A combined radical and non-radical oxidation processes for efficient degradation of Acid Orange 7 in the homogeneous Cu(II)/PMS system: important role of chloride

Environmental Science and Pollution Research - Trace copper ion (Cu(II)) in water and wastewater can trigger peroxymonosulfate (PMS) activation to oxidize organic compounds, but it only works under...     

Preparation of Viscose Fibres Stripped of Reactive Dyes and Wrinkle-Free Crosslinked Cotton Textile Finish

The chemical recycling of cellulosic fibres may represent a next-generation fibre–fibre recycling system for cotton textiles, though remaining challenges include how to accommodate fibre blends, dyes, wrinkle-free finishes, and other impurities from finishing. These challenges may disrupt the regeneration process steps and reduce the fibre quality. This study examines the impact on regenerated viscose fibre properties of a novel alkaline/acid bleaching sequence to strip reactive dyes and dimethyloldihydroxyethyleneureas (DMDHEU) wrinkle-free finish from cotton textiles. Potentially, such a bleaching sequence could advantageously be integrated into the viscose process, reducing the costs and environmental impact of the product. The study investigates the spinning performance and mechanical properties (e.g., tenacity and elongation) of the regenerated viscose fibres. The alkaline/acid bleaching sequence was found to strip the reactive dye and DMDHEU wrinkle-free finish from the cotton fabric, so the resulting pulp could successfully be spun into viscose fibres, though the mechanical properties of these fibres were worse than those of commercial viscose fibres. This study finds that reactive dyes and DMDHEU wrinkle-free finish affect the viscose dope quality and the regeneration performance. The results might lead to progress in overcoming quality challenges in cellulosic chemical recycling.     

Cyclodextrin-based supramolecular assemblies: a versatile toolbox for the preparation of functional porous materials

The discovery of ordered mesoporous materials in 1992 by Mobil Oil Corporation scientists has opened great opportunities for new applications in many emerging fields such as heterogeneous catalysis, biocatalysis, energy conversion, biosensors, photocatalytic devices and environmental technologies. Porous materials are grouped by the International Union of Pure and Applied Chemistry (IUPAC) into three classes according to their pore diameter: microporous (<?2 nm), mesoporous (2–50 nm) and macroporous (>?50 nm). One of the most versatile methods for the preparation of those materials is the soft template approach which combines the sol–gel process with molecular self-assembly. While the micelles formed by ionic or nonionic surfactants, as well as amphiphilic polymers, have been extensively used as templates, the supramolecular assemblies formed between cyclodextrins and block copolymers have been less investigated, despite their large chemical and structural diversity. This review article focuses mainly on nanostructured porous inorganic materials derived from cyclodextrins or cyclodextrin-based assemblies. More than 100 references are described and discussed, in which we look both at their synthesis and characterization, as well as their applications in the emerging fields of heterogeneous catalysis and photocatalysis. A special attention is paid to the evaluation of the critical parameters that need to be controlled for improving their (photo) catalytic performances.     

Special issue on contamination,remediation and health for pollutants in natural aquatic,soil, sediments and atmospheric environments

Environmental Geochemistry and Health -     

Heat dissipation characteristic in the intake grille and radiator of a fuel cell vehicle

ABSTRACT

In this study, a three-dimension (3D) computational model was proposed to investigate the flow and heat transfer characteristics of the intake grilles of two different fuel cell vehicles. The models of the intake grilles were constructed according to the actual sizes of two vehicles, namely, Roewe 950 and Toyota Mirai, considering the heat dissipation unit to simplify the heat transfer model of the vehicle. The results showed that relative to Roewe 950, Mirai intake air flow rate was approximately 10% higher, the heat transfer capacity was approximately 7% higher, and the intake grille area was larger. The coolant outlet temperature of Mirai was lower than that of Roewe 950, which was beneficial for the long term and stable operation of a fuel cell. This comparative study provided guidance for the intake grille and radiator design of fuel cell vehicles. The only difference between fuel cell vehicles on the market and conventional vehicles was that in the former, the internal combustion engine was replaced with a fuel cell stack, which had insufficient heat transfer capacity because of the reducing temperature difference. Increasing the intake grille area and the heat exchange capacity of the radiator were the key issues for the development of fuel cell vehicles. In this study, an optimal window opening angle of the radiator fin of 23° provided a maximal heat transfer coefficient.     

2005-2019年我国重特大安全生产事故特征分析

为探究我国重特大安全生产事故特征,选取2005-2019年国内852起重特大事故作为研究对象,基于Python编程语言针对重特大事故发生的年份、季度、月份、工作日与非工作日、地域特征进行分析.结果表明:2005-2019年,国内重特大安全生产事故起数和死亡人数均在不断下降;第四季度发生重特大事故最多,而第三季度平均每起事故造成的死亡人数最多;重特大事故数量和死亡人数随月份显示出反复波动的趋势,均呈现3个"^",形;工作日期间发生的重特大事故数量最多,非工作日平均事故率最大;国庆节是重特大事故发生最多的节假日;贵州、湖南、山西、云南、河南等省份"十四五"期间需要重点加强安全和应急管理.     

Promoting e-mobility in India: challenges,framework, and future roadmap

The purpose of the research is to identify the critical challenges that are impeding the adoption of e-mobility in India. It also aims to give a roadmap how to address these challenges while taking into considerations concerns of all the relevant stakeholders. Based on an in-depth literature review, an exploratory research design is employed to delve deep into various aspects of e-mobility. This is followed by a three-phase Delphi technique to identify and rate the e-mobility challenges in the Indian context. The study successfully identifies four different categories of challenges and proposes integrative framework for e-mobility. Further, the research goes on to lay out the future roadmap for mass adoption of electric vehicles (EVs) in India. The research is novel in terms of presenting a holistic viewpoint on e-mobility in India. Its originality lies in identifying the major inhibitors obstructing EVs adoption in India and then suggesting the roadmap how to overcome these impediments for mass adoption of e-mobility.     

Introduced and cryptogenic species in Port Phillip Bay, Victoria, Australia

Port Phillip Bay (PPB) is a large (1,930 km²), temperate embayment in southern Victoria, Australia. Extensive bay-wide surveys of PPB have occurred since 1840. In 1995/1996 the Commonwealth Scientific and Industrial Research Organization (CSIRO) Centre for Research on Introduced Marine Pests (CRIMP) undertook an intensive evaluation of the region with the aims of developing a comprehensive species list of native and introduced biota and contrasting previous bay-wide assessments with a current field survey in order to detect new incursions and discern alterations to native communities. Two methods were used to meet these aims: a re-evaluation of regional museum collections and published research in PPB to identify and determine the timing of introductions; and field surveys for benthic (infauna, epifauna and encrusting) organisms between September 1995 to March 1996. One hundred and sixty introduced (99) and cryptogenic (61) species were identified representing over 13% of the recorded species of PPB. As expected, the majority of these are concentrated around the shipping ports of Geelong and Melbourne. Invasions within PPB appear to be increasing, possibly due to an increase in modern shipping traffic and an increase in aquaculture (historically associated with incidental introductions); however the records of extensive biological surveys suggest that this may, in part, be an artefact of sampling effort. In contrast to Northern Hemisphere studies, PPB (and Southern Hemisphere introductions in general) have significantly different suites of successfully invading taxa. PPB is presented as one of the most invaded marine ecosystems in the Southern Hemisphere.Communicated by M.S. Johnson, Crawley