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1.
Shinya Inazumi Hiroyasu Ohtsu Yu Otake Makoto Kimura Masashi Kamon 《Journal of Material Cycles and Waste Management》2009,11(1):55-64
An evaluation method that can express the local leakage of leachate from joint sections in steel pipe sheet pile (SPSP) cutoff
walls is discussed in this study. In particular, the evaluation of environmental feasibility (containment of leachates containing
toxic substances) considering a three-dimensional arrangement and hydraulic conductivity distribution of the joint sections
in the SPSP cutoff wall is compared with an evaluation that uses the equivalent hydraulic conductivity. This equivalent hydraulic
conductivity assumes that the joint section and the steel pipe are integrated; therefore, the hydraulic conductivity is substituted
with a uniform permeable layer. However, in an evaluation that employs the equivalent hydraulic conductivity, it is difficult
to consider the local leakage of leachate containing toxic substances from the joint sections in the SPSP cutoff wall. It
was established that evaluations of the environmental feasibility of SPSP cutoff walls with joint sections must take into
account the local leakage of leachates containing toxic substances from the joint sections. Also, it was clarified that technologies
that lower the hydraulic conductivities of joint sections in SPSP cutoff walls and also facilitate the use of sparser joint
arrangements contribute significantly to increasing the environmental feasibility of SPSP cutoff walls at landfill sites. 相似文献
2.
The biodegradation of polycyclic aromatic hydrocarbons (PAHs) in aqueous deoxyribonucleic acid (DNA) solution from contaminated soil washing was investigated. Initial data with a model effluent consisting of anthracene, phenanthrene, pyrene and benzo[a]pyrene that were individually dissolved in 1% aqueous DNA solution confirmed their positive degradation by Sphingomonas sp. at around 10(8)CFU mL(-1) initial cell loading. For anthracene and phenanthrene, complete removal was achieved within 1h treatment. Degradation of pyrene and benzo[a]pyrene took a relatively longer time of a few days and weeks, respectively. DNA-dissolved PAHs were also degraded relatively faster than PAH crystals in aqueous medium to suggest that the binding of the PAHs in the polymer does not pose serious constraint to bacterial uptake. The DNA was stable against the PAH-degrading bacteria. Parallel experiments with actual DNA solutions obtained during pyrene extraction from an artificially spiked soil also showed similar results. Close to 100% pyrene degradation was achieved after 1d treatment. With its chemical stability, the cell-treated DNA was re-used up to four cycles without a considerable decline in extraction performance. 相似文献
3.
Influence of chemical characteristics of humic substances on the partition coefficient of a chlorinated dioxin 总被引:2,自引:0,他引:2
The partition coefficients (Koc) of 1,2,3,4,6,7,8-heptachlorodibenzo-p-dioxin (HpCDD) with respect to a variety of humic substances (HSs) were evaluated by a method involving solid-phase microextraction and gas chromatography-electron capture detection. The log Koc values for each of the HS samples were in the range of 6.4-7.7. The log Koc values for HAs from tropical peat, brown forest and ando soils were in the range of 7.3-7.6, similar to the calculated value for the octanol-water partition coefficient (log Koc=7.56). In contrast, the log Koc values for FAs and peat HAs were 0.5-1 unit lower than the calculated value. The parameters for the polarity of HSs, as calculated from (N+O)/C, O/C atomic ratios and the carboxyl group content, were numerically similar related to the log Koc for HpCDD. These results show that the Koc values for HpCDD are significantly influenced by the polarity of HSs. 相似文献
4.
Modified clean-up for PBDD,PBDF and PBDE with an active carbon column--its application to sediments 总被引:1,自引:0,他引:1
Choi JW Onodera J Kitamura K Hashimoto S Ito H Suzuki N Sakai S Morita M 《Chemosphere》2003,53(6):637-643
A clean-up method for polybrominated dibenzo-p-dioxins (PBDDs), dibenzofurans (PBDFs) and diphenyl ethers (PBDEs) was modified using combinations of multi-layered silica gel, Florisil and active carbon columns. By using active carbon column chromatography in the final procedure, PBDEs were well separated from PBDD/Fs in an elution test with reference standards. We report the application of this method to sediment samples taken from industrialized areas in Japan. These sediments contained PBDEs ranging in concentration from 13 to 2394 pg/g, dry wt. PBDEs did not interfere with the quantification of PBDD/Fs. In addition, PBDEs found in the PBDD/F fraction did not interfere with the identification of PBDFs using the HRGC/HRMS separation method. Some 2,3,7,8-tetra- to hexabrominated dioxins and furans were also detected in the sediment samples. 相似文献
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6.
