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1.
Kulmatov Rashid Taylakov Abdurazok Khasanov Sayidjakhon 《Environmental science and pollution research international》2021,28(10):12245-12255
Environmental Science and Pollution Research - The Aydar-Arnasay Lake System (AALS) is located in the middle of the Syrdarya River, to the south of the Chardara Reservoir, and in Jizakh and Navoi... 相似文献
2.
Heavy metal accumulation in Littoraria scabra along polluted and pristine mangrove areas of Tanzania
The periwinkle Littoraria scabra was collected at polluted and pristine mangrove sites along the Tanzanian coastline, including Msimbazi, Mbweni (i.e. Dar es Salaam) and Kisakasaka, Nyamanzi and Maruhubi (i.e. Zanzibar). Periwinkles were morphologically characterized, sexed and their heavy metal content was determined using ICP-MS. Analysis revealed that L. scabra from polluted areas contained higher soft tissue heavy metal levels, were significantly smaller and weighed less compared to their conspecifics from the unpolluted mangroves. The current morphological observations may be explained in terms of growth and/or mortality rate differences between the polluted and non-polluted sites. Although a variety of stressors may account for these adverse morphological patterns, our data suggest a close relationship with the soft tissue heavy metal content. Compared to soft tissue heavy metal levels that were measured in L. scabra along the same area in 1998, most metals, except for arsenic, chromium and iron have decreased dramatically. 相似文献
3.
The potential of cost-effective coconut husk for the removal of toxic metal ions for environmental protection 总被引:2,自引:0,他引:2
Coconut (Cocos nucifera) husk, an agricultural waste, has been thoroughly investigated for the removal of toxic Cd(II), Cr(III) and Hg(II) ions from aqueous media. The parameters like nature and composition of electrolyte, concentration of toxic ions, dosage of coconut husk, and equilibration time between the two phases were optimized for their maximum accumulation onto the solid surface. The effect of common ions on the uptake of metal ions has been monitored under optimal conditions. The variation of retention of each metal ion with temperature was used to compute the thermodynamic quantities DeltaH, DeltaS and DeltaG. The values 18.1+/-0.6 kJmol(-1), 74+/-2 Jmol(-1)K(-1), and -3.8+/-0.04 kJmol(-1) at 298 K; 10.8+/-0.8 kJmol(-1), 48.8+/-2.7 Jmol(-1)K(-1), and -4.6+/-0.3 kJmol(-1) at 298 K; and -37.4+/-2k Jmol(-1), 105+/-7 Jmol(-1)K(-1) and -2.58+/-0.5 kJmol(-1) at 298 K were obtained for Cd(II), Cr(III) and Hg(II) ions, respectively. The sorption data were analysed by applying different sorption isotherms. The sorption capacity and energy were evaluated for each metal ion. The values of the Freundlich constants 1/n and C(m) were 0.92+/-0.04 and 52.6+/-22.2 mmolg(-1); 0.85+/-0.05 and 56.0+/-0.03 mmolg(-1); and 0.88+/-0.03 and 6.84+/-0.45 mmolg(-1) for Cd(II) Cr(III) and Hg(II) ions, respectively. Similarly, the Dubinin-Radushkevich (D-R) constants beta, X(m,) and E were evaluated for the three metal ions. To check the selectivity of the sorbent, sorption of a number of elements was measured under similar conditions. Separation of Zn(II) from Cd(II); Cr(III) from I(I), Zr(IV), Se(IV), and Hg(II) from Se(IV) and Zn(II) can be achieved using this sorbent. This cheap material has potential applications in analytical chemistry, water decontamination, industrial effluent treatment and in pollution abatement. 相似文献
4.
Mujahid Farid Shafaqat Ali Muhammad Rizwan Rashid Saeed Hafiz Muhammad Tauqeer Rasham Sallah-Ud-Din Ahmed Azam Nighat Raza 《Environmental science and pollution research international》2017,24(26):21050-21064
The complex bio-geochemistry of soil allows pollutant to persist for a longer period of time which further decreased the fertility and natural composition of land. Nickel, an inorganic pollutant, coming from a wide range of industrial and manufacturing units possesses serious threat to soil degradation and crop productivity around the world. The present study was carried to evaluate the combined role of microwave irradiation (MR) and citric acid (CA) on the phytoextraction potential of Brassica napus L. under Ni stress. An initial seed germination test was conducted to select effective time scale of MR exposure. Highest seed germination was observed at exposure of 2.45 GHz frequency for 30 s. Healthy seeds of B. napus L. genotype Faisal Canola (RBN-03060) treated with MR at 2.45 GHz for 30 s were sown in plastic pots filled with 5 kg of soil. Nickel and CA applied exogenously in solution form with different combinations to both MR-treated and untreated B. napus plants. The MR-treated plants showed higher growth, biomass, photosynthetic pigments (Chl a, b, total, and carotenoids) and activities of antioxidant enzymes (SOD, POD, APX, CAT) as compared to untreated plants who showed higher reactive oxygen species (MDA, H2O2) and electrolyte leakage. Increasing Ni concentration significantly decreased the physiological and biochemical attributes of B. napus both in MR-treated and untreated plants. The addition of CA alleviated Ni-induced toxic effects in both MR-treated and untreated plants by improving antioxidant defense system. The degree of Ni stress mitigation was higher in MR-treated plants. The Ni concentration was higher in root, stem, and leaves of MR-treated plants under CA application as compared to untreated plants. The present study concluded that seeds treated with MR before sowing showed higher accumulation and concentration of Ni from soil, and this phenomenon boosted with the application of CA. 相似文献
5.
