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Despite the widespread use of benzotriazoles as corrosion inhibitors in many household goods, studies on the occurrence of these compounds in indoor air are scarce. In this study, five benzotriazole derivatives were measured in 83 indoor air samples collected from various locations in Albany, New York, USA. Benzotriazoles were found in a majority of the indoor air samples, and the concentrations of their sum in bulk (vapor plus particulate phases) indoor air ranged from below the method limit of quantification to 492 ng·m?3 (geometric mean: 5.8 ng·m?3). The highest geometric mean concentration was found in air samples collected in parking garages (155 ng·m?3), followed by barbershops (13.6), public places (11.5), auto repair shops (5.2), automobiles (4.5), homes (4.5), offices (3.7), and laboratories (2.8). Inhalation exposure to benzotriazoles was calculated on the basis of the measured geometric mean concentrations and air inhalation rate. The highest exposure dose was found for teenagers, with a geometric mean inhalation exposure dose of 79 ng·day?1. The body-weight normalized exposure dose, however, was the highest for infants, at 3.2 ng·(kg bw)?1·day?1. 相似文献
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上软下硬地层地区进行隧道开挖时,常引起较大的地表沉降,危及地表构筑物。依托深圳地铁7号线安托山停车场出入线下穿深圳北环大道工程,采用现场监测研究方法,对该类地层双线隧道下穿既有道路引起的围岩及地层位移进行研究。研究结果表明:道路荷载对隧道围岩沉降有较大影响,当双线隧道间距较小时,全断面注浆对注浆段上方较浅地层位移影响较明显,对临近隧道较深处影响较明显,全断面注浆对地面沉降有较好的控制作用,但要注意控制隆起,该工程中全断面注浆对注浆加固圈以外8 m内影响较大,8~13 m范围影响较小。通过多种监测手段相结合,可以更好的保障施工安全。 相似文献
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评价甲基环戊二烯基三羰基锰(MMT)抗爆剂 总被引:4,自引:0,他引:4
评述了抗爆剂甲基环戊二烯基三羰基锰(MMT)研究和应用的最新进展。MMT的合成工艺简单,抗爆能力优良,燃烧沉积物易于清除,不会堵塞尾气催化净化剂,毒性较小,环境安全性高,可替代四乙基铅作为抗爆剂。 相似文献
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为了有效减少装配式建筑工程施工安全事故,考虑政府监管部门与施工单位之间存在信息不对称,基于有限理性条件下双方互动关系构建装配式建筑施工安全动态监管演化博弈模型,并分析其稳定策略.采用系统动力学(SD)方法仿真分析在动态监管策略及外部变量调整条件下的演化博弈过程.研究结果表明:政府强弱监管的成本差、施工单位加强安全管理的... 相似文献
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Numerical study of the effects of local atmospheric circulations on a pollution event over Beijing-Tianjin-Hebei, China 总被引:2,自引:0,他引:2
Yucong Miao Shuhua Liu Yijia Zheng Shu Wang Bicheng Chen Hui Zheng Jingchuan Zhao 《环境科学学报(英文版)》2015,27(4):9-20
Currently, the Chinese central government is considering plans to build a trilateral economic sphere in the Bohai Bay area, including Beijing, Tianjin and Hebei(BTH), where haze pollution frequently occurs. To achieve sustainable development, it is necessary to understand the physical mechanism of the haze pollution there. Therefore, the pollutant transport mechanisms of a haze event over the BTH region from 23 to 24 September 2011 were studied using the Weather Research and Forecasting model and the FLEXible-PARTicle dispersion model to understand the effects of the local atmospheric circulations and atmospheric boundary layer structure. Results suggested that the penetration by sea-breeze could strengthen the vertical dispersion by lifting up the planetary boundary layer height(PBLH) and carry the local pollutants to the downstream areas; in the early night, two elevated pollution layers(EPLs) may be generated over the mountain areas: the pollutants in the upper EPL at the altitude of 2–2.5 km were favored to disperse by long-range transport, while the lower EPL at the altitude of 1 km may serve as a reservoir, and the pollutants there could be transported downward and contribute to the surface air pollution.The intensity of the sea–land and mountain–valley breeze circulations played an important role in the vertical transport and distribution of pollutants. It was also found that the diurnal evolution of the PBLH is important for the vertical dispersion of the pollutants,which is strongly affected by the local atmospheric circulations and the distribution of urban areas. 相似文献
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介绍一种用五氧化二钇对TiO2进行施主掺杂来改善TiO2的光作用范围的方法,并研究用该方法制备的掺杂二氧化钛对久效磷的降解情况.钇离子以草酸盐化合物形式按比例掺杂到草酸氧钛酸中,经过结晶析出针状钇掺杂草酸氧钛酸晶体,再经过热分解和焙烧获得钇掺杂二氧化钛光催化剂粉体.钇掺杂二氧化钛光催化剂粉体中金红石矿型TiO2和锐钛矿型TiO2都分别控制为质量百分数45%和55%左右,粒度分布在0.2~0.5 μm范围,颗粒接近球形,掺钇杂量为质量百分数0.2%时光催化效果较佳,日光灯降解6 h后,久效磷的无机磷回收率达到质量百分数96.4%. 相似文献
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Li Haifeng Liu Yuxian Lan Yongyin Zhao Yanan Lu Anxiang Li Cheng Lei Rongrong Xue Jingchuan Liu Wenbin 《Environmental science and pollution research international》2022,29(39):58828-58842
Environmental Science and Pollution Research - Despite the restrictions on polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecanes (HBCDDs), these chemicals are still ubiquitous... 相似文献
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