以机械设备为起因的工伤事故中,叉车事故比较常见。首先介绍了日本国内叉车事故的分类统计数据,从硬件设备方面,概述了叉车减灾的主要措施,针对驾驶员在行驶中将肢体伸出驾驶仓外时易发生冲撞或挤压事故的情况,提出了基于光幕及激光扫描器的驾驶员肢体伸出仓外的监控方法。然后根据叉车的不同刹车性能指标,探讨了如何设定检测领域大小的问题。对蓄电池式1.5t叉车进行的实验表明,在检测系统能直接控制刹车的情况下,我们提出的方法是行之有效的。 相似文献
7.
Despite the fact that several manufacturers of service robots launched their innovations into the market, worldwide guidelines or regulations concerning the safety aspects of service robots are not yet available. However the general principles and methodologies of safety of machinery (e.g., ISO/IEC Guide 51, partly ISO14121, ISO12100) could be implemented to a certain degree. The safety of seven service robots as an emerging technology was verified by safety professionals of “NPO – the Safety Engineering Laboratory” a Non Profit Organization. NPO verified the “Critical Hazards” for each service robot mentioned by the respective manufacturers. For those cases, both the “As Low As Reasonably Practicable” principle and the “Reasonable Alternative Design” standard were applied for judging if the risk associated with the Critical Hazards were tolerable or not and if state of the art measures for reducing the risk were applied adequately. These experiences will help to establish guidelines for the safety of service robots as an emerging technology in the future. 相似文献
8.
Treatment of bleaching wastewater from pulp paper plants in China using enzymes and coagulants 总被引:1,自引:0,他引:1
ZHANG Tong Shinji Wa Takao Yamagishi Ichikawa Hiroyasu Kenji Tatsumi ZHAO Qingxiang 《环境科学学报(英文版)》1999,11(4):480-484
IntroductionBleachingwastewaterfrompulppaperplantscontainsmanykindsofchlorinatedorganiccompoundswhichareprovedtobecarcinogenic,mutagenicandrefractory(Gellman,1988;Paasivirta,1988;Garden,1990;Suntio,1988;Vuorinen,1987;Seppala,1988).Severalmethods,inc… 相似文献
9.
Tomoaki Tsutsumi Toshihiko Yanagi Munetomo Nakamura Yoichi Kono Hiroyasu Uchibe Takao Iida Tsuguhide Hori Reiko Nakagawa Kazuhiro Tobiishi Rieko Matsuda Kumiko Sasaki Masatake Toyoda 《Chemosphere》2001,45(8):1129-1137
Total diet study (TDS) samples of 14 food groups from 16 locations in Japan, collected in 1999 and 2000, were analyzed for polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), and dioxin-like polychlorinated biphenyls (dioxin-like PCBs) to estimate the update of daily intake of these contaminants from food. The mean daily intake of toxic equivalency (TEQ) for an adult weighing 50 kg, calculated at non-detected isomer concentrations equal to zero (ND=0), was estimated to be 2.25 pg TEQ/kg b.w./day. When non-detected isomer concentrations are assumed to be equal to half of the limits of detection (ND=1/2 LOD), the mean daily intake was estimated to be 3.22 pg TEQ/kg b.w./day. These values were below the tolerable daily intake (TDI) of 4 pg TEQ/kg b.w. for PCDD/Fs and dioxin-like PCBs set in Japan. In both the estimates, the mean daily intakes were highest from fish and shellfish (76.9% at ND=0 and 53.9% at ND=1/2 LOD of the total TEQs), followed by those from meat and eggs (15.5% at ND=0 and 11.7% at ND=1/2 LOD of the total TEQs). Congener specific data revealed that these total TEQ levels were dominated by 1,2,3,7,8-PeCDD, 2,3,4,7,8-PeCDF and 3,3′,4,4′,5-PeCB in each case (71.7% at ND=0 and 63.1% at ND=1/2 LOD of the total TEQs). The dioxin-like PCBs (non-ortho and mono-ortho PCBs) accounted for about 50% of these total TEQs. These data will be very useful in the risk assessment of PCDD/Fs and dioxin-like PCBs from food in Japan. 相似文献
10.
Hiroyasu Yamazaki Masayuki Terada Akira Tsuboi Chizuyo Matsubara Toshiaki Hata Yasuo Kakiuchi 《毒物与环境化学》2013,95(1-2):71-81
Orally administered 3H‐benzo(a)pyrene (BP) was persistent in protein fraction of liver, lung and kidney. The radioactivity in this fraction increased with time after administration and accounted for about 50%, 40% and 65% of total radioactivity in liver, lung and kidney, respectively at 48 hr. The BP metabolites binding proteins were located in cytosol and had molecular weights of 40,000–60,000 and 80,000–100,000 as determined by gel filtration and polyacrylamide gel disc electrophoresis. In addition, at 48hr after administration, about 80% of radioactivity in high molecular weight protein fraction was found to be precipitated by trichloroacetic acid treatment. These results suggest that BP metabolites might be transported by and are persistent in these protein fractions of liver, lung and kidney if the intake of BP is continuous. These proteins, therefore, appeared to be closely related to cell toxicity or mutagenicity in these organs as well as DNA. 相似文献