A field study of triclosan loss rates in river water (Cibolo Creek, TX)

Triclosan (TCS) is an anti-microbial agent used in down-the-drain consumer products. Following sewage treatment some of the triclosan will enter receiving waters. This study was designed to determine the die-away rate of triclosan released into a river as part of the sewage treatment plant effluent matrix. The study was conducted in Cibolo Creek, a moderate sized stream (discharge approximately 0.1 m(3)s(-1)) located in South Central Texas. Triclosan was analyzed from samples collected upstream of the sewage treatment plant, the sewage treatment plant effluent, and the river downstream from the effluent discharge. The first-order loss rate of parent triclosan from the water column was calculated from measured data (0.06 h(-1)) and this rate corresponded to a 76% reduction in triclosan over an 8 km river reach below the discharge. Mathematical modeling indicated that sorption and settling accounted for approximately 19% of total triclosan loss over 8 km. When removing sorption and settling, the remaining amount of triclosan had an estimated first-order loss rate of 0.25 h(-1). This loss rate was presumably due to other processes such as biodegradation and photolysis. These data show that loss of parent triclosan from the water column is rapid. Additional data are needed to fully document loss mechanisms.     

Risk assessment approach for untreated wastewater using the QUAL2E water quality model

This paper presents a novel approach for assessing the risk of consumer product ingredients in surface waters that receive untreated wastewater. The approach utilizes the water quality simulation model QUAL2E for predicting the impact caused by conventional pollutants, as well as the exposure concentration of consumer product ingredients. This approach invokes an impact zone concept whereby the receiving water can be thought of as a natural wastewater treatment system. After the river has recovered via self-purification, the ecosystem is then assessed by traditional risk assessment methods. This approach was validated using data collected from the Balatuin River, which is located in the Philippines. Results from this study support the use of QUAL2E for assessing the risk of consumer product ingredients in riverine systems receiving untreated wastewater.