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排序方式: 共有100条查询结果,搜索用时 15 毫秒
1.
Mendel Z Dunkelblum E Branco M Franco JC Kurosawa S Mori K 《Die Naturwissenschaften》2003,90(7):313-317
The biological activity of the Matsucoccus spp. sex pheromones and diene modified analogs has been tested in forests of Israel and Portugal in order to explore the structure-activity relationship of the pine bast scale pheromone/kairomone system. The response of the adult predatory bugs, Elatophilus hebraicus and E. crassicornis and of the brown lacewing, Hemerobius stigma is more selective than that of the conspecific Matsucoccus males. The removal of the terminal methyl group from the diene terminus of both pheromones 1 and 2 eliminates all kairomonal activity but retains moderate pheromonal activity. Addition of a methyl group to the diene terminus of pheromones 1 and 2 sustains full pheromonal and kairomonal activities of the Elatophilus spp. but eliminates entirely the kairomonal activity of H. stigma. Subtle designed alterations in the structure of the diene group, typical of all Matsucoccus pheromones, change the mode of the kairomonal activity markedly. 相似文献
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Noya Y Mikami Y Taneda S Mori Y Suzuki AK Ohkura K Yamaki K Yoshino S Seki K 《Environmental science and pollution research international》2008,15(4):318-321
GOAL, SCOPE, AND BACKGROUND: Diesel exhaust is believed to consist of thousands of organic constituents and is a major cause of urban pollution. We recently reported that a systematic separation procedure involving successive solvent extractions, followed by repeated column chromatography, resulted in the isolation of vasodilatory active nitrophenols. These findings indicated that the estimation of the amount of nitrophenols in the environment is important to evaluate their effect on human health. The isolation procedure, however, involved successive solvent extractions followed by tedious, repeated chromatography, resulting in poor fractionation and in a significant loss of accuracy and reliability. Therefore, it was crucial to develop an alternative, efficient, and reliable analytical method. Here, we describe a facile and efficient acid-base extraction procedure for the analysis of nitrophenols. MATERIALS AND METHODS: Diesel exhaust particles (DEP) were collected from the exhaust of a 4JB1-type engine (ISUZU Automobile Co., Tokyo, Japan). Gas chromatography-mass spectrometry (GC-MS) analysis was performed with a GCMS-QP2010 instrument (Shimadzu, Kyoto, Japan). RESULTS: A solution of DEP in 1-butanol was extracted with aqueous NaOH to afford a nitrophenol-rich oily extract. The resulting oil was methylated with trimethylsilyldiazomethane and subsequently subjected to GC-MS analysis, revealing that 4-nitrophenol, 3-methyl-4-nitrophenol, 2-methyl-4-nitrophenol, and 4-nitro-3-phenylphenol were present in significantly higher concentrations than those reported previously. DISCUSSION: Simple acid-base extraction followed by the direct analysis of the resulting extract by GC-MS gave only broad peaks of nitrophenols with a poor detection limit, while the GC-MS analysis of the sample pretreated with (trimethylsilyl)diazomethane gave satisfactorily clear chromatograms with sharp peaks and with a significantly lowered detection limit (0.5 ng/ml, approximately 100 times). CONCLUSION: The present method involving an acid-base extraction, in situ derivatization, and GC-MS analysis has shown to be a simple, efficient, and reliable method for the isolation and identification of the chemical substances in DEP. 相似文献
8.
Ayami Hayashi Keigo Akimoto Toshimasa Tomoda Masanobu Kii 《Mitigation and Adaptation Strategies for Global Change》2013,18(5):591-618
Fresh water is one of the most important resources required for human existence, and ensuring its stable supply is a critical issue for sustainable development. The effects of a general set of agriculture and water management adaptations on the size of the world’s water-stressed population were assessed for a specific but consistent scenario on socio-economic development and climate change during the 21st century. To maintain consistency with agricultural land use change, we developed a grid-based water supply–demand model integrated with an agro-land use model and evaluated the water-stressed population using a water withdrawals-to-availability ratio for river basins. Our evaluation shows that, if no adaptation options are implemented, the world’s water-stressed population will increase from 1.8 billion in 2000 to about 3.3 billion in 2050, and then remain fairly constant. The population and economic growth rather than climate change will be dominant factors of this increase. Significant increase in the water-stressed population will occur in regions such as North Africa and the Middle East, India, Other South Asia, China and Southeast Asia. The key adaptation options differ by region, depending on dominant crops, increase in crop demand and so on. For instance, ‘improvement of irrigation efficiency’ and ‘enhancement of reclamation water’ seem to be one of important options to reduce the water stress in Southeast Asia, and North Africa and the Middle East, respectively. The worldwide implementation of adaptation options could decrease the water-stressed population by about 5 % and 7–17 %, relative to the scenario without adaptations, in 2050 and 2100, respectively. 相似文献
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Lu Y Beeman RW Campbell JF Park Y Aikins MJ Mori K Akasaka K Tamogami S Phillips TW 《Die Naturwissenschaften》2011,98(9):755-761
We report that the abdominal epidermis and associated tissues are the predominant sources of male-produced pheromones in the
red flour beetle, Tribolium castaneum and, for the first time, describe the stereoisomeric composition of the natural blend of isomers of the aggregation pheromone
4,8-dimethyldecanal (DMD) in this important pest species. Quantitative analyses via gas chromatography–mass spectrometry showed
that the average amount of DMD released daily by single feeding males of T. castaneum was 878 ± 72 ng (SE). Analysis of different body parts identified the abdominal epidermis as the major source of aggregation
pheromone; the thorax was a minor source, while no DMD was detectable in the head. No internal organs or obvious male-specific
glands were associated with pheromone deposition. Complete separation of all four stereoisomers of DMD was achieved following
oxidation to the corresponding acid, derivatization with (1R, 2R)- and (1S, 2S)-2-(anthracene-2,3-dicarboximido)cyclohexanol to diastereomeric esters, and their separation on reversed-phase high-performance
liquid chromatography at −54°C. Analysis of the hexane eluate from Porapak-Q-collected volatiles from feeding males revealed
the presence of all four isomers (4R,8R)/(4R,8S)/(4S,8R)/(4S,8S) at a ratio of approximately 4:4:1:1. A walking orientation bioassay in a wind tunnel with various blends of the four synthetic
isomers further indicated that the attractive potency of the reconstituted natural blend of 4:4:1:1 was equivalent to that
of the natural pheromone and greater than that of the 1:1 blend of (4R,8R)/(4R,8S) used in commercial lures. 相似文献
10.
Kawanishi Masanobu Mori Kentaro Yamada Rina Ito-Harashima Sayoko Yagi Takashi 《Environmental science and pollution research international》2020,27(9):9227-9235
Environmental Science and Pollution Research - A yeast reporter gene assay system with improved performance for dioxin detection was established. Since yeast reporter gene assays are relatively... 相似文献