Technical feasibility study of a low-cost hybrid PAC-UF system for wastewater reclamation and reuse: a focus on feedwater production for low-pressure boilers

This study has applied the concept of the hybrid PAC-UF process in the treatment of the final effluent of the palm oil industry for reuse as feedwater for low-pressure boilers. In a bench-scale set-up, a low-cost empty fruit bunch-based powdered activated carbon (PAC) was employed for upstream adsorption of biotreated palm oil mill effluent (BPOME) with the process conditions: 60 g/L dose of PAC, 68 min of mixing time and 200 rpm of mixing speed, to reduce the feedwater strength, alleviate probable fouling of the membranes and thus improve the process flux (productivity). Three polyethersulfone ultrafiltration membranes of molecular weight cut-off (MWCO) of 1, 5 and 10 kDa were investigated in a cross-flow filtration mode, and under constant transmembrane pressures of 40, 80, and 120 kPa. The permeate qualities of the hybrid processes were evaluated, and it was found that the integrated process with the 1 kDa MWCO UF membrane yielded the best water quality that falls within the US EPA reuse standard for boiler-feed and cooling water. It was also observed that the permeate quality is fit for extended reuse as process water in the cement, petroleum and coal industries. In addition, the hybrid system’s operation consumed 37.13 Wh m⁻³ of energy at the highest applied pressure of 120 kPa, which is far lesser than the typical energy requirement range (0.8–1.0 kWh m⁻³) for such wastewater reclamation.

     

Estimation of Daily Streamflow of Southeastern Coastal Plain Watersheds by Combining Estimated Magnitude and Sequence

Commonly used methods to predict streamflow at ungauged watersheds implicitly predict streamflow magnitude and temporal sequence concurrently. An alternative approach that has not been fully explored is the conceptualization of streamflow as a composite of two separable components of magnitude and sequence, where each component is estimated separately and then combined. Magnitude is modeled using the flow duration curve (FDC), whereas sequence is modeled by transferring streamflow sequence of gauged watershed(s). This study tests the applicability of the approach on watersheds ranging in size from about 25‐7,226 km² in Southeastern Coastal Plain (U.S.) with substantial surface storage of wetlands. A 19‐point regionalized FDC is developed to estimate streamflow magnitude using the three most selected variables (drainage area, hydrologic soil index, and maximum 24‐h precipitation with a recurrence interval of 100 years) by a greedy‐heuristic search process. The results of validation on four watersheds (Trent River, North Carolina: 02092500; Satilla River, Georgia: 02226500; Black River, South Carolina: 02136000; and Coosawhatchie River, South Carolina: 02176500) yielded Nash‐Sutcliffe efficiency values of 0.86‐0.98 for the predicted magnitude and 0.09‐0.84 for the predicted daily streamflow over a simulation period of 1960‐2010. The prediction accuracy of the method on two headwater watersheds at Santee Experimental Forest in coastal South Carolina was weak, but comparable to simulations by MIKE‐SHE.     

Child passengers and driver culpability in fatal crashes by driver gender

Objective: Studies based on accident statistics generally suggest that the presence of a passenger reduces adult drivers' accident risk. However, passengers have been reported to be a source of distraction in a remarkable portion of distraction-related crashes. Although the effect of passengers on driving performance has been studied extensively, few studies have focused on how a child passenger affects the driver.

?A child in a car is a potential distractor for parents, especially for mothers of small children, who often suffer from sleep deficit. The aim of this study was to examine how the presence of child passengers of different ages is associated with a higher driver culpability, which was expected due to child-related distraction and fatigue.

Methods: The analysis was based on the comprehensive data of fatal crashes studied in-depth by multidisciplinary road accident investigation teams in Finland during 1988–2012. Teams determine the primary party who had the most crucial effect on the origin of the event. We define the primary party as culpable and the others involved as nonculpable drivers. The culpability rate was defined as the percentage of culpable drivers and rates were compared for drivers with a child/teen passenger aged 0–17 years (N = 348), with an adult passenger without children (N = 324), and when driving alone (N = 579), grouped by child age and driver gender.

