Environmental interactions of Sulphlex pavement

Sulphlex, a mixture of elemental sulfur and plasticizers, has been considered for use as an asphalt substitute in road construction. Because this material contains substantial quantities of elemental sulfur, it is a potential substrate for growth of sulfur-oxidising bacteria. Experiments, performed to determine the susceptibility of Sulphlex in Sulphlex-containing media to degradation by Thiobacillus thiooxidans, resulted in breakdown of the Sulphlex material and concomitant production of acid. In concurrent studies, plants were grown in Sulphlex-amended soils. These plants exhibited higher sulfur content and reduced productivity as compared with plants grown in unamended soils, indicating that Sulphlex was being broken down in the soil and that the breakdown products were apparently having a detrimental effect on plant productivity. These experiments indicate that naturally occurring sulfur-oxidising bacteria have the potential to break down Sulphlex paving material, resulting in adverse effects on both the structural integrity of the pavement and the local environment.     

Influence of Suspended Clay Minerals and Humic Matter on the Solid Phase Extraction Efficiency of Selected Pesticides from Water

The purpose of this investigation was to determine the influence of humic acids (HA) and Ca-montmorillonite (CaM) on the solid-phase extraction (SPE) efficiency of atrazine, alachlor and α-cypermethrin from water samples at various pH-values. The nature and intensity of binding of the studied pesticides to CaM were determined by X-ray diffraction analysis and termogravimetric analysis (TGA) test. The studied pesticides eluted from discs were analysed by thin-layer chromatography (TLC). The effects of CaM and humic acid were generally pH-dependent and acted independently in extraction efficiency influence. Lower recovery of pesticides was observed at higher pH values when CaM was ≥0.1 g and was attributed to greater dispersion of clay, increased surface area and subsequent adsorption. Concentrations of dissolved organic carbon (DOC) in humic acid had less effect on the extraction efficiency when water was at pH 8 compared to water at pH 2, which was probably due to greater nonpolar interactions of the pesticides to the charge-neutralized humic acid molecule.