Spatial and seasonal dynamics of phosphorous and physicochemical variables in the Negro River Estuary (Argentina): a preliminary approach

Environmental Science and Pollution Research - Nutrient discharge into rivers and estuaries and the factors that control it need to be further understood to decrease the risk of harmful algae...     

Speciation of gold(III)-L-histidine complex: a multi-instrumental approach

The formation and structure of gold (III)-L-histidine complex was investigated with the use of carbon (13C) and proton (1H) nuclear magnetic resonance (NMR), infrared (IR) spectroscopy, capillary electrophoresis (CE), capillary electrophoresis-inductively coupled plasma-mass spectroscopy (CE-ICP-MS), X-ray fluorescence spectroscopy (XRF), matrix-assisted laser desorption/ionization (MALDI), and laser desorption mass spectroscopy (LDMS). It was found that two L-histidine molecules and one gold ion slowly form a complex in acidic solution. Each L-histidine molecule provided two nitrogen ligands; one was the alpha-amino group and the other from the imidazole ring. The Au(III)-bis-L-histidine complex precipitates after deprotonation of the free carboxylic group, resulting in an increase in the solution acidity. Determination of the exact sequence of events and the identity of the complex was a comprehensive instrumental analysis problem involving the above techniques.     

Chemosensory cues allow male lizards<Emphasis Type="Italic"> Psammodromus algirus</Emphasis> to override visual concealment of sexual identity by satellite males

Males of many species of lizards show conspicuous breeding colors but, in some species, young competitively inferior males conceal their sexual identity by a female-like dull coloration that allows them to evade aggression from dominant males and to adopt an alternative satellite-sneaking mating tactic. However, large males of the lizard Psammodromus algirus reacted aggressively to young intruder males despite their female-like coloration, suggesting that they might have the ability to recognize competitor males by chemosensory cues. We experimentally manipulated the head coloration (brown vs orange) and scents (male vs female) of small young males. For staged agonistic encounters, we compared the response of resident unmanipulated large males to the different manipulated small males. When we manipulated only the color of small males, the response of resident large males was independent of the paint manipulation; brown and orange males elicited a similar aggressive response. However, when we also manipulated the scent, small males painted orange or brown, but bearing the scent of males, received a significantly higher number of aggressive responses than small males painted orange or brown, but bearing the scent of females. The results showed that, at close range, the reaction of large males to manipulated individuals was dependent on the scent, whereas color seemed to be less important. Coloration may be, however, more important in long-distance communication as shown by the outcome of the first encounters. Also, orange coloration may increase the intensity of the aggressive response. Effective sex recognition by territorial large males is important in natural situations to avoid sneak matings by young male competitors. Thus, even if small males visually conceal their sexual identity, chemosensory cues allow large males to identify them at close range.     

A proposal for environmental indicators towards industrial building sustainable assessment

The construction sector carries out a very important role in the development of society. It is a basic component of economic activity, having a great influence on employment generation and country growth. The sector generates appreciable environmental changes and effects throughout the planet, leading to gradual exhaustion of natural resources and contamination of basic elements, such as air, water and soil. Recently, there have been advances in favour of more environmentally friendly buildings. Basically, sustainable construction has centred on residential and office buildings. It could be said that there is a lack of sustainability in the construction of industrial buildings, as they present characteristics which differ from other building typologies. This article aims to assess and analyze industrial building environmental effects, and considers a set of green study criteria, such as: location, materials, energy and water consumption, construction and deconstruction characteristics, and waste management in industrial building. At the same time, the studies are hierarchically structured into different assessment elements, such as: criteria, subcriteria and, finally, indicators, comprising the assessment model.     

Phytoremediation potential of the novel atrazine tolerant Lolium multiflorum and studies on the mechanisms involved

Atrazine impact on human health and the environment have been extensively studied. Phytoremediation emerged as a low cost, environmental friendly biotechnological solution for atrazine pollution in soil and water. In vitro atrazine tolerance assays were performed and Lolium multiflorum was found as a novel tolerant species, able to germinate and grow in the presence of 1 mg kg⁻¹ of the herbicide. L. multiflorum presented 20% higher atrazine removal capacity than the natural attenuation, with high initial degradation rate in microcosms. The mechanisms involved in atrazine tolerance such as mutation in psbA gene, enzymatic detoxification via P₄₅₀ or chemical hydrolysis through benzoxazinones were evaluated. It was demonstrated that atrazine tolerance is conferred by enhanced enzymatic detoxification via P₄₅₀. Due to its atrazine degradation capacity in soil and its agronomical properties, L. multiflorum is a candidate for designing phytoremediation strategies for atrazine contaminated agricultural soils, especially those involving run-off avoiding.     

