Survey of the occurrence of residues of methyl tertiary butyl ether (MTBE) in Dutch drinking water sources and drinking water

An indicative survey has been carried out in The Netherlands investigating the presence of methyl tertiary butyl ether (MTBE) in drinking water and the corresponding sources. In total, 71 different sites used for the preparation of drinking water in The Netherlands were sampled in two successive seasons in 2001 involving the analysis of 156 samples. (ground water (n = 88), surface water (n = 17), bank filtrate water (n = 6) and drinking water (n = 45)). To combine high sample throughput with high selectivity and sensitivity, off-line purge and trap for sampling and gas chromatography mass spectrometry equipped with an automated thermal desorption sampler (TDS-GC-MS) was selected as the preferred analytical methodology. The developed procedure enabled the analysis of at least 40 samples per day and provided a limit of quantification of 2 ng l(-1). In the first period 63 samples of raw water were analyzed. Concentrations ranged between < 10 ng l(-1) and 420 ng l(-1) with a median concentration below 10 ng l(-1). The second period was focused at the re-sampling of positive locations (MTBE > 10 ng l(-1)) and a few additional drinking water utilities of which both the raw and drinking water of the utilities were analyzed. The median concentration of MTBE in the selected set of drinking water samples was 20 ng l(-1) (n = 45). At one location MTBE was found at a level of 2900 ng l(-1) caused by point source contamination of the ground water (11 900 ng l(-1)). Special attention has been paid to the quality of the results by analyzing all samples in duplicate and the analysis of control samples during each series of analyses.     

环境中的药物——LC-MS/MS分析地表水和地下水

成百上千的活性物质正被用于人药和兽药处方中.由于药物的广泛应用,它们的残留物可通过多种途径进入环境.虽然主要通过尿和粪便的排泄,但是药品生产中的排放也应被考虑.当抗生素用于水产业,就会产生更直接的影响.污水处理设备不能完全除去药物,因此药物会出现在地表和地下水样品中.近年来,人们对环境中药物的兴趣正在增加,需要建立一种快速、灵敏、有选择性的方法来分析水样.     

Ablagerung toxischer Chemieabfälle im August 2006 in Abidjan, Republik Côte d’Ivoire: Versuch einer Rekonstruktion

Background

Globally, every year several hundred million tons of problematic, e.g. chemical, wastes are generated stemming to more than 90% from the 25 OECD countries. Due to their partly considerable toxicity special and often expensive measures are required for their disposal. According to the Secretary of the ‘Basel Convention on the Control of Transboundary Movements of Hazardous Waste and Their Disposal’ annually at least 8.5 million tons of wastes are transboundarily traded. Although the ‘Basel Convention’ has set up rules how to handle international waste streams, certain waste amounts are illegally transported from the OECD countries to developing countries — basically for reasons of expenses. Often an environmental safe treatment of toxic waste is not ensured or even not possible in the receiving countries. As set forth in a report of the European Network for the Implementation and Enforcement of Environmental Law (IMPEL) published in 2006, the illegal trade with toxic waste has steadily increased. 3000 shipping documents of 17 European seaports were examined and 258 cargo holds were inspected showing that 68 of 140 waste shippings were illegal. Preventing illegal transports of waste meets with various obstacles. Controlling measures require considerable personal, technical, and logistic resources that are not sufficiently available in each country concerned. Missing or ineffective administrative structures hamper fast actions to stop illegal waste disposal. Partly, the political will to take the necessary steps is lacking. An additional problem is the fact that waste that is obtained from the regular shipping business is not subject to the Basel Convention but to the ‘International Convention for the Prevention of Pollution from Ships’. The implementing statures are summarized in the document MARPOL 73/78; the International Maritime Organization (IMO) is responsible. Identifying the origin of waste and thus defining the responsibility occasionally raises difficulties. This background provides a basis to try to reconstruct the course of events concerning the disposal of chemical waste in Abidjan.

Methods

Several information sources were utilized to reconstruct the course of events at Abidjan in August 2006; e.g. public press, declarations of international governmental organizations, especially of the UN and of its subsidiary organizations, communiqués of the Secretary of the Basel Convention, and statements of several NGOs. Nevertheless a complete reconstruction of the incident is impossible, since a detailed and reliable historical report is not available. Furthermore the responsible politicians have not undertaken significant efforts to shed light upon the incident. Additionally relevant documents of the participating companies are not available to the public.

