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Werner Mikus Lilla Zadory Dennis Rumley Dean Hegg Risto Laulajainen 《Umweltwissenschaften und Schadstoff-Forschung》2010,22(4):511-512
BOOKS
The Handbook of Environmental Chemistry Founded by: Otto Hutzinger – Publisher: Springer – Editors-in-chief: Damià Barceló · Andrey G. Kostianoy – ISSN: 1867-979X 相似文献2.
Chlorination of naphthalene by Cl atoms has been studied in the gas phase. The chlorinating agent was produced by γ-radiolysis of tetrachloromethane. At low conversions only monosubstituted products are observed. Both isomers are formed, the yield of 1-chloronaphthalene exceeding that one of its isomer. The extent of the addition reaction increases with the temperature. The relative Arrhenius plot of observed rate constants is linear over the temperature range investigated (60–120 °C) and its slope corresponds to a difference of 11.0 kJ/mol between the activation energies of 2-chloronaphthalene and 1-chloronaphthalene. 相似文献
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