Organic aerosol characterization by complementary measurements of chemical bonds and molecular fragments

Organic aerosol chemical markers from normalized concentrations of independent measurements of mass fragments (using Aerosol Mass Spectrometry, AMS) are compared to bond-based functional groups (from Fourier Transform Infrared spectroscopy, FTIR) during eight field projects in the western hemisphere. Several field projects show weak correlations between alcohol group fractions and m/z 60 fractions, consistent with the organic hydroxyl groups and the fragmentation of saccharides, but the weakness of the correlations indicate chemical differences among the relationships for ambient aerosols in different regions. Carboxylic acid group fractions and m/z 44 fractions are correlated weakly for three projects, with correlations expected for aerosols dominated by di-acid compounds since their fragmentation is typically dominated by m/z 44. Despite differences for three projects with ratios of m/z 44 to m/z 57 fragments less than 10, five projects showed a linear trend between the project-average m/z 44 to m/z 57 ratio and the ratio of acid and alkane functional groups. While this correlation explains only a fraction of the fragment and bond variability measured, the consistency of this relationship at multiple sites indicates a general agreement with the interpretation of the relative amount of m/z 44 as a carboxylic acid group marker and m/z 57 as an alkane group marker.     

Redox processes in water remediation

Groundwater is the main source of drinking water and water for agricultural and industrial usage. Therefore, groundwater contamination is prevented and contaminated groundwater is remediated to protect public health and the environment. Methods to remediate groundwater contamination have been recently developed. The use of redox processes in water remediation technologies has not been properly reviewed. Numerous water remediation technologies, such as ultrasonication, bioremediation, electrokinetics and nanotechnology, are closely related to redox processes. Redox processes control the chemical speciation, bioavailability, toxicity, mobility and adsorption of water pollutants in environment. Here, we review (1) general introduction of redox processes, (2) applicability of redox processes in water remediation, and (3) catalytic enhancement of redox potentials to explore its wide applicability in environmental remediation.     

Effect of surfactants on phosphatase level of fresh water fish Labeo rohita

Alterations in the activity of enzymes Acid phosphatase (E.C.3.1.3.2) and Alkaline phosphatase (EC 3.1.3.1) in organs such as liver, gills and muscle of rohu following its exposure to surfactants viz. CTAB, SDS and Triton X-100 were analyzed. Different levels of exposure were given depending on the LC50 value of the surfactant used. Also, the influence of age and weight of the organisms was tested simultaneously. The activity of ACP in the tissues of fish exposed to all the three surfactants showed marked enhancement after exposure; the effect being highest in the liver followed by gill and muscle. Activity levels of ALP in different tissues of the fish exposed to the surfactants also showed an increase. Maximum increase was found in the liver followed by muscle, and gill. The increase in the levels of these enzymes indicates a stressful condition of the fish.     

Integrated process approach for degradation of p-cresol pollutant under photocatalytic reactor using activated carbon/TiO2 nanocomposite: application in wastewater treatment

Environmental Science and Pollution Research - Over the years, biodegradation has been an effective technique for waste water treatment; however, it has its own limitations. In order to achieve a...     

Influencing resilience: the role of policy entrepreneurs in mainstreaming climate adaptation

One way to make development pathways more resilient in the face of a changing climate has been through mainstreaming adaptation into government policies, planning and sectoral decision‐making. To date, many of the transferable lessons have taken the form of technical approaches such as risk assessments and toolkits. This article instead draws on evidence from South Asia to emphasise some of the more tacit and informal approaches used to influence adaptation policy. Despite their apparent significance in policy processes, such tactics are often neither planned for nor well reported in resilience‐building projects and programme documents. Using evidence to populate a typology of influencing strategies, this article looks particularly at the role of policy entrepreneurs who navigate the political complexity of both formal and informal governance systems to promote successful adaptation mainstreaming. It concludes with recommendations for adaptation and resilience programming that can more effectively harness the breadth of influencing strategies.     

