC procedure has been developed. Studies conducted in water at different temperatures, pH and organic content reveal that the persistence of the pesticide decreases with the increase in all the three variables. In the three different types of soils studied, the effect of pH is more or less apparent on a similar line. On an average a faster decay is observed in the case of plants than in water and soil. The decay profiles in all these cases follow first order kinetics. The metabolites were identified by GC-MS. The investigations reflect that degradation occurs through hydrolysis, S-oxidation, dealkylation and thiono-thiol rearrangement. The pathways seem to be complex and different metabolites were observed with the change in the matrix. Quinalphos oxon, O-ethyl-O-quinoxalin-2-yl phosphoric acid, 2-hydroxy quinoxaline and quinoxaline-2-thiol were observed in all the matrices. Results further indicate that the metabolites, 2-hydroxy quinoxaline and oxon, which are more toxic than parent compound, persist for a longer time.     

Biofilm growth-percolation models and channeling in biofilter clogging

Biomass accumulation is a load-limiting factor in the operation of biofilters used for air pollution control. As the biofilm thickens, portions at the base are no longer exposed to contaminants and oxygen and, thus, provide no treatment. Smaller pores are filled with biomass so that air no longer flows into them. As airflow paths are restricted, air may be prevented from reaching some pores even before they are filled. Eventually blockage becomes sufficiently widespread so that increasing head loss and decreasing removal efficiency require that the system be shut down. Optimization of biofilter design requires a better understanding of the mechanisms by which biofilters clog. In this work, a numerical percolation model of the blockage process was developed for application to biofilters. It allows comparison of pore blockage histories for various pore size distributions and predicts biomass accumulation, head loss, and treatment efficiency as a function of time, as well as total time, until blockage prevents further operation. Although the model was reasonably accurate in predicting the time before complete clogging, it underestimated intermediate values of head loss. Observations of a clogged biofilter suggest that this occurs because clogging later in the process is nonuniform at scales that are large in comparison with individual pores.     

Identification of degradation products of thiram in water, soil and plants using LC-MS technique

In order to evaluate the deleterious effects of exposure to pesticides on a target population, a comprehensive study on their degradation in the various segments of ecosystem under varying environmental conditions is needed. In view of this, a study has been carried out on the metabolic pathways of thiram, a dithiocarbamate fungicide, in a variety of matrices namely water and soil under controlled conditions and plants in field conditions. The identification of degradation products was carried out in samples collected at various time points using LC-MS. The degradation products identified can be rationalized as originating by a variety of processes like hydrolysis, oxidation, N-dealkylation and cyclization. As a result of these processes the presence of some metabolites like dimethyl dithiocarbamate, bis(dimethyl carbamoyl) disulphide, bis(dimethyl dithiocarbamoyl) trisulphide and N-methyl-amino-dithiocarbamoyl sulphide was observed in all the cases. However, some different metabolites were observed with the change in the matrix or its characteristics such as cyclised products 2(N, N-dimethyl amino)thiazoline carboxylic acid and 2-thioxo-4-thiazolidine were observed only in plants. The investigations reflect that degradation initiates with hydrolysis, subsequently oxidation/dealkylation, followed by different types of reactions. The pathways seem to be complex and dependent on the matrices. Dimethyl dithiocarbamate and oxon metabolites, which are more toxic than parent compound, seem to persist for a longer time. Results indicate persistence vis-a-vis toxicity of pesticide and its metabolites and also provide a data bank of metabolites for forensic and epidemiological investigations.     

Context and Systems: Thinking More Broadly About Effectiveness in Strategic Environmental Assessment in China

China is an illustrative—and extreme—case of the difficulties of balancing the pursuit of economic, social, and environmental objectives. In 2003 it adopted a form of Strategic Environmental Assessment (SEA) for its plans and programs (referred to here as PEIA) with the aim of moving towards greater environmental sustainability. The literature has explored primarily the issue of methods and legal procedures. This research contributes to the analysis of PEIA through a different set of interpretative lens. Drawing on recent developments in the theory and practice of SEA, I propose a conceptualization of SEA effectiveness that combines direct and incremental impacts, and a need for context-specific systems as a way to focus on the relationship between assessment, planning, and their context, and thus maximize effectiveness. This framework underpins the analysis of China’s experience, which I explore with the help of interview material and the literature. The result is an evaluation of the strengths and weaknesses of PEIA in terms of its purpose, assessment concept, process, and methods. The detailed analysis of six aspects of the context helps explain the origin of such shortcomings, and identify opportunities for its improvement. I conclude defining elements of a context-specific system for SEA that seeks to maximize the opportunity for incremental, as well as direct, effectiveness in China.     

Benzene removal by nano magnetic particles under continuous condition from aqueous solutions

Benzene removal evaluated using Fe304 nano continuous condition. A 44 initial benzene concentration, from aqueous solutions was magnetic particles （NM） in factorial design including NM dose, contact time and pH was investigated in 16 experiments （Taguchi OA design）. The results indicated that all factors were significant and the optimum condition was： pH 8, NM dose of 2000 mg.L-1, benzene concentrations of 100 mg.L-1 and contact time of 14min. The maximum benzene uptake and distribution ratio in the optimum situation were 49.4mg.g-1 and 38.4L.g-1, respectively. The nano particles were shown to capture 98.7% of the benzene in optimum batch condition and 94.5% in continuous condition. The isotherm data proved that the Bmnauer-Emmett-Teller model fit more closely and produced an isotherm constant （b） less than one, indicating favorable adsorption. Regeneration studies verified that the benzene adsorbed by the NM could be easily desorbed by temperature, and thereby, NM can be employed repeatedly in water and wastewater management.     

Biodegradation of styrene laden waste gas stream using a compost-based biofilter

Biological treatment of waste gas styrene vapor was investigated in a three-stage bench-scale biofilter. Yard waste compost mixed with shredded hard plastics in a 25:75 v/v ratio of plastics:compost was inoculated with thickened municipal activated sludge. Microbial acclimation to styrene was achieved by exposing the system to an inlet concentration (C(In)) of 0.25 gm(-3) styrene and an empty bed retention time (EBRT) of 360 s for 30 days. Under steady-state conditions, maximum elimination capacity (EC) obtained was 45 gm(-3)h(-1) at a loading rate (L) of 60 gm(-3)h(-1) (C(In) of 2 gm(-3) and EBRT of 120 s). Reduction of retention time adversely impacted the performance resulting in the maximum EC of 39 and 27 gm(-3)h(-1) for EBRT of 60 and 30 s, respectively. Evaluation of the concentration profile along the bed height indicated dominance of first-order kinetics at C(In) < or = 0.45 gm(-3) and zero-order for higher concentrations.     

基于人类可持续发展指数的中国1990—2010年人类-环境系统可持续性评价

中国经济的快速发展对人类-环境系统造成了巨大压力。如何全面地评估中国人类-环境系统可持续性已成为当前可持续性科学的一个研究热点。论文基于"人类可持续发展指数"在国家、区域和省三个尺度上系统评价了中国人类-环境系统1990—2010年的可持续性。研究结果表明,2010年中国人类-环境系统可持续性为中上水平,总体呈现东高西低的空间格局。1990—2010年中国人类-环境系统可持续性表现为增长趋势,中西部可持续性增长快于东部。经济和社会可持续性指标呈增加趋势,环境可持续性指标为下降趋势。可见,中国人类-环境系统可持续性的空间格局与动态变化均不协调,需进一步促进中西部社会经济发展及加强生态文明建设以实现社会、经济与环境可持续性的全面提高。