The importance of achieving a high customer satisfaction with recycling services in communities

Some studies show that there are external, infrastructural, and economic factors that enable individuals and communities to act ecologically. A variable associated with sustainable behavior is the level of satisfaction with infrastructural and economic factors, which in turn relates to recycling behavior. The main aim of this study was to assess the reliability and validity of the customer satisfaction with recycling scale and to analyze its relationship with sociodemographic variables (age and gender), house location (in the center or the suburbs, population size of), and psychological variables (self-reported individual recycling behaviors, general satisfaction with recycling service companies, and the perception of costs and the quality of service). A total of 1498 individuals responded to the in-home questionnaire related to these variables. Exploratory and confirmatory factorial analyses confirm a good fit for a four-dimensional model: assurance, tangibles, empathy, and communication. Results show that those individuals who live in town centers tend to self-report higher levels of satisfaction with tangibles than those living in the suburbs. Population sizes correlate significantly and negatively with the four dimensions of service satisfaction, while age seems to relate significantly and negatively to all the studied variables. Finally, we discuss the implications regarding the importance of customer satisfaction in facilitating the environmentally responsible behavior.     

Spiking solvent, humidity and their impact on 2,4-D and 2,4-DCP extractability from high humic matter content soils

The 2,4-dichlorophenoxyacetic acid (2,4-D) is a hormone-like herbicide widely used in agriculture. Although its half life in soil is approximately two weeks, the thousands of tons introduced in the environment every year represent a risk for human health and the environment. Considering the toxic properties of this compound and its degradation products, it is important to assess and monitor the 2,4-D residues in agricultural soils. Furthermore, experiments of phyto/bioremediation are carried out to find economic and environmental friendly tools to restore the polluted soils. Accordingly, it is essential to accurately measure the amount of 2,4-D and its metabolites in soils. There is evidence that 2,4-D extraction from soil samples seriously depends on the physical and chemical properties of the soil, especially in those soils with high content of humic acids. The aim of this work was to assess the variables that influence the recovery and subsequent analysis of 2,4-D and its main metabolite (2,4-dichlorophenol) from those soils samples. The results showed that the recovery efficiency depends on the solvent and method used for the extraction, the amount and kind of solvent used for dissolving the herbicide and the soil water content at the moment of spiking. An optimized protocol for the extraction and quantification of 2,4-D and its main metabolite from soil samples is presented.     

Dissipation of 2,4-D in soils of the Humid Pampa region, Argentina: a microcosm study

Phenoxy herbicides like 2,4-dichlorophenoxyacetic acid (2,4-D) are widely used in agricultural practices. Although its half life in soil is 7-14d, the herbicide itself and its first metabolite 2,4-dichlorophenol (2,4-DCP) could remain in the soil for longer periods, as a consequence of its intensive use. Microcosms assays were conducted to study the influence of indigenous microflora and plants (alfalfa) on the dissipation of 2,4-D from soils of the Humid Pampa region, Argentina, with previous history of phenoxy herbicides application. Results showed that 2,4-D was rapidly degraded, and the permanence of 2,4-DCP in soil depended on the presence of plants and soil microorganisms. Regarding soil microbial community, the presence of 2,4-D degrading bacteria was detected even in basal conditions in this soil, possibly due to the adaptation of the microflora to the herbicide. There was an increment of two orders of magnitude in herbicide degraders after 15d from 2,4-D addition, both in planted and unplanted microcosms. Total heterotrophic bacteria numbers were about 1x10(8) CFUg(-1) dry soil and no significant differences were found between different treatments. Overall, the information provided by this work indicates that the soil under study has an important intrinsic degradation capacity, given by a microbial community adapted to the presence of phenoxy herbicides.