Factors affecting the adoption of multiple climate‐smart agricultural practices in the Indo‐Gangetic Plains of India

Climate change poses a major threat to agricultural production and food security in India, and climate‐smart agriculture (CSA) is crucial in addressing the potential impacts. Using survey data from 1,267 farm households in 25 villages from Bihar and Haryana in the Indo‐Gangetic Plains, this study analyzes the factors that determine the probability and level of adoption of multiple CSA practices, including seeds of stress‐tolerant varieties, minimum tillage, laser land leveling, site‐specific nutrient management and crop diversification. We applied a multivariate probit model for the simultaneous multiple adoption decisions, and ordered probit models for assessing the factors affecting the level of adoption. The adoption of the various CSA practices is interrelated, whereas several factors, including household characteristics, plot characteristics, market access and major climate risks are found to affect the probability and level of CSA adoption. Climate‐smart agriculture (CSA) adoption and its intensity also vary significantly between eastern Bihar, which is relatively poor and densely populated, and north‐western Haryana. Engaging multiple stakeholders such as farmers, agricultural institutions, agricultural service providers and concerned government departments at the local level is crucial for the large‐scale uptake of CSA. The study, therefore, calls for agricultural policy reforms so that most of the issues related to the uptake of CSA can be adequately addressed.     

Understanding the factors that influence household use of clean energy in the Similipal Tiger Reserve,India

Biotic pressure in and around protected areas (PA) is the primary cause of biodiversity loss in many developing countries across the globe. The pressure comes partly from biomass energy dependency in the form of heavy extraction of fuelwood from the forests. Although biomass fuels provide easily accessible and affordable sources of domestic energy to the rural masses, their combustion results in environmental and health‐related hazards. The objectives of this paper are to assess the patterns of household energy use in a subsistence forest economy and analyze the factors that influence their energy use choice for cooking and lighting. The paper uses primary data collected randomly from 244 households located in and around the Similipal Tiger Reserve (STR), situated in the eastern Indian state of Odisha. Age of the household head, number of days in wage employment, number of adult males and females in a household, education of the household head and landholding size are found to be the major variables that determine household fuelwood collection sources inside the reserve. Considering household structure as an income indicator, the analysis clearly shows that non‐poor households prefer to use clean energy (i.e. solar) for lighting, while poor households tend to use solid fuel. Energy policies for development should be based on the realistic proposition that fuelwood will remain the major source of energy for cooking for substantial proportions of the world’s population. Promotion of public education, social forestry schemes and fuel‐efficient improved chulhas should be encouraged in order to reduce household dependence on fuelwood. Moreover, devolving sufficient property rights over forest resources to local communities may help secure their broad‐based and active participation in the decision‐making process, which may result in a positive change in the attitude of the local people towards biodiversity conservation.     

The Indus Irrigation System,Natural Resources,and Community Occupational Quality in the Delta Region of Pakistan

This study examines the impact of an elaborated irrigation system on the natural resources and society in the deltaic part of the Indus River in Pakistan. Time series information was collected to analyze the ecological and natural resource dynamics, and their impacts on the structure and quality of the occupations of the people in the Indus delta during pre- and post-irrigation system development periods. The information was collected through literature review, reconnaissance, structured questionnaire survey, focus group discussions, and interviews. The findings revealed that the expansion of the irrigation system and the resulting reduction in the downstream flow had their differential impacts on the various segments of downstream ecology and society. Some of the resources, for example the agricultural mudflats have been adversely affected due to the accelerated seawater intrusion that severely impinged on the paddy farms. On the other natural resources like mangroves, the impacts had been both negative and positive. On one hand, the diversity of the mangroves species had deteriorated while on other hand, the mangroves have benefited from such development because of the alleviated pressure of camel grazing as a result of the occupational change on the part of the camel herders. Furthermore, changes in the hydrological regimes had forced the paddy farmers and camel herders to switch to fishing as an alternative source of employment and income. Considering that currently about 87% people are already engaged primarily in marine fishery, this scenario is threatening the sustainability of the fishery resources as well as the livelihoods of all, the traditional and converted fishermen. The findings of the study are therefore meant to advocate the different treatments which should be accorded to the various segments of the downstream ecology and society during the planning of any remedial irrigation projects in order to mitigate the adverse impacts of the previous irrigation development strategies and of any water resources development to be carried out in the future.