A new strategy for determination of hydroxylamine and phenol in water and waste water samples using modified nanosensor

A carbon paste electrode modified with p-chloranil and carbon nanotubes was used for the sensitive and selective voltammetric determination of hydroxylamine (HX) and phenol (PL). The oxidation of HX at the modified electrode was investigated by cyclic voltammetry (CV), chronoamperommetry, and electrochemical impedance spectroscopy. The values of the catalytic rate constant (k), and diffusion coefficient (D) for HX were calculated. Square wave voltammetric peaks current of HX and PL increased linearly with their concentrations at the ranges of 0.1–172.0 and 5.0–512.0 μmol L^?1, respectively. The detection limits for HX and PL were 0.08 and 2.0 μmol L^?1, respectively. The separation of the anodic peak potentials of HX and PL reached to 0.65 V, using square wave voltammetry. The proposed sensor was successfully applied for the determination of HX and PL in water and wastewater samples.     

Comparative distribution of the scalp hair trace metal contents in the benign tumour patients and normal donors

The scalp hair samples of benign tumour patients (n = 77) and normal donors (n = 86) were analysed for selected trace metal contents using atomic absorption spectrophotometry. In the scalp hair of benign tumour patients, highest average levels were found for Ca (1,401 microg/g), followed by Na (476.9 microg/g), Mg (441.6 microg/g), Zn (438.3 microg/g), K (119.2 microg/g) and Fe (96.38 microg/g) while in comparison, the maximum mean levels in the scalp hair of normal donors were shown by Ca (556.5 microg/g), followed by Zn (154.2 microg/g), Mg (153.4 microg/g), Na (97.45 microg/g) and Fe (81.68 microg/g). Almost all metal levels revealed higher dispersion and asymmetry in the scalp hair of benign tumour patients compared with the normal donors. The average concentrations of Ca, Cd, Co, K, Mg, Mn, Na, Ni, Pb, Sb, Sr and Zn were significantly higher in the hair of benign tumour patients compared with the normal donors. Significant gender-based differences were also observed in the scalp hair metal contents of benign tumour patients. Strong positive correlations were found between Cd-Cr (0.547) and Cd-Co (0.507) in the hair of benign tumour patients whereas Ca-Mg, Mg-Sr, Co-Cd, Cr-Cd, Li-Cr, Li-Co, Li-Cd, Na-Cd, Na-Co and Na-Li exhibited strong relationships (r > 0.50) in the hair of normal donors. Cluster analysis (CA) and principal component analysis (PCA) were used for the source identification and apportionment of scalp hair trace metals in the two donor groups. The scalp hair of benign tumour patients and normal donors revealed six and five main clusters of trace metals, respectively. PCA extracted seven principal components of trace metals in the scalp hair of benign tumour patients while six principal components were observed in the case of normal donors. The study evidenced significantly different patterns of metal distribution in the hair of benign tumour patients in comparison with normal donors.     

Spatio-temporal changes associated with natural and anthropogenic factors in wetlands of Great Rann of Kachchh,India

Studies about wetlands have been identified as a key component of environmental change. The present study assesses the spatio-temporal changes in the wetlands of the Great Rann of Kachchh, in the Kachchh Biosphere Reserve, India, using remote sensing and GIS techniques. Satellite time-series data from Landsat (1977, 1990 and 1999) and IRS P6 (2006, 2008–2012) were used. The Normalised Difference Water Index (NDWI) was derived for each year and the layers were manually edited to obtain a high classification accuracy. The analysis found that the area has undergone considerable change from 1977 to 2011. The natural wetland area of 30.6 km² was converted to salt pans. An area of about 255 km² (41.6 %) of natural grassland was invaded by Prosopis juliflora, which raises further conservation concerns and emphasises the importance of having intervention plans to manage this ecosystem. The highest water spread of 1171 km² was observed in September 2011, followed by 2010, 2009 and 2008 in the same month. The present study is useful in planning the long-term management and conservation of the Great Rann of Kachchh wetland.     

The COVID-19 impact on air condition usage: a shift towards residential energy saving

Environmental Science and Pollution Research - The enforcement of the Movement Control Order to curtail the spread of COVID-19 has affected home energy consumption, especially HVAC systems....