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1.
Buse Tuğba Zaman Emine Gülhan Bakırdere Nursu Aylin Kasa Serenay Deniz Sabriye Sel Dotse Selali Chormey Sezgin Bakırdere 《Environmental monitoring and assessment》2018,190(7):437
This study describes the determination of trace levels of copper by slotted quartz tube atomic absorption spectrometry after dispersive liquid-liquid microextraction. A ligand synthesized from the reaction of salicylaldehyde and 1-naphthylamine was used to form coordinate copper complex prior to extraction. All parameters that influence the output of complex formation, extraction, and instrumental measurement were optimized to enhance the absorbance signal of copper. Under the optimum conditions, about 104-fold enhancement in sensitivity was recorded over the conventional flame atomic absorption spectrometer, corresponding to a 0.51 ng/mL detection limit. The percent relative standard deviation calculated for the lowest concentration (4.8%) indicated high precision for the experimental procedure. Accuracy and applicability of the optimum method were determined by performing spiked recovery tests on urine, lake water, and mineral water samples. Satisfactory recovery results were obtained between 82.2 and 106.3% at four different concentrations. Matrix matching method was also performed to increase the accuracy of quantification, and the percent recovery calculated for 175 ng/mL was 105.14%. 相似文献
2.
Sorption of alpha and beta hydrophobic endosulfan in a Vertisol from southeast region of Turkey 总被引:1,自引:0,他引:1
Aye Dilek Atasoy Ahmet Ruhi Mermut Halil Kumbur Faruk nce Hüdaverdi Arslan Emel Deniz Avc 《Chemosphere》2009,74(11):1450-1456
Endosulfan has been applied to control numerous insects in a variety of food and non-food crops. Limited information is available on dynamics of this pesticide in the soil. The objective of this research was to determine the adsorption–desorption behavior of the alpha (α) and beta (β) endosulfan in a Vertisol from the southeast region of Turkey, where cotton is the main crop in the large irrigated lowlands. The α and β endosulfan were adsorbed considerably and Freundlich adsorption–desorption isotherms fitted the α and β endosulfan data (R2 > 0.98). Freundlich adsorption coefficients (Kf) for the α endosulfan ranged between 21.63 and 16.33 while for the β endosulfan they were between 14.01 and 17.98 for the Ap and Bw2 horizons. The difference of Kf values of α and β endosulfan for two horizons were explained with the slight difference in the amount of organic matter and clay, but considerable difference in Fe contents of the two horizons. Alpha and β endosulfan Kfd values were 118.03 and 45.81 for the Ap and 48.08 and 68.71 for the Bw2 horizons. Higher adsorption and desorption behavior of the endosulfan isomers for the same horizon was attributed to poor physical bonding between the endosulfan molecule and the surfaces of fundamental soil particles. This fact is thought to increase the effective use of endosulfan in agriculture with a possibility of its movement to the surface and groundwater in the Vertisol studied. 相似文献
3.
Background, aim and scope
Due to their ecological niche and insectivore nature, lizards are of increased risk of exposure to pesticides in agricultural areas. In addition to their potential direct effects on non-target species, insecticides can also result in indirect impacts on lizard population by reducing their food source. Carbaryl is a common insecticide that is widely used in areas of Turkey that are home to a variety of reptiles. However, to date, little is known about the potential effects of the exposure of reptiles such as lizards or snakes to this pesticide. The aim of the study was to investigate toxic effects of carbaryl on the testes of snake-eyed lizard, Ophisops elegans that is common to regions in Turkey where Carbaryl is applied and that it can be easily cultured in the laboratory. 相似文献4.
Air pollution forecasting in Ankara, Turkey using air pollution index and its relation to assimilative capacity of the atmosphere 总被引:1,自引:0,他引:1
D. Deniz Genc Canan Yesilyurt Gurdal Tuncel 《Environmental monitoring and assessment》2010,161(1-4):11-27
A conditional time-averaged gradient (COTAG) system has been developed to provide direct long-term (weekly to monthly) average flux gradient measurements for a range of trace gases, between land and atmosphere. Over daily periods, atmospheric conditions can range from high stability, where the vertical gradients of ambient concentration are enhanced due to very small diffusivity, to highly unstable conditions, in which concentration gradients are small due to the intense turbulent activity of the surface layer. The large vertical gradients generated by high stability would bias the estimate of the actual flux: to avoid this, the COTAG system samples conditionally, within a carefully refined range of stability. A comparison with a continuous flux gradient system suggested that the removal of stable conditions from the sampling period does not substantially modify the evaluation of the long-term fluxes. 相似文献
5.
Adem Asan Rukiye Aydin Deniz Karsli Semiz Vildan Erci Ibrahim Isildak 《Environmental monitoring and assessment》2013,185(3):2115-2121
In this study, an ultra-sensitive and highly selective, rapid flow-injection spectrophotometric method for the determination of iron (II) and total iron has been proposed. The method was based on the reaction between iron (II) and 2′, 3, 4′, 5, 7-pentahydroxyflavone in slightly acidic solution with a strong absorption at 415 nm. The carrier solution used was 1?×?10?5 M 2′, 3, 4′, 5, 7-pentahydroxyflavone in 0.1 M HAc/Ac? buffer solution at pH 4.5. Parameters that affect simultaneously the determination of iron (II) and interfering ions were tested. The relative standard deviation for the determination of 50 μg L?1 iron (II) was 0.85 % (n?=?10), and the limit of detection (blank signal plus three times the standard deviation of the blank) was 3 μg L?1, both based on injection volumes of 20 μL. The method has been successfully applied to the determination of iron (II) and total iron in water samples and ore samples. The method was verified by analysing a certified reference material Zn/Al/Cu 43XZ3F. 相似文献
6.
