In situ hydrothermal fabrication of visible light-driven g-C3N4/SrTiO3 composite for photocatalytic degradation of TC

Environmental Science and Pollution Research - A series of g-C3N4/SrTiO3 (CN/SrTiO3) composites with the different mass ratio of g-C3N4 were prepared by facile in situ hydrothermal growth method,...     

给水厂污泥陶粒制备及其对氮磷吸附研究

水中氮磷的去除能有效控制水体富营养化。用给水厂的两种污泥在3种烧结温度下制备陶粒,并进行陶粒同步吸附氮磷的性能实验。结果表明,600℃烧结温度下平流沉淀池湿污泥制备的陶粒吸附氮磷的综合效果最好。该陶粒对磷酸盐和氨氮的吸附过程都符合Langmuir模型和准二级动力学模型。pH为7时,陶粒同步吸附氮磷,对氨氮的吸附量可达0.650mg/g,对磷酸盐的吸附量可达0.706mg/g。可见,给水厂污泥陶粒同步吸附氮磷表现出良好的吸附效果。     

浅谈卧龙特区梯级电站建设对自然保护区的影响

根据笔者参加卧龙特区梯级电站规划中了解到的一些情况,首先阐述了保护区的自然环境和社会环境以及在此背景上造成的当前大熊猫的处境。接着分析了梯级电站建设可能带来的生态效益、经济效益和社会效益。同时,又估计到会带来的一些不利影响,重点是对大熊猫的生存环境方面。最后,从加强自然保护角度建议对方案中在核心区布置的一些梯级电站应持慎重态度,并提了几点保护措施。     

Mechanism and kinetic properties of NO3-initiated atmospheric degradation of DDT

In this article, the NO3 radical-initiated atmospheric oxidation degradation of DDT was theoretically investigated using molecular orbital theory calculations. All the calculations of intermediates, transition states and products were performed at the MPWB1K/6-311+G(3df,2p)//MPWB1K/6-31+G(d,p) level of theory. Several energetically favorable reaction pathways were revealed. The formation mechanisms of secondary pollutants were presented and discussed. The rate constants were deduced over the temperature range of 273–333 K using canonical variational transition-state(CVT) theory with the small curvature tunneling(SCT) method. Our study shows that H abstraction from the alkyl group and NO3 addition to the C3 atom of the benzene ring are the dominant reaction pathways. The rate-temperature formula of the overall rate constants is k(T)(DDT+NO3) =(7.21 × 10.15)exp(–153.81/T) cm3/(mol·sec) over the possible atmospheric temperature range of 273–333 K. The atmospheric lifetime of DDT determined by NO3 radical is about 52.5 days, which indicates that it can be degraded in the gas phase within several months.     

废CRT玻璃循环利用现状与研究进展

随着技术的发展,CRT逐步被LED等取代。废弃CRT锥管玻璃含有氧化铅,含铅玻璃是一种对环境有害的物质,如何处理这些玻璃,是目前被广泛关注的课题之一。从循环利用的角度出发,分析了锥管玻璃的氧化物含量,将废弃CRT玻璃中的氧化物含量与照明及建材玻璃的组成比较,研究了废阴极射线管及屏锥在玻璃工业中的循环利用。