Modelling the Balance of Metals in the Amended Soil for the Case of ‘Atmosphere–Plant–Soil’ System

Changing the concepts of economic development and introducing new amendments can hardly decrease the accumulation in the soil of such pollutants as metals, remaining there for a long time. The predictive models for describing the balance of metals in the soil, which are based on the ‘atmosphere–plant–soil’ system and reflect the complicated physical–chemical nature of the metals’ migration, expressed by coefficients obtained in long-term observations in natural conditions, allow for evaluating long-term concentration of metals in the soil. The model BALANS evaluates self-purification of soil, taking into account the uptake of metals of aerogenic origin by the soil together with amendments, their physical–chemical migration and the type of microrelief determining its intensity as well as the absorbed biomass of plants and the removal of metals with crops. In this model, the half-period of metals’ washing out from the soil, found for the microrelief characteristic of low places, exceeds 200 years for Ni, Cr and Pb and makes 90 and 150 years for Zn and Cu, respectively.     

Aliphatic and polycyclic aromatic hydrocarbons in the bottom sediments from Klaipėda Harbour,Lithuania (Baltic Sea)

A total of 22 bottom surface sediment samples were collected from Klaip?da Harbour, Lithuania (Baltic Sea). Sediment parameters, such as grain size and concentrations of total organic carbon, aliphatic hydrocarbons (ALHs) and polycyclic aromatic hydrocarbons (PAHs), were determined. Hydrocarbon contamination levels in the sediments were estimated based on classifications provided in the literature, and potential biological effects were assessed based on the effects range low–effects range median values of the Sediment Quality Guidelines and on the total toxic benzo(a)pyrene equivalent. The results demonstrated that concentrations of PAHs and total aliphatic hydrocarbons in the sediments varied between 1.6 and 5456?ng?g^?1 d.w. and 6.9 and 727?μg?g^?1 d.w., respectively. In most cases, the concentrations of ALHs and PAHs in the sediments indicated low to moderate levels of pollution and were not observed to have any significant adverse effects on living biota. To determine possible sources of hydrocarbons, hydrocarbon compositions were analysed, and ALHs’ and PAHs’ specific diagnostic ratios were calculated. According to the results, the Klaip?da Harbour bottom sediments were dominated by PAHs of pyrogenic origin, whereas the origin of ALHs was mixed, that is, anthropogenic with a biogenic (aquatic and terrestrial) input.     

Modelling of a Capillary Rise Height of Biochar by Modified Lucas–Washburn Equation

Environmental Modeling & Assessment - Lucas–Washburn equation is a fundamental expression which is used to describe capillary rise in porous materials according to average pore radius,...     

Changes in pro-environmental behaviour and its determinants during long-term period in a transition country as Lithuania

Environment, Development and Sustainability - The changes in pro-environmental behaviour, whether people become more environmentally friendly or not, have been analysed very scarcely. Therefore,...     

Herbicides based on 2,4-D: its behavior in agricultural environments and microbial biodegradation aspects. A review

Environmental Science and Pollution Research - One of the main herbicides used in the agricultural environments is 2,4-dichlorophenoxyacetic acid (2,4-D). It is a synthetic plant hormone auxin...     

Multilingual education of students on a global scale and perspective—international networking on the example of bioindication and biomonitoring (B&B technologies)

Living or formerly living organisms are being used to obtain information on the quality of the general health status of our environment by bioindication and biomonitoring methods for many decades. Thus, different roads toward this common scientific goal were developed by a lot of different international research groups. Global cooperation in between various scientific teams throughout the world has produced common ideas, scientific definitions, and highly innovative results of this extremely attractive working field. The transdisciplinary approach of different and multifaceted scientific areas—starting from biology, analytical chemistry, via health physics, up to social and economic issues—have surpassed mental barriers of individual scientists, so that “production” of straightforward common results related to the influence of material and immaterial environmental factors to the well-being of organisms and human life has now reached the forefront of international thinking. For the further sustainable development of our common scientific “hobby” of bioindication and biomonitoring, highest personal energy has to be given by us, being teachers to our students and to convince strategically decision makers as politicians to invest (financially) into the development of education and research of this innovative technique. Young people have to be intensively convinced on the “meaning” of our scientific doing, e.g., by extended forms of education. One example of multilingual education of students on a global scale and perspective is given here, which we started about 3 years ago.     

