Synthesis of piperazine functionalized magnetic sporopollenin: a new organic-inorganic hybrid material for the removal of lead(II) and arsenic(III) from aqueous solution

Environmental Science and Pollution Research - The present work describes the successful functionalization/magnetization of bio-polymeric spores of Lycopodium clavatum (sporopollenin) with...     

Investigation on the effect of sintering temperature on kaolin hollow fibre membrane for dye filtration

Despite its extraordinary price, ceramic membrane can still be able to surpass polymeric membrane in the applications that require high temperature and pressure conditions, as well as harsh chemical environment. In order to alleviate the high cost of ceramic material that still becomes one of the major factors that contributes to the high production cost of ceramic membrane, various attempts have been made to use low cost ceramic materials as alternatives to well-known expensive ceramic materials such as alumina, silica, and zirconia in the fabrication of ceramic membrane. Thus, local Malaysian kaolin has been chosen as the ceramic material in this study for the preparation of kaolin hollow fibre membrane since it is inexpensive and naturally abundant in Malaysia. Due to the fact that the sintering process plays a prominent role in obtaining the desired morphology, properties, and performances of prepared ceramic membrane, the aim of this work was to study the effect of different sintering temperatures applied (ranging from 1200 to 1500 °C) in the preparation of kaolin hollow fibre membrane via dry/wet phase inversion-based spinning technique and sintering process. The morphology and properties of membrane were then characterised by SEM, AFM, FTIR, XRD, and three-point bending test, while the performances of membrane were investigated by conducting water permeation and Reactive Black 5 (RB5) dye rejection tests. From the experimental results obtained, the sintering temperature of 1400 °C could be selected as the optimum sintering temperature in preparing the kaolin hollow fibre membrane with the dense sponge-like structure of separation layer that resulted in the good mechanical strength of 70 MPa with the appreciable water permeation of 75 L/h m² bar and RB5 rejection of 68%.     

Trilemma association of energy consumption,carbon emission,and economic growth of BRICS and OECD regions: quantile regression estimation

Environmental Science and Pollution Research - Recent research has shown a huge impact of non-renewable energy (NRE) production on environmental health. In this context, this work analyzes the...     

Influence of overlap between the laser beam tracks on surface quality in laser polishing of AISI H13 tool steel

Polishing by laser beam radiation is a novel manufacturing process to modify the initial surface topography in order to achieve a desired level of surface finish. The performance of laser polishing (LP) is determined by an optimum combination of several key process parameters. In this regard, the overlap between two successive laser beam tracks is one of the important LP process parameters, which has a significant effect over the final surface quality. In the current study, influence of overlap between the laser beam tracks on surface quality was experimentally investigated during the laser polishing of AISI H13 tool steel. Surface areas were polished by using four different overlap percentages (e.g. 80%, 90%, 95%, and 97.5%) while applying the same energy density. The improvement of surface quality was estimated through the analysis of line profiling surface roughness R_a, areal topography surface roughness S_a, and material ratio function. Also, individual components of the surface quality, e.g. waviness and roughness, and their evolution during LP were statistically analyzed using the power spectral density and the transfer functions. Finally, as an example of the best achieved LP result, flat surface area was polished using optimum set of the process parameters improving surface quality by 86.7% through the reduction of an areal topography surface roughness S_a from 1.35 μm to 0.18 μm.     

The influence of personality traits on sustainability-oriented entrepreneurial intentions: the moderating role of servant leadership

Environment, Development and Sustainability - Economic, environmental, and social imperatives make sustainability-oriented entrepreneurship an indispensable phenomenon of the day, yet only sparse...     

Composting of municipal solid waste by different methods improved the growth of vegetables and reduced the health risks of cadmium and lead

Environmental Science and Pollution Research - Reutilization of putrescible municipal solid wastes (MSW) in agriculture can provide valuable plant nutrients. However, it may pose serious...     

The effect of nutrients shortage on plant’s efficiency to capture solar radiations under semi-arid environments