Şeyda Fikirdeşici Ergen Esra Üçüncü Tunca Alper Devrim Ozkan Tolga Tarkan Ölmez Emrah Acaröz Ahmet Altındağ 《Chemistry and Ecology》2013,29(5):455-465
The accumulations of Al, Cd, Cr, Cu, Fe, Ni, Pb and Zn in the exoskeleton, gills, hepatopancreas and abdominal muscles of crayfish Astacus leptodactylus (Eschscholtz, 1823) were determined. The strongest correlation observed was between Cr and Ni in the gills (r?=?0.904); moderate to strong correlations between Al, Cr, Fe, Ni and Cu were also observed in gill tissue. Disregarding the gills, the strongest correlation was found between Cu and Zn in the hepatopancreas (r?=?0.808); the correlation between these two metals might have been a result of metallothionein activity. The accumulation of Pb was found to correlate with that of Cd in the exoskeleton, Cd and Zn in the gills, Zn and Cu in the hepatopancreas and Cu in the abdominal muscle. None of these correlations were present in lakewater and sediment samples, suggesting that the crayfish metabolism may be responsible for the co-accumulation of metal–metal pairs. As all correlations in non-gill tissues are observed between divalent metals, a shared transporter such as divalent metal transporter 1 might be involved in the accumulation of these metals. 相似文献
7.
Timur Deniz Ozer Cinar Ana C Marques C P Leslie Grady 《Water environment research》2006,78(4):340-352
The response of a mixed microbial culture to cyclic aerobic and anoxic (denitrifying) conditions was studied in a chemostat with a 48-hour hydraulic residence time receiving a feed containing benzoate and pyruvate. When the cyclic conditions were 3-hour aerobic and 9-hour anoxic, the bacteria-degraded benzoate aerobically via the catechol 2,3-dioxygenase (C23DO) pathway. The quantity of C23DO remained constant throughout the anoxic period but decreased during the initial portion of the aerobic period before returning to the level present in the anoxic period. Anoxic biodegradation of benzoate was via benzoyl-CoA reductase, which remained constant regardless of the redox condition. The aerobic benzoate uptake capability (AeBUC) of the culture increased during the aerobic period but decreased during the anoxic period. The anoxic benzoate uptake capability (AnBUC) exhibited the opposite response. When the cycle was 6-hour aerobic and 6-hour anoxic, aerobic biodegradation of benzoate proceeded via the protocatechuate 4,5-dioxygenase (P45DO) pathway. The P45DO activity decreased early in the aerobic period, but then increased to the level present during the anoxic period. The level of benzoyl-CoA reductase was constant throughout the cycle. Furthermore, AeBUC and AnBUC responded in much the same way as in the 3/9-hour chemostat. During a 9-hour aerobic and 3-hour anoxic cycle, the culture synthesized both P45DO and C23DO, with the former having significantly higher activity. Unlike the other two cycles, AeBUC changed little during the aerobic period, although AnBUC decreased. The culture was well-adapted to the cyclic conditions as evidenced by the lack of accumulation of either substrate during any cycle tested. This suggests that cyclic aerobic-anoxic processes can be used in industrial wastewater-treatment facilities receiving significant quantities of simple aromatic compounds like benzoate. However, the results showed that the kinetics of benzoate degradation were different under aerobic and anoxic conditions, a situation that must be considered when modeling cyclic bioreactors receiving aromatic compounds. 相似文献
8.
Enver Guler Deniz Ozakdag Muserref Arda Mithat Yuksel Nalan Kabay 《Environmental geochemistry and health》2010,32(4):335-339
The effect of feed seawater temperature on the quality of product water in a reverse osmosis process was investigated using
typical seawater at Urla Bay, Izmir region, Turkey. The tests were carried out at different feed seawater temperatures (11–23°C)
using two RO modules with one membrane element each. A number of variables, including pH, conductivity, total dissolved solids,
salinity, rejection percentage of a number of ions (Na+, K+, Ca2+, Mg2+, Cl−, HCO3
−, and SO4
2−), and the levels of boron and turbidities in collected permeates, were measured. The suitability of these permeates as irrigation
and drinking water was checked by comparison with water quality standards. 相似文献
9.
Colby J. Tanner Gül Deniz Salalι Andrew L. Jackson 《Behavioral ecology and sociobiology》2011,65(2):249-256
Human activity can have a large impact on surrounding ecosystems. For example, humans alter resource distributions for other
species, potentially modifying these species competitive dynamics. These changes in local competitive processes are frequently
associated with species invasions. Here, we investigate how differences in resource distribution affect competitive behaviour
using the highly invasive European shore crab (Carcinus maenas). Using a controlled laboratory experiment in combination with behaviour assays and social network analysis, we show that
individuals feeding in habitats with clumped food distributions are more aggressive than individuals feeding in habitats where
food is evenly dispersed, and this aggression is present even on days where crabs are not feeding. Additionally, this persistent
aggression can be induced, suggesting that individuals of this invasive species possess the flexibility to modify their competitive
behaviours in response to differences in food distributions. Furthermore, we show how these individual responses can lead
to changes in overall organisation of aggressive interactions within a population. We discuss these results in relation to
how human impacts can have long-term effects on competitive behavioural strategies, and how behavioural flexibility can allow
invasive species to colonise and persist in highly impacted sites such as urban ecosystems. 相似文献
10.
Hanedar Asude Çifçi Deniz İzlen Zafer Nur Görgün Erdem 《Journal of Material Cycles and Waste Management》2022,24(5):1760-1767
Journal of Material Cycles and Waste Management - In this study, the amount of medical waste generated in a high-populated city in Turkey between January 2018 and August 2021 was evaluated, and the... 相似文献