Conclusions

The analyzed incident makes obvious that the control mechanisms of the Basel Convention can be circumvented. It remains unclear who has to take the political responsibility for the death of 10 people and for the health defects of thousands of humans. Possible civil and criminal consequences are not foreseeable for the actors and company owners involved in the illegal waste dumping. The people of Abidijan are confronted with unresolved questions regarding the occurrence of chronic diseases and possible long-term effects of remaining waste portions.

Recommendations and Perspectives

The incident demonstrates that the control of the transboundary transport and disposal of hazardous waste needs to be enforced and legal grey areas should be eliminated. It should be a task of the OECD countries and of all other economically and technically developed countries and organizations to support the developing countries’ efforts to build up the personal, technical, and infrastructural capacities for an efficient control of waste imports.     

Pesticides in Urban Atmospheres

A study of airborne particulate pesticides in urban atmospheres was conducted in 1963 and 1964. Samples were collected in eight agricultural communities and in jour communities with active insect control programs. Sampling and analysis procedures are described, briefly. Ambient concentrations of the various pesticides found in the different communities are presented. Survey, community; pollutant, pesticides, particulates.     

SYSTEMATIC APPROACHES TO ENVIRONMENTAL IMPACT ASSESSMENT: AN EVALUATION1

ABSTRACT. Increased public awareness of the environmental effects of large-scale projects and concomittant public participation in the environmental impact assessment process demand that assessment methods and procedures fulfill a wide range of desirable characteristics. These are developed and offered as specific criteria against which currently proposed environmental assessment procedures should be judged. Such procedures as checklists, matrices, networks (stepped matrices), overlays, linear vector analyses, and nonlinear evaluation systems are presented and judged in light of the proposed criteria. It is concluded that the use of checklists, the most common assessment format used to date, does not constitute a viable assessment procedure. Use of the matrix or stepped matrix techniques in conjunction with the linear vector or nonlinear evaluation systems, with the latter modified slightly, is seen as an approach to environmental assessment that will achieve most of the established criteria.     

Relation of Benzene Soluble Organic Matter to Suspended Participate Matter in the Atmosphere

This paper presents information concerning the response to the availability of control program grants under Sect. 4 of the Clean Air Act, P.L. 88-206. Statistics concerning awards are presented together with a discussion of the nature of the projects supported and the impact of this support on air pollution control efforts throughout the country.     

Mineralogy, morphology, and textural relationships in coatings on quartz grains in sediments in a quartz-sand aquifer

Mineralogical studies of coatings on quartz grains and bulk sediments from an aquifer on Western Cape Cod, Massachusetts, USA were carried out using a variety of transmission electron microscopy (TEM) techniques. Previous studies demonstrated that coatings on quartz grains control the adsorption properties of these sediments. Samples for TEM characterization were made by a gentle mechanical grinding method and focused ion beam (FIB) milling. The former method can make abundant electron-transparent coating assemblages for comprehensive and quantitative X-ray analysis and the latter technique protects the coating texture from being destroyed. Characterization of the samples from both a pristine area and an area heavily impacted by wastewater discharge shows similar coating textures and chemical compositions. Major constituents of the coating include Al-substituted goethite and illite/chlorite clays. Goethite is aggregated into well-crystallized domains through oriented attachment resulting in increased porosity. Illite/chlorite clays with various chemical compositions were observed to be mixed with goethite aggregates and aligned sub-parallel to the associated quartz surface. The uniform spatial distribution of wastewater-derived phosphorus throughout the coating from the wastewater-contaminated site suggests that all of the coating constituents, including those adjacent to the quartz surface, are accessible to groundwater solutes. Both TEM characterization and chemical extraction results indicate there is a significantly greater amount of amorphous iron oxide in samples from wastewater discharge area compared to those from the pristine region, which might reflect the impact of redox cycling of iron under the wastewater-discharge area. Coating compositions are consistent with the moderate metal and oxy-metalloid adsorption capacities, low but significant cation exchange capacities, and control of iron(III) solubility by goethite observed in reactive transport experimental and modeling studies conducted at the site.