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C. K. Ngan U. B. Cheah W. Y. Wan Abdullah K. P. Lim B. S. Ismail 《Water, Air, & Soil Pollution: Focus》2005,5(1-2):125-136
The fate of chlorothalonil, chlorpyrifos and profenofos in sandy loam soil under tropical condition was studied in a vegetable
plot in the Cameron Highlands, Malaysia. The plot was treated with chlorothalonil, chlorpyrifos and profenofos according to
normal agricultural practices of the Cameron Highlands. Water (runoff and lysimeter), soil and bedload sediment samples were
taken according to a sampling schedule. Residues in water, soil and bedload sediment samples were laboratory analysed to determine
amount. Chlorothalonil residues were detected in the range of < 0.01–0.08 mg/kg in the soil, < 0.01–0.02 ng/mL in the leachate,
< 0.01–0.02 ng/mL in the runoff and < 0.01–0.11mg/kg in the sediment. Field studies of chlorpyrifos showed residue levels
of < 0.01–0.06 mg/kg in the soil, < 0.01–0.07 ng/mL in the leachate, < 0.01–0.08 ng/mL in the runoff and < 0.01–0.62 mg/kg
in the sediment. Residue levels of profenofos were detected in the range of < 0.01–0.02 mg/kg in the soil, < 0.01–0.87 ng/mL
in the leachate, < 0.01–0.08 ng/mL in the runoff and < 0.01–0.35 mg/kg in the sediment. The three pesticides dissipated rapidly,
with DT50 (time for 50% loss) of less than two days. The study showed that these pesticides dissipated rapidly under the climatic
conditions of the Cameron Highlands in Malaysia. 相似文献
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Ismai BS Enoma AO Cheah UB Lum KY Malik Z 《Journal of environmental science and health. Part. B》2002,37(4):355-364
Laboratory studies utilizing radioisotopic techniques were conducted to determine the adsorption, desorption, and mobility of endosulfan (6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxanthiepin3-oxide) and methamidophos (O,S-dimethyl phosphorothioate) in sandy loam and clay soils of the Cameron Highlands and the Muda rice-growing area, respectively. High Freundlich adsorption distribution coefficients [Kads(f)] for endosulfan (6.74 and 18.75) and low values for methamidophos (0.40 and 0.98) were obtained in the sandy loam and clay soils, respectively. The observed Koc values for endosulfan were 350.85 (sandy loam) and 1143.19 (clay) while Koc values of 20.92 (sandy loam) and 59.63 (clay) were obtained for methamidophos. Log Kow of 0.40 and 1.25 were calculated for endosulfan as well as -1.96 and -1.21 for methamidophos in the sandy loam and clay soils, respectively. Desorption was common to both pesticides but the desorption capacity of methamidophos from each soil type far exceeded that of endosulfan. Soil thin layer chromatography (TLC) and column studies showed that while methamidophos was very mobile in both soils, endosulfan displayed zero mobility in clay soil. 相似文献
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