Zearalenone screening of human breast milk from the Naples area

The mycotoxin zearalenone exhibits estrogenic and anabolic properties in several animal species, humans included. Food contamination by zearalenone is caused either by direct contamination of grains, fruits, and their based-products or by “carry-over” of mycotoxins in animal tissues, milk, and eggs after intake of contaminated feedstuff. Now, a survey on zearalenone contamination in breast milk of healthy primiparous women living in the Naples countryside was conducted. From 47 healthy primiparous women, breast milk samples were collected within the first six weeks after delivery as well as clinical data of mother–newborn pairs. Breast milk analyses were performed with both competitive indirect enzyme-linked immunosorbent assay and high-performance liquid chromatography with fluorescence detection. At 36.9 ± 2.6 days after vaginal delivery, the mean zearalenone contents of the breast milk samples were 1.13 ± 0.34 µg/L. The zearalenone levels correlated with both mother weights before pregnancy (r = ?0.506; P < 0.001) and at delivery (r = ?0.351; P < 0.05). The present results indicate that breast milk may be contaminated with zearalenone.     

Genotoxicity biomarkers and acetylcholinesterase activity in natural populations of Mytilus galloprovincialis along a pollution gradient in the Gulf of Oristano (Sardinia, western Mediterranean)

A year-round biomonitoring study on blue mussels (Mytilus galloprovincialis) was carried out in 4 selected sites along the Gulf of Oristano (Sardinia, Italy): a commercial port (Port), the outlet of the S'Ena Arrubia and Marceddì lagoons (in the catchment area of intensive agricultural and diary activities, and abandoned mining), and a reference site (North). Heavy metal concentrations in sediments from Marceddì were 2-3 to 10-20 times higher in Pb, Cd and Zn, respectively, than those found at North and S'Ena Arrubia. Higher values (P<0.05) of micronuclei frequency were detected in mussels from Marceddì and Port compared to those detected in mussels from North and S'Ena Arrubia. DNA damage in animals from North was significantly lower than that at the other sites. Results of acetylcholinesterase inhibition consistently showed the strongest effects in mussels from Port and Marceddì. Our results suggest that these biomarkers can be used in coastal marine biomonitoring as early signals of exposure and adverse effects along a pollution gradient.     

WATER QUALITY OF AN INTENSWE AGRICULTURAL WATERSHED IN QUEBEC1

ABSTRACT: . Under a watershed based approach being examined by the Quebec Ministry of Agriculture to accelerate the adoption of conservation practices, a study on the impacts of agricultural practices on the St. Esprit watershed was initiated in the fall of 1993. The water quality of this 26 km² intensive agricultural watershed was studied over an 18 month period. Water samples taken at the outlet of the watershed were analyzed for nitrate, phosphate, suspended sediment, and atrazine. Water quality data were analyzed to establish seasonal trends in pollutant concentration and load in the watercourse. Spring snowmelt was identified as a significant period of pollutant material export. All pollutant materials displayed seasonal variability in the export process. Peak pollutant concentrations were associated with high flow events. Mean observed pollutant concentrations did not exceed drinking water quality standards.     

Detection and quantitative analysis of organochlorine compounds (PCBs and DDTs) in deep sea fish liver from Mediterranean Sea

Background, aim and scope  

Polychlorinated biphenyls (PCB) and dichlorodiphenyltrichloroethane (DDT) concentrations were determined in the liver of two deep sea fish species, Mediterranean slimehead and blackfin sorcerer, from the Adriatic Sea (southeastern Mediterranean Sea).     

A Review of the United States' Past and Projected Water Use

Good information and data on water demands are needed to perform good analyses, yet collecting and compiling spatially and temporally consistent water demand data are challenges. The objective of our work was to understand the limitations associated with water‐use estimates and projections. We performed a comprehensive literature review of national and regional United States (U.S.) water‐use estimates and projections. We explored trends in past regional projections of freshwater withdrawals and compared these values to regional estimates of freshwater withdrawals made by the U.S. Geological Survey. Our results suggest a suite of limitations exist that have the potential for influencing analyses aiming to extract explanatory variables from the data or using the data to make projections and forecasts. As we explored regional projections, we paid special attention to the two largest water demand‐side sectors — thermoelectric energy and irrigation — and found thermoelectric projections are more spread out than irrigation projections. All data related to water use have limitations, and there is no alternative to making the best use that we can of the available data; our article provides a comprehensive review of these limitations so that water managers can be more informed.     

Atmospheric pollution in an urban environment by tree bark biomonitoring - part II: Sr, Nd and Pb isotopic tracing

The harmful effect of manmade particles on natural processes and human health is documented by a large number of studies showing a positive correlation between particulate matter (PM) concentration and health effects. Diminution of this health risk necessitates among others the precise knowledge of the particle sources, their physical and chemical properties and their dissemination in the environment. Pb isotope ratios have been successfully used during the past decades as tracers of anthropogenic Pb disseminated in the biosphere. Here we show that tree bark biomonitoring with lead (Pb), strontium (Sr) and neodymium (Nd) isotope ratios as tracers allow a thorough analysis of the impacts of industrial and other anthropogenic emissions on the urban environment. This is the first comprehensive multi-isotope tracer study of atmospheric pollution in an urban environment allowing to identify and to integrate the different plume paths of emissions in a digital map system. This innovative approach might become an important tool for environmental management and policy-making processes dealing especially with risks and surveillance of air quality in the urban environment.