?Drivers with specific risk-related behavior (substantial speeding, driving when intoxicated, unbelted, or without a license) were excluded from the analyses, in order to make the drivers with and without children comparable. Only drivers 26–47 years old were included, representing parents with children 0–9 years of age.

Results: Male drivers were less often culpable with 0- to 17-year-old passengers in the car than alone or with adults. This was not the case with female drivers. The gender difference in culpability was most marked with small children age 0–4 years. Female drivers' culpability rate with a 0- to 4-year-old child passenger was higher and male drivers' culpability rate was lower compared to drivers without passengers or with only adult passengers.

Conclusion: The results indicate that female drivers are at higher risk of crashes than male drivers when driving with small children. Further research is needed to replicate this finding and to determine causal mechanisms.     

Modeling natural attenuation of petroleum hydrocarbon contamination using alternate electron acceptors: Case study comparing bioplume iii with BIOSCREEN

Natural attenuation holds great promise as a cost‐effective means of remedying groundwater contamination at petroleum spill sites: this is particularly true at sites with sufficient background concentrations of alternate electron acceptors (nitrate and/or sulfate). The study reported in this article compared the results of a new Environmental Protection Agency (EPA) numerical model (BIOPLUME III) with an updated EPA analytical model (BIOSCREEN Version 1.4) used to predict natural attenuation at an underground fuel spill site in Oklahoma. High background sulfate concentrations were shown to result in unrealistic predictions from both BIOSCREEN and BIOPLUME III. BIOSCREEN could be easily used with a data set not significantly enlarged from that used in a routine leaking fuel tank investigation. BIOPLUME III was much more difficult to use and did not yield reliable results. Results of this study indicate that the additional complexity of the BIOPLUME III model is not justified for simple sites.     

Growing hot pepper for cabbage looper, Trichopulsia ni (Hübner) and spider mite, Tetranychus urticae (Koch) control

With the public perception that synthetic pesticides leave harmful residues in crop produce for human consumption, there has been increased interest in using natural products for pest control. The potential of using fruit extracts of hot pepper for controlling the cabbage looper, Trichopulsia ni (Hübner) and spider mite, Tetranychus urticae Koch is explored in this investigation. Crude extracts from fruits of Capsicum chinense, C. frutescens, C. baccatum, and C. annuum, were prepared and tested under laboratory conditions for their insecticidal and acaricidal performance. Mortality was greatest (94%) when fruit extract of accession PI-593566 (C. annuum) was sprayed on larvae of the cabbage looper, while crude extracts of accessions PI-241675 (C. frutescens) and PI-310488 (C. annuum) were repellent to the spider mite. We investigated differences in chemical composition of the crude fruit extracts that may explain the observed differences in mortality and repellency between accessions. Gas Chromatography-Mass Spectrometry spectrometric analysis revealed that capsaicin and dihydrocapsaicin, the pungent components of pepper fruit, were not correlated with toxicity or repellency, indicating that the two capsaicinoids are not likely related to the efficacy of pepper fruit extracts. Major compounds in hot pepper fruit extracts were detected and identified as pentadecanoic acid methyl ester, hexadecanoic acid methyl ester, and octadecanoic acid methyl ester. Spectrometric analysis and toxicity to cabbage looper larvae revealed that pentadecanoic acid methyl ester is likely related to cabbage looper mortality. However, the concentration of pentadecanoic acid methyl ester in some accessions was insufficient to explain the observed mortality of cabbage looper and repellency of spider mite. Fruit extracts of accessions PI-593566 (C. annuum) and PI-241675 (C. frutescens) could be useful for managing populations of cabbage loopers and spider mites, which could reduce reliance on synthetic pesticides. Further study is needed to investigate performance of hot pepper extracts under ultra-violet light and field conditions.