粉尘在巷道中的紊流传递分析

建立的粉尘在巷道中的传递方程是一个二维平流扩散输运方程。在巷道顶底板为吸收壁的条件下，导出了粉尘浓度分布函数。传统的工业沉降室沉降效率公式（横向混合模型）只是论文所列方程的一个特例。降低紊流强度和减小紊流扩散系数和纵向弥散系数均可提高沉降效率     

重力作用下尘粒运动的数值解法

提出了重力作用下尘粒运动的数值解法。依据尘粒的重力、浮力及所受到的阻力推出了尘粒自然沉降时的运动方程。当尘粒的运动在斯托克斯领域内时采用理论公式求解其运动轨迹,当尘粒的运动进入非斯托克斯领域内时,提出了修正斯托克斯公式的方法以达到用理论公式来近似模拟该领域内的尘粒自然沉降运动     

Investigation of the reaction of hexabromocyclododecane with polysulfide and bisulfide in methanol/water solutions

Reactions of hexabromocyclododecane (HBCD), a widely used brominated flame retardant, with reduced sulfur species (e.g., polysulfide and bisulfide) were investigated in well-defined solutions under anoxic conditions. It is likely that reactions of HBCD with reduced sulfur species such as polysulfides and bisulfide present in anoxic subregions of coastal water bodies and sediments could have a significant impact on the fate of HBCD. The second-order reaction rate constant of HBCD with polysulfides in 80% methanol/20% water at 40°C is 2.2 (±0.3)×10(-2) M(-1) s(-1). The second-order reaction rate constant of HBCD with bisulfide is 8.9 (±2.8)×10(-4) M(-1) s(-1) under the same conditions. The formation of two products was observed with either of the two reduced sulfur species. The experiments also indicate that the γ-isomer of HBCD is reacting significantly faster with reduced sulfur species than the α-isomer.