Farid Mujahid Ali Shafaqat Akram Nudrat Aisha Rizwan Muhammad Abbas Farhat Bukhari Syed Asad Hussain Saeed Rashid 《Environmental science and pollution research international》2017,24(20):16845-16859
Environmental Science and Pollution Research - Chromium (Cr) is a biologically non-essential, carcinogenic and toxic heavy metal. The cultivation of Cr-tolerant genotypes seems the most favorable... 相似文献
6.
In a controlled environment experiment, using Cd spiked soil, lettuce plants were grown under a range of DTPA levels and were subsequently harvested to determine levels of phytoaccumulation. Cadmium phytoaccumulation significantly increased with increasing soil Cd level (P < 0.05) but unexpectedly decreased with increasing DTPA levels, despite the fact that solubility of Cd was increased in the soil. Cadmium translocation (from root to shoot) increased after DTPA application. Lettuce growth was inhibited by both Cd and DTPA (at and above 10 and 500 mg kg?1 respectively), as a result of higher Cd mobility and subsequent toxicity which was caused by DTPA higher dosages. Metal solubility in the soil (ranged between 2.8 and 26.5 mg kg?1) was found to be significantly higher (P < 0.01) as compared to control with increasing DTPA levels even after 3 months of DTPA application. Cadmium tissue concentration in all DTPA treatments was less than in the corresponding control treatment, indicating a negative effect of DTPA application on Cd uptake. In conclusion, lettuce was an unsuitable plant species for Cd accumulation, at least when associated with a DTPA chelator. 相似文献
7.
Loghman Khoda Krami Fazel Amiri Alireza Sefiyanian Abdul Rashid B. Mohamed Shariff Tayebeh Tabatabaie Biswajeet Pradhan 《Environmental monitoring and assessment》2013,185(12):9871-9888
One hundred and thirty composite soil samples were collected from Hamedan county, Iran to characterize the spatial distribution and trace the sources of heavy metals including As, Cd, Co, Cr, Cu, Ni, Pb, V, Zn, and Fe. The multivariate gap statistical analysis was used; for interrelation of spatial patterns of pollution, the disjunctive kriging and geoenrichment factor (EFG) techniques were applied. Heavy metals and soil properties were grouped using agglomerative hierarchical clustering and gap statistic. Principal component analysis was used for identification of the source of metals in a set of data. Geostatistics was used for the geospatial data processing. Based on the comparison between the original data and background values of the ten metals, the disjunctive kriging and EFG techniques were used to quantify their geospatial patterns and assess the contamination levels of the heavy metals. The spatial distribution map combined with the statistical analysis showed that the main source of Cr, Co, Ni, Zn, Pb, and V in group A land use (agriculture, rocky, and urban) was geogenic; the origin of As, Cd, and Cu was industrial and agricultural activities (anthropogenic sources). In group B land use (rangeland and orchards), the origin of metals (Cr, Co, Ni, Zn, and V) was mainly controlled by natural factors and As, Cd, Cu, and Pb had been added by organic factors. In group C land use (water), the origin of most heavy metals is natural without anthropogenic sources. The Cd and As pollution was relatively more serious in different land use. The EFG technique used confirmed the anthropogenic influence of heavy metal pollution. All metals showed concentrations substantially higher than their background values, suggesting anthropogenic pollution. 相似文献
8.
9.
Fuels like coal and rubber are frequently used for brick burning. However, both coal and rubber contain heavy metals. These heavy metals may elutriate in the wake of fly ash or may adsorb or absorb in the product. The present work deals with the analysis of heavy metals in some samples collected from brick burning industries located in the vicinity of a metropolitan city, Peshawar, Pakistan. Samples from raw clay, product, chimney scale and fossil fuel & rubber were collected and leached with acid mixture. The leachates were concentrated and analyzed by atomic absorption spectrophotometer for the determination of chromium (Cr), lead (Pb), cadmium (Cd) and antimony (Sb). It was observed that heavy metals are present in clay, brick and chimney scale. However, significant amount of these metals was observed in chimney scale. It is inferred that such emanations laden with heavy metals are accompanying the stack gases which are being dumped in to the environment. In order to avoid environmental problems, strict environmental regulations shall be enforced and a constant check on these emanations to the environment must be made to ensure clean air act. 相似文献
10.
Kamal A. Rashid Masood Arjmand Heinrlch Sandertnann Ralph O. Mumma 《Journal of environmental science and health. Part. B》2013,48(6):721-729
Abstract Chloroanilines are constituents of many agrochemicals and have been found to be metabolized to succinic acid conjugates, e.g., succinamides and succinimides. The mutagenic potential of five chloroanilines and their succinamides and succinimide derivatives have been tested with two strains of Salmonella typhimurium (TA98 and TA100) with and without rat hepatic micro‐somal fraction. None of the compounds produced a dose response effect with a two‐fold increase in revertants indicating that these compounds are not mutagens or promutagens in these assays. 相似文献