Radiation use efficiency (RUE) is considered critical for calculation of crop yield. The crop productivity can be improved by increasing the interception of solar radiation and maintaining higher RUE for plants. Irrigation water and nitrogen (N) supply are the main limiting factors for RUE in maize (Zea mays L.) across the semi-arid environments. Field experiments were conducted during two consecutive growing seasons (2009–2010) to optimize RUE in relation to N application timings and rates with varying irrigation water management practices. In experiment 1, three N application timings were made, while in experiment 2, three possible water management practices were used. In both experiments, five N rates (100, 150, 200, 250, and 300 kg N ha⁻¹) were applied to evaluate the effects of irrigation water and N on cumulative photosynthetic active radiation (PARi), dry matter RUE (RUE_DM), and grain yield RUE (RUE_GY). The results demonstrated that cumulative PARi and RUEs were not constant during the plant growth under varying the nutrients. The water and N significantly influenced cumulative PARi and RUEs during the both growing seasons. In experiment 1, the maximum cumulative PARi was observed by application of 250 kg N ha⁻¹ in three splits (1/3 N at V2, 1/3 N at V16, and 1/3 N at R1 stage), and the highest RUE_DM was achieved by the application of 300 kg N ha⁻¹. However, the highest RUE_GY was observed by application of 250 kg N ha⁻¹. In experiment 2, the maximum cumulative PARi was attained at normal irrigation regime with 250 kg N ha⁻¹, while the highest RUE_DM and RUE_GY were recorded at normal irrigation regime with the application of 300 kg N ha⁻¹. The regression analysis showed significant and positive correlation of RUE_GY with grain yield. Therefore, optimum water and N doses are important for attaining higher RUE, which may enhance maize grain yield semi-arid environment; this may be considered in formulating good agricultural practices for the environmental conditions resembling to those of this study.

     

Acid generation upon thermal concentration of natural water: The critical water content and the effects of ionic composition

Thermal evaporation of a variety of simulated pore waters from the region of Yucca Mountain, Nevada, produced acidic liquids and gases during the final stages of evaporation. Several simulated pore waters were prepared and then thermally distilled in order to collect and analyze fractions of the evolved vapor. In some cases, distillates collected towards the end of the distillation were highly acidic; in other cases the pH of the distillate remained comparatively unchanged during the course of the distillation. The results suggest that the pH values of the later fractions are determined by the initial composition of the water. Acid production stems from the hydrolysis of magnesium ions, especially at near dryness. Near the end of the distillation, magnesium nitrate and magnesium chloride begin to lose water of hydration, greatly accelerating their thermal decomposition to form acid. Acid formation is promoted further when precipitated calcium carbonate is removed. Specifically, calcium chloride-rich pore waters containing moderate (10–20 ppm) levels of magnesium and nitrate and low levels of bicarbonate produced mixtures of nitric and hydrochloric acid, resulting in a precipitous drop in pH to values of 1 or lower after about 95% of the original volume was distilled. Waters with either low or moderate magnesium content coupled with high levels of bicarbonate produced slightly basic fractions (pH 7–9). If calcium was present in excess of bicarbonate, waters containing moderate levels of magnesium produced acid even in the presence of bicarbonate, due to the precipitation of calcium carbonate. Other salts such as halite and anhydrite promote the segregation of acidic vapors from residual basic solids. The concomitant release of wet acid gas has implications for the integrity of the alloys under consideration for containers at the Yucca Mountain nuclear waste repository. Condensed acid gases at very low pH, especially mixtures of nitric and hydrochloric acid, are capable of corroding even alloys, such as nickel-based Alloy 22, which are considered to be corrosion-resistant under milder conditions.     

Accumulation of trace metals in the muscle and liver tissues of five fish species from the Persian Gulf

In this study, concentrations of 16 elements were quantified in muscles and livers of 141 fishes belonging to five commercially species. It was also our intention to evaluate potential risks to human health associated with seafood consumption. The grunt, flathead, greasy grouper, tiger-tooth croaker and silver pomfret fish species were obtained from Abadan, Deylam, Bushehr-Nirogah, Dayyer port, Lengeh port and Abbas port in Hormozgan, Bushehr and Khozesran provinces at the Iranian waters of the Persian Gulf. The contents of Al, As, Be, Cd, Cr, Co, Cu, Fe, Pb, Mn, Mo, Ni, Sb, Tl, V and Zn in fish muscles and livers were determined by Inductively Coupled Plasma Mass Spectrometry (ICP MS), after digestion in a CEM (Mars 5) microwave oven using nitric acid and hydrogen peroxide. Our results indicated that almost all metals were more accumulated in younger flathead, greasy grouper and tiger-tooth fishes. Contrary to the other fish species, grunt seems to stronger accumulating elements in the older fishes. Strong and positive correlations were observed in three or more of the fish species between V, Al, Fe, Tl, Co and Pb. The results confirmed that fish muscle and liver tissues appeared to be good bio-indicators for identification of coastal areas exposed to metallic contaminants. The results also showed that the element levels in the muscles of all fishes in our study were lower than the maximum allowable concentrations and pose no threat to public health, except for arsenic.