Biomarkers of environmental contaminants in the coastal waters of Estonia (Baltic Sea): effects on eelpouts (Zoarces viviparus)

The eastern Baltic Sea near the Estonian coast is heavily navigated by numerous cargo ships and oil tankers. Hundreds of accidents and oil spills happen yearly in this area. Yet, there is a lack of data concerning the distribution and effects of the environmental contaminants, especially polycyclic aromatic hydrocarbons (PAHs). Different parts of the Baltic Sea have different levels of contamination; therefore a wide range of monitoring stations in coastal areas in the Gulf of Finland and Gulf of Riga were chosen. The aim of the present research was to document the responses of chosen biomarkers of environmental contaminants in different unstudied areas of the Estonian coastal sea. During 2009 and 2010 we measured PAH metabolites, EROD activities, geno- and cytotoxicity, histology, parasites and other biomarkers from the eelpout (Zoarces viviparus), a resident benthic fish species. The results showed that fish from the Gulf of Riga emitted lower levels of fluorescence in fixed wavelength analyses (representing equivalents of PAH metabolites in bile and urine), and consistently, showed less geno- and cytotoxicity and parasite infection, higher liver somatic index (LSI) and a higher condition factor (CF) than fish inhabiting areas close to the Baltic proper and in the Gulf of Finland. The results point to the effect of long-range contaminant transportation, whether atmospheric or hydrodynamic, and also to the intensive shipping activity in international routes. This study fills the gap of knowledge in this area that has persisted until now. Nevertheless, more studies in this area on the different groups of contaminants are necessary, to specify the factors that are responsible for observed biological effects.     

New beach in a shallow estuarine lagoon: a model-based <Emphasis Type="Italic">E. coli</Emphasis> pollution risk assessment

A 3D hydrodynamic model has been applied to the Curonian Lagoon to study the pollution impact of E. coli on a new beach that might be opened in the lagoon. Through a field survey the E. coli inputs were measured and then used in the numerical model, and through laboratory experiments the decay rate of E. coli was established. The model has been calibrated and validated for the year 2015, and several scenarios have been studied, such as sewage system breakdown, severe weather conditions or high river loads. The model has then been run for a period of 12 years to obtain a robust statistics for the pollution on the planned beach. Results show that the decay rate of E. coli is between 0.55 days and 2.3 days and the modeled decay times are compatible with these numbers. The only scenario that would create a risk for the bathing waters of the beach is a breakdown of the sewage system on the Curonian Spit. In this case the hours (and days) over legally allowable bathing threshold were computed in order to estimate the number of days the beach could be closed. These results have been confirmed by the 12 year simulations. With an influence map analysis the two most critical sewage systems could be identified.     

A biochar-based medium in the biofiltration system: Removal efficiency,microorganism propagation,and the medium penetration modeling

Biofiltration is a method of biological treatment belonging to cleaner technologies because it does not produce secondary air pollutants, but helps to integrate natural processes in microorganisms for decomposing volatile air pollutants and solving odor problems. The birch wood biochar has been chosen as a principal material for biofilter bed medium. The experiments were conducted at the temperatures of 24, 28, and 32 °C, while the concentration of acetone, xylene, and ammonium reached 300 mg/m³ and the flow rate was 100 m³/hr. Before passing through the stage of the experimental research into the packing material inside biofilters, microorganisms were introduced. Four strains of microorganisms (including micromycetes Aspergillus versicolor BF-4 and Cladosporium herbarum 7KA, as well as yeast Exophiala sp. BF1 and bacterium Bacillus subtilis B20) were selected. At the inlet loading rate of 120 g/m³/hr, the highest elimination capacity of xylene in the biochar-based biofilter with the inoculated medium was 103 g/m³/hr, whereas that of ammonia was 102 g/m³/hr and that of acetone was 97 g/m³/hr, respectively. The maximum removal efficiency reached 86%, 85%, and 81%, respectively. The temperature condition (though characterized by some rapid changes) can hardly have a considerable influence on the biological effect (i.e., microbiological activity) of biofiltration; however, it can cause the changes in physical properties (e.g., solubility) of the investigated compounds.

Implications: The birch biochar can be successfully used in the biofiltration system for propagation of inoculated microorganisms, biodegrading acetone, xylene, and ammonia. At the inlet loading rate of 120 g/m³/hr, the highest elimination capacity of xylene was 103 g/m³/hr, that of ammonia was 102 g/m³/hr, and that of acetone was 97 g/m³/hr, respectively. The morphological structure of biochar can be affected by the aggressive air contaminants, causing the change in the medium specific surface area, which is one of the factors controlling the biofilter performance. Although biological effects in biofiltration are typically considered to be more important than physical effects, the former may be more important for compounds with high Henry’s Law coefficient values, and the biofilter design should thus provide conditions